Citation: ZHANG Shuyi, BAO Jingxian, WU Bo, ZHONG Liangshu, SUN Yuhan. Research Progress on the Photocatalytic Conversion of Methane and Methanol[J]. Acta Physico-Chimica Sinica, ;2019, 35(9): 923-939. doi: 10.3866/PKU.WHXB201810002 shu

Research Progress on the Photocatalytic Conversion of Methane and Methanol

ZHANG Shuyi ^1,2 ,
BAO Jingxian ^1,3 ,
WU Bo ^1,2 ,
ZHONG Liangshu ^1,4,, ,
SUN Yuhan ^1,4,,

1.
CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute
2.
Chinese Academy of Sciences, Shanghai 201203, P. R. China
3.
University of the Chinese Academy of Sciences, Beijing 100049, P. R. China
4.
College of Sciences, Shanghai University, Shanghai 200444, P. R. China

Corresponding author: ZHONG Liangshu, zhongls@sari.ac.cn SUN Yuhan, sunyh@sari.ac.cn
Received Date: 8 October 2018
Revised Date: 21 November 2018
Available Online: 26 September 2018
Fund Project: National Natural Science Foundation of China 21573271National Natural Science Foundation of China 21703278"Transformational Technologies for Clean Energy and Demonstration" and Strategic Priority Research Program of the Chinese Academy of Sciences XDA21020600This work was supported by the National Key R & D Program of China 2018YFB0604700Key Research Program of Frontier Sciences, CAS QYZDB-SSW-SLH035National Natural Science Foundation of China 91545112This work was supported by the National Key R & D Program of China (2017YFB0602202, 2018YFB0604700), National Natural Science Foundation of China (21573271, 91545112, 21703278), Key Research Program of Frontier Sciences, CAS (QYZDB-SSW-SLH035), the "Transformational Technologies for Clean Energy and Demonstration" and Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21020600)This work was supported by the National Key R & D Program of China 2017YFB0602202

With the increasing energy demands and the limited petroleum reserves, it is highly desirable to produce fuels and chemicals from non-petroleum feedstocks, such as coal, natural gas and biomass. Catalytic conversion of C₁ resources (CO, CO₂, CH₃OH, CH₄, etc.) affords various products and attracts increasing attention from both academia and industries. Methane and methanol are important C₁ feedstocks in the production of fuels and chemicals. In order to obtain high selectivity for the target product, it is necessary to control the activation of C―H bonds in methane and methanol. However, this remains a great challenge. Although the traditional thermal catalytic conversion of methane and methanol has been developed over decades, there are still some disadvantages associated with the catalytic process, such as harsh reaction conditions, high energy consumption, and low selectivity. Photocatalysis, which is driven by photoenergy, can compensate for the Gibbs free energy. In the photocatalytic reactions, semiconductor photocatalysts absorb photons and generate electrons and holes in their conduction and valence bands, respectively, to accelerate the reaction rate. The position of the conduction band determines the oxidation capacity, and the bandgap determines the light absorption property. Normally, the oxidation capacity of photocatalysts is regulated by choosing semiconductors with a suitable bandgap or anions/cations doping. Fabrication of heterojunction and loading metalsare recognized as effective methods to promote the separation of electron-hole pairs and improve the photocatalytic efficiency. In contrast to thermal catalysis, photocatalysis can be carried out under mild reaction conditions with low energy consumption. Recently, photocatalysis has been considered an attractive route for the efficient conversion of methane and methanol to fuels and chemicals. Partial oxidation of methane, which is necessary to avoid the formation of byproducts, can be achieved by adjusting the wavelength and intensity of the light and the oxidation capacity of the photocatalysts. In addition, light-induced plasmon resonance improves the efficiency of methane conversion by forming an intrinsic high-energy magnetic field that can polarize methane. In methanol conversion, the C―H bond can be selectively activated, instead of the O―H bond, by light irradiation. Therefore, C―C coupling can be realized for the production of various value-added chemicals from methanol. This review summarizes the recent advances in the photocatalytic conversion of methane and methanol including the reactions of reforming, oxidation, and coupling. Perspectives and challenges for further research on the photocatalytic conversion of methane and methanol are also discussed.
- Activation of C―H bond,
- C₁ chemistry,
- Methane,
- Methanol,
- Photocatalysis
1. [1]
  Herrerias, C. I.; Yao, X.; Li, Z.; Li, C. -J. Chem. Rev. 2007, 107, 2546. doi: 10.1021/cr050980b doi: 10.1021/cr050980b
2. [2]
  Singh, M. K.; Akula, H. K.; Satishkumar, S.; Stahl, L.; Lakshman, M. K. ACS Catal. 2016, 6, 1921. doi: 10.1021/acscatal.5b02603 doi: 10.1021/acscatal.5b02603
3. [3]
  Yu, J. -T.; Pan, C. Chem. Commun. 2016, 52, 2220. doi: 10.1039/c5cc08872k doi: 10.1039/c5cc08872k
4. [4]
  Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. Science 2016, 351, 1421. doi: 10.1126/science.aad9289 doi: 10.1126/science.aad9289
5. [5]
  Smith, K. T.; Berritt, S.; Gonzalez-Moreiras, M.; Ahn, S.; Smith, M. R., III; Baik, M. -H.; Mindiola, D. J. Science 2016, 351, 1424. doi: 10.1126/science.aad9730 doi: 10.1126/science.aad9730
6. [6]
  Takamatsu, K.; Hirano, K.; Satoh, T.; Miura, M. J. Org. Chem. 2015, 80, 3242. doi: 10.1021/acs.joc.5b00307 doi: 10.1021/acs.joc.5b00307
7. [7]
  Warratz, S.; Burns, D. J.; Zhu, C.; Korvorapun, K.; Rogge, T.; Scholz, J.; Jooss, C.; Gelman, D.; Ackermann, L. Angew. Chem. Int. Ed. 2017, 56, 1557. doi: 10.1002/anie.201609014 doi: 10.1002/anie.201609014
8. [8]
  Zhang, F. -L.; Hong, K.; Li, T. -J.; Park, H.; Yu, J. -Q. Science 2016, 351, 252. doi: 10.1126/science.aad7893 doi: 10.1126/science.aad7893
9. [9]
  Liao, K.; Negretti, S.; Musaev, D. G.; Bacsa, J.; Davies, H. M. L. Nature 2016, 533, 230. doi: 10.1038/nature17651 doi: 10.1038/nature17651
10. [10]
  Liao, K. B.; Pickel, T. C.; Oyarskikh, V. B.; Acsa, J. B.; Usaev, D. G. M.; Davies, H. M. L. Nature 2017, 551, 609. doi: 10.1038/nature24641 doi: 10.1038/nature24641
11. [11]
  Liao, K.; Yang, Y.-F.; Li, Y.; Sanders, J. N.; Houk, K. N.; Musaev, D. G.; Davies, H. M. L. Nat. Chem. 2018, 551, 609. doi: 10.1038/s41557-018-0087-7 doi: 10.1038/s41557-018-0087-7
12. [12]
  Tzirakis, M. D.; Lykakis, I. N.; Orfanopoulos, M. Chem. Soc. Rev. 2009, 38, 2609. doi: 10.1039/B812100C doi: 10.1039/B812100C
13. [13]
  Zhang, X.; MacMillan, D. W. C. J. Am. Chem. Soc. 2017, 139, 11353. doi: 10.1021/jacs.7b07078 doi: 10.1021/jacs.7b07078
14. [14]
  Capacci, A. G.; Malinowski, J. T.; McAlpine, N. J.; Kuhne, J.; MacMillan, D. W. C. Nat. Chem. 2017, 9, 1073. doi: 10.1038/nchem.2797 doi: 10.1038/nchem.2797
15. [15]
  Maeda, H.; Takayama, H.; Segi, M. Photochem. Photobiol. Sci 2018, 17, 1118. doi: 10.1039/c8pp00239h doi: 10.1039/c8pp00239h
16. [16]
  Jeffrey, J. L.; Terrett, J. A.; MacMillan, D. W. C. Science 2015, 349, 1532. doi: 10.1126/science.aac8555 doi: 10.1126/science.aac8555
17. [17]
  Nicewicz, D. A.; MacMillan, D. W. C. Science 2008, 322, 77. doi: 10.1126/science.1161976 doi: 10.1126/science.1161976
18. [18]
  Shaw, M. H.; Shurtleff, V. W.; Terrett, J. A.; Cuthbertson, J. D.; MacMillan, D. W. C. Science 2016, 352, 1304. doi: 10.1126/science.aaf6635 doi: 10.1126/science.aaf6635
19. [19]
  Zuo, Z.; Ahneman, D. T.; Chu, L.; Terrett, J. A.; Doyle, A. G.; MacMillan, D. W. C. Science 2014, 345, 437. doi: 10.1126/science.1255525 doi: 10.1126/science.1255525
20. [20]
  Xie, S.; Shen, Z.; Deng, J.; Guo, P.; Zhang, Q.; Zhang, H.; Ma, C.; Jiang, Z.; Cheng, J.; Deng, D.; et al. Nat.Commun. 2018, 9, 1181. doi: 10.1038/s41467-018-03543-y doi: 10.1038/s41467-018-03543-y
21. [21]
  Villa, K.; Murcia-López, S.; Morante, J. R.; Andreu, T. Appl. Catal. B 2016, 187, 30. doi: 10.1016/j.apcatb.2016.01.032 doi: 10.1016/j.apcatb.2016.01.032
22. [22]
  Nomikos, G. N.; Panagiotopoulou, P.; Kondarides, D. I.; Verykios, X. E. Appl. Catal. B 2014, 146, 249. doi: 10.1016/j.apcatb.2013.03.018 doi: 10.1016/j.apcatb.2013.03.018
23. [23]
24. [24]
  Hammond, C.; Forde, M. M.; Ab Rahim, M. H.; Thetford, A.; He, Q.; Jenkins, R. L.; Dimitratos, N.; Lopez-Sanchez, J. A.; Dummer, N. F.; Murphy, D. M.; et al. Angew. Chem. Int. Ed. 2012, 51, 5129. doi: 10.1002/anie.201108706 doi: 10.1002/anie.201108706
25. [25]
  Ab Rahim, M. H.; Forde, M. M.; Jenkins, R. L.; Hammond, C.; He, Q.; Dimitratos, N.; Lopez-Sanchez, J. A.; Carley, A. F.; Taylor, S. H.; Willock, D. J.; et al. Angew. Chem. Int. Ed. 2013, 52, 1280. doi: 10.1002/anie.201207717 doi: 10.1002/anie.201207717
26. [26]
  Forde, M. M.; Armstrong, R. D.; Hammond, C.; He, Q.; Jenkins, R. L.; Kondrat, S. A.; Dimitratos, N.; Lopez-Sanchez, J. A.; Taylor, S. H.; Willock, D.; et al. J. Am. Chem. Soc. 2013, 135, 11087. doi: 10.1021/ja403060n doi: 10.1021/ja403060n
27. [27]
  Agarwal, N.; Freakley, S. J.; McVicker, R. U.; Althahban, S. M.; Dimitratos, N.; He, Q.; Morgan, D. J.; Jenkins, R. L.; Willock, D. J.; Taylor, S. H.; et al. Science 2017, 358, 223. doi: 10.1126/science.aan6515 doi: 10.1126/science.aan6515
28. [28]
  Liu, H.; Meng, X.; Dao, T. D.; Zhang, H.; Li, P.; Chang, K.; Wang, T.; Li, M.; Nagao, T.; Ye, J. Angew. Chem. Int. Ed. 2015, 54, 11545. doi: 10.1002/anie.201504933 doi: 10.1002/anie.201504933
29. [29]
  Han, B.; Wei, W.; Chang, L.; Cheng, P.; Hu, Y. H. ACS Catal. 2015, 6, 494. doi: 10.1021/acscatal.5b02653 doi: 10.1021/acscatal.5b02653
30. [30]
  Liu, H.; Meng, X.; Dao, T. D.; Liu, L.; Li, P.; Zhao, G.; Nagao, T.; Yang, L.; Ye, J. J. Mater. Chem. A 2017, 5, 10567. doi: 10.1039/c7ta00704c doi: 10.1039/c7ta00704c
31. [31]
  Pan, F.; Xiang, X.; Deng, W.; Zhao, H.; Feng, X.; Li, Y. ChemCatChem 2018, 10, 940. doi: 10.1002/cctc.201701565 doi: 10.1002/cctc.201701565
32. [32]
  Liu, H.; Dao, T. D.; Liu, L.; Meng, X.; Nagao, T.; Ye, J. Appl. Catal. B 2017, 209, 183. doi: 10.1016/j.apcatb.2017.02.080 doi: 10.1016/j.apcatb.2017.02.080
33. [33]
  Murcia-López, S.; Bacariza, M. C.; Villa, K.; Lopes, J. M.; Henriques, C.; Morante, J. R.; Andreu, T. ACS Catal. 2017, 7, 2878. doi: 10.1021/acscatal.6b03535 doi: 10.1021/acscatal.6b03535
34. [34]
  Sastre, F.; Fornes, V.; Corma, A.; Garcia, H. Chemistry 2012, 18, 1820. doi: 10.1002/chem.201102273 doi: 10.1002/chem.201102273
35. [35]
  Hu, Y.; Anpo, M.; Wei, C. J. Photochem. Photobiol. A 2013, 264, 48. doi: 10.1016/j.jphotochem.2013.05.005 doi: 10.1016/j.jphotochem.2013.05.005
36. [36]
  Li, L.; Fan, S.; Mu, X.; Mi, Z.; Li, C. J. J. Am. Chem. Soc. 2014, 136, 7793. doi: 10.1021/ja5004119 doi: 10.1021/ja5004119
37. [37]
  Meng, L.; Chen, Z.; Ma, Z.; He, S.; Hou, Y.; Li, H.-H.; Yuan, R.; Huang, X.-H.; Wang, X.; Wang, X.; et al. Energ. Environ. Sci. 2018, 11, 294. doi: 10.1039/c7ee02951a doi: 10.1039/c7ee02951a
38. [38]
  Li, L.; Li, G. D.; Yan, C.; Mu, X. Y.; Pan, X. L.; Zou, X. X.; Wang, K. X.; Chen, J. S. Angew. Chem. Int. Ed. 2011, 50, 8299. doi: 10.1002/anie.201102320 doi: 10.1002/anie.201102320
39. [39]
  Li, L.; Cai, Y. Y.; Li, G. D.; Mu, X. Y.; Wang, K. X.; Chen, J. S. Angew. Chem. Int. Ed. 2012, 51, 4702. doi: 10.1002/anie.201200045 doi: 10.1002/anie.201200045
40. [40]
  Li, Z.; Mo, L.; Kathiraser, Y.; Kawi, S. ACS Catal. 2014, 4, 1526. doi: 10.1021/cs401027p doi: 10.1021/cs401027p
41. [41]
  Zhao, Y.; Kang, Y. Q.; Li, H.; Li, H. X. Green Chem. 2018, 20, 2781. doi: 10.1039/c8gc00743h doi: 10.1039/c8gc00743h
42. [42]
  Margossian, T.; Larmier, K.; Kim, S. M.; Krumeich, F.; Fedorov, A.; Chen, P.; Muller, C. R.; Coperet, C. J. Am. Chem. Soc. 2017, 139, 6919. doi: 10.1021/jacs.7b01625 doi: 10.1021/jacs.7b01625
43. [43]
  Zhang, Y. X.; Dragan, A.; Geddes, C. D. J. Phys.Chem. C 2009, 113, 15811. doi: 10.1021/jp900958n doi: 10.1021/jp900958n
44. [44]
  Xiong, Z.; Chen, X.; Wang, X.; Peng, L.; Yan, D.; Lei, H.; Fu, Y.; Wu, J.; Li, Z.; An, X.; et al. Appl. Surf. Sci. 2013, 268, 524. doi: 10.1016/j.apsusc.2012.12.161 doi: 10.1016/j.apsusc.2012.12.161
45. [45]
  Nagli, L.; Gaft, M.; Gornushkin, I.; Glaus, R. Opt. Commun. 2016, 378, 41. doi: 10.1016/j.optcom.2016.05.071 doi: 10.1016/j.optcom.2016.05.071
46. [46]
  Kondratenko, V. A.; Berger-Karin, C.; Kondratenko, E. V. ACS Catal. 2014, 4, 3136. doi: 10.1021/cs5002465 doi: 10.1021/cs5002465
47. [47]
  Park, J. H.; Kwon, Y.-i.; Nam, G. D.; Joo, J. H. J. Mater. Chem. A 2018, 6, 14246. doi: 10.1039/c8ta03021a doi: 10.1039/c8ta03021a
48. [48]
  Zhu, S.; Lian, X.; Fan, T.; Chen, Z.; Dong, Y.; Weng, W.; Yi, X.; Fang, W. Nanoscale 2018, 10, 14031. doi: 10.1039/c8nr02588f doi: 10.1039/c8nr02588f
49. [49]
  Sushkevich, V. L.; Palagin, D.; Ranocchiari, M.; van Bokhoven, J. A. Science 2017, 356, 523. doi: 10.1126/science.aam9035 doi: 10.1126/science.aam9035
50. [50]
  Khan, N. A.; Kennedy, E. M.; Dlugogorski, B. Z.; Adesina, A. A.; Stockenhuber, M. Catal. Commun. 2014, 53, 42. doi: 10.1016/j.catcom.2014.04.012 doi: 10.1016/j.catcom.2014.04.012
51. [51]
  Aslam, M.; Ismail, I. M.; Chandrasekaran, S.; Hameed, A. J. Hazard. Mater. 2014, 276, 120. doi: 10.1016/j.jhazmat.2014.05.022 doi: 10.1016/j.jhazmat.2014.05.022
52. [52]
  Tanaka, A.; Hashimoto, K.; Kominami, H. J. Am. Chem. Soc. 2014, 136, 586. doi: 10.1021/ja410230u doi: 10.1021/ja410230u
53. [53]
  Hameed, A.; Ismail, I. M. I.; Aslam, M.; Gondal, M. A. Appl. Catal. A 2014, 470, 327. doi: 10.1016/j.apcata.2013.10.045 doi: 10.1016/j.apcata.2013.10.045
54. [54]
  Li, R.; Han, H.; Zhang, F.; Wang, D.; Li, C. Energy Environ. Sci. 2014, 7, 1369. doi: 10.1039/c3ee43304h doi: 10.1039/c3ee43304h
55. [55]
  Ohkubo, K.; Hirose, K. Angew. Chem. Int. Ed. 2018, 57, 2126. doi: 10.1002/anie.201710945 doi: 10.1002/anie.201710945
56. [56]
  Keller, G. E.; Bhasin, M. M. J. Catal. 1982, 73, 9. doi: 10.1016/0021-9517[82] 90075-6 doi: 10.1016/0021-9517[82]90075-6
57. [57]
  Brady, C.; Murphy, B.; Xu, B. ACS Catal. 2017, 7, 3924. doi: 10.1021/acscatal.7b00879 doi: 10.1021/acscatal.7b00879
58. [58]
  Liu, Y.; Li, D.; Wang, T.; Liu, Y.; Xu, T.; Zhang, Y. ACS Catal. 2016, 6, 5366. doi: 10.1021/acscatal.6b01362 doi: 10.1021/acscatal.6b01362
59. [59]
  Okolie, C.; Lyu, Y.; Kovarik, L.; Stavitski, E.; Sievers, C. ChemCatChem 2018, 10, 2700. doi: 10.1002/cctc.201701892 doi: 10.1002/cctc.201701892
60. [60]
  Guo, J. J.; Hu, A.; Chen, Y.; Sun, J.; Tang, H.; Zuo, Z. Angew. Chem. Int. Ed. 2016, 55, 15319. doi: 10.1002/anie.201609035 doi: 10.1002/anie.201609035
61. [61]
  Hu, A.; Guo, J. J.; Pan, H.; Tang, H.; Gao, Z.; Zuo, Z. J. Am. Chem. Soc. 2018, 140, 1612. doi: 10.1021/jacs.7b13131 doi: 10.1021/jacs.7b13131
62. [62]
  Hu, A.; Guo, J. -J.; Pan, H.; Zuo, Z. Science 2018, 361, 668. doi: 10.1126/science.aat9750 doi: 10.1126/science.aat9750
63. [63]
  Su, L. -W.; Li, X. -R.; Sun, Z. -Y. Energ. Policy 2013, 63, 130. doi: 10.1016/j.enpol.2013.08.031 doi: 10.1016/j.enpol.2013.08.031
64. [64]
  Chiarello, G. L.; Aguirre, M. H.; Selli, E. J. Catal. 2010, 273, 182. doi: 10.1016/j.jcat.2010.05.012 doi: 10.1016/j.jcat.2010.05.012
65. [65]
  Liu, Z.; Yin, Z.; Cox, C.; Bosman, M.; Qian, X.; Li, N.; Zhao, H.; Du, Y.; Li, J.; Nocera, D. G. Sci. Adv. 2016, 2, e1501425. doi: 10.1126/sciadv.1501425 doi: 10.1126/sciadv.1501425
66. [66]
  Liu, Y.; Yang, S.; Yin, S.-N.; Feng, L.; Zang, Y.; Xue, H. Chem. Eng. J. 2018, 334, 2401. doi: 10.1016/j.cej.2017.12.016 doi: 10.1016/j.cej.2017.12.016
67. [67]
  DePuccio, D. P.; Landry, C. C. Catal. Sci.Technol. 2016, 6, 7512. doi: 10.1039/c6cy01449f doi: 10.1039/c6cy01449f
68. [68]
  Liu, J.; Han, C.; Yang, X.; Gao, G.; Shi, Q.; Tong, M.; Liang, X.; Li, C. J. Catal. 2016, 333, 162. doi: 10.1016/j.jcat.2015.11.005 doi: 10.1016/j.jcat.2015.11.005
69. [69]
  Liang, X.; Yang, X.; Gao, G.; Li, C.; Li, Y.; Zhang, W.; Chen, X.; Zhang, Y.; Zhang, B.; Lei, Y.; et al. J. Catal. 2016, 339, 68. doi: 10.1016/j.jcat.2016.03.033 doi: 10.1016/j.jcat.2016.03.033
70. [70]
  Yang, X.; Zhang, A.; Gao, G.; Han, D.; Han, C.; Wang, J.; Lu, H.; Liu, J.; Tong, M. Catal. Commun. 2014, 43, 192. doi: 10.1016/j.catcom.2013.10.010 doi: 10.1016/j.catcom.2013.10.010
71. [71]
  Han, C. H.; Yang, X. Z.; Gao, G. J.; Wang, J.; Lu, H. L.; Liu, J.; Tong, M.; Liang, X. Y. Green Chem. 2014, 16, 3603. doi: 10.1039/c4gc00367e doi: 10.1039/c4gc00367e
72. [72]
  Fan, Y. H.; Bao, J. X.; Shi, L.; Li, S. G.; Lu, Y. W.; Liu, H. J.; Wang, H.; Zhong, L. S.; Sun, Y. H. Catal. Lett. 2018, 148, 2274. doi: 10.1007/s10562-018-2465-6 doi: 10.1007/s10562-018-2465-6
73. [73]
  Fan, Y.; Li, S.; Bao, J.; Shi, L.; Yang, Y.; Yu, F.; Gao, P.; Wang, H.; Zhong, L.; Sun, Y. Green Chem. 2018, 20, 3450. doi: 10.1039/c8gc00971f doi: 10.1039/c8gc00971f
74. [74]
  Chiarello, G. L.; Ferri, D.; Selli, E. J. Catal. 2011, 280, 168. doi: 10.1016/j.jcat.2011.03.013 doi: 10.1016/j.jcat.2011.03.013
75. [75]
  Highfield, J. G.; Chen, M. H.; Nguyen, P. T.; Chen, Z. Energ. Environ. Sci. 2009, 2. doi: 10.1039/b907781m doi: 10.1039/b907781m
76. [76]
  Naldoni, A.; D'Arienzo, M.; Altomare, M.; Marelli, M.; Scotti, R.; Morazzoni, F.; Selli, E.; Dal Santo, V. Appl. Catal. B 2013, 130-131, 239. doi: 10.1016/j.apcatb.2012.11.006 doi: 10.1016/j.apcatb.2012.11.006
77. [77]
  Guo, Q.; Xu, C.; Ren, Z.; Yang, W.; Ma, Z.; Dai, D.; Fan, H.; Minton, T. K.; Yang, X. J. Am. Chem. Soc. 2012, 134, 13366. doi: 10.1021/ja304049x doi: 10.1021/ja304049x
78. [78]
  Shen, M.; Henderson, M. A. J. Phys.Chem. C 2012, 116, 18788. doi: 10.1021/jp3046774 doi: 10.1021/jp3046774
79. [79]
  Zhang, J.; Peng, C.; Wang, H.; Hu, P. ACS Catal. 2017, 7, 2374. doi: 10.1021/acscatal.6b03348 doi: 10.1021/acscatal.6b03348
80. [80]
  Iwase, Y.; Kobayashi, T.; Inazu, K.; Miyaji, A.; Baba, T. Catal. Lett. 2007, 118, 146. doi: 10.1007/s10562-007-9171-0 doi: 10.1007/s10562-007-9171-0
81. [81]
  Tang, X. C.; Zeng, Z. W.; Jiang, L. H.; Chen, L. A.; Wang, Z. M.; Jia, D. A. Z. Acta Chim. Sin. 2010, 68, 2013.
82. [82]
  Jogunola, O.; Salmi, T.; Kangas, M.; Mikkola, J. P. Chem. Eng. J. 2012, 203, 469. doi: 10.1016/j.cej.2012.06.085 doi: 10.1016/j.cej.2012.06.085
83. [83]
  Lu, Z.; Gao, D.; Yin, H.; Wang, A.; Liu, S. J. Ind. Eng. Chem 2015, 31, 301. doi: 10.1016/j.jiec.2015.07.002 doi: 10.1016/j.jiec.2015.07.002
84. [84]
  Phillips, K. R.; Jensen, S. C.; Baron, M.; Li, S. C.; Friend, C. M. J. Am. Chem. Soc. 2013, 135, 574. doi: 10.1021/ja3106797 doi: 10.1021/ja3106797
85. [85]
  Shen, Z. B.; Xie, S. J.; Fan, W. Q.; Zhang, Q. H.; Xie, Z. K.; Yang, W. M.; Wang, Y. D.; Lin, J. C.; Wu, X. J.; Wan, H. L.; et al. Catal. Sci.Technol. 2016, 6, 6485. doi: 10.1039/c6cy01468b doi: 10.1039/c6cy01468b
86. [86]
  Xie, S. J.; Shen, Z. B.; Zhang, H. M.; Cheng, J.; Zhang, Q. H.; Wang, Y. Catal. Sci. Technol. 2017, 7, 923. doi: 10.1039/c6cy02510b doi: 10.1039/c6cy02510b
87. [87]
  Pospech, J.; Fleischer, I.; Franke, R.; Buchholz, S.; Beller, M. Angew Chem. Int. Ed. 2013, 52, 2852. doi: 10.1002/anie.201208330 doi: 10.1002/anie.201208330
88. [88]
  Chan, L. K. M.; Poole, D. L.; Shen, D.; Healy, M. P.; Donohoe, T. J. Angew. Chem. Int. Ed. 2014, 53, 761. doi: 10.1002/anie.201307950 doi: 10.1002/anie.201307950
89. [89]
  Liu, Z. H.; Yang, Z. Z.; Yu, X. X.; Zhang, H. Y.; Yu, B.; Zhao, Y. F.; Liu, Z. M. Org. Lett. 2017, 19, 5228. doi: 10.1021/acs.orglett.7b02462 doi: 10.1021/acs.orglett.7b02462
90. [90]
  Zhu, C. J.; Zhang, Y. F.; Zhao, H. Q.; Huang, S. J.; Zhang, M.; Su, W. P. Adv. Synth. Catal. 2015, 357, 331. doi: 10.1002/adsc.201500006 doi: 10.1002/adsc.201500006
91. [91]
  Yang, J.; Xie, D.; Zhou, H.; Chen, S.; Duan, J.; Huo, C.; Li, Z. Adv. Synth. Catal. 2018, 360, 3471. doi: 10.1002/adsc.201800467 doi: 10.1002/adsc.201800467
92. [92]
  Griesbeck, A. G.; Reckenthaler, M. Beilstein J. Org. Chem. 2014, 10, 1143. doi: 10.3762/bjoc.10.114 doi: 10.3762/bjoc.10.114
1. [1]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
2. [2]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
3. [3]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
4. [4]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
5. [5]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
6. [6]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
7. [7]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
8. [8]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
9. [9]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
10. [10]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
13. [13]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
14. [14]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
15. [15]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
16. [16]
  Qin Li , Ziyao Jia , Ye Chen , Mingze Ma , Lin Li , Tao Huang . A Journey into the Enigmatic World of Pickering Emulsion: A Chemical Science Popularization Experiment. University Chemistry, 2024, 39(9): 311-318. doi: 10.3866/PKU.DXHX202306035
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
19. [19]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
20. [20]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009

Get Citation

PDF

XML

Metrics

PDF Downloads(90)
Abstract views(2622)
HTML views(941)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142