Citation: WANG Dan, DING Xunlei, LIAO Henglu, DAI Jiayu. Methane Activation on (Au/Ag)₁-Doped Vanadium Oxide Clusters[J]. Acta Physico-Chimica Sinica, ;2019, 35(9): 1005-1013. doi: 10.3866/PKU.WHXB201809006 shu

Methane Activation on (Au/Ag)₁-Doped Vanadium Oxide Clusters

WANG Dan ¹ ,
DING Xunlei ^2,, ,
LIAO Henglu ² ,
DAI Jiayu ^1,,

1.
Department of Physics, College of Arts and Sciences, National University of Defense Technology, Changsha 410073, P. R. China
2.
School of Mathematics and Physics, North China Electric Power University, Beijing 102206, P. R. China

Corresponding author: DING Xunlei, dingxl@ncepu.edu.cn DAI Jiayu, jydai@nudt.edu.cn
Received Date: 4 September 2018
Revised Date: 15 October 2018
Accepted Date: 15 October 2018
Available Online: 18 September 2018
Fund Project: the Science and Technology Project of Hunan Province, China 2017RS3038The project was supported by the National Natural Science Foundation of China (91545122, 11774429), the Science and Technology Project of Hunan Province, China (2017RS3038) and the Fundamental Research Funds for the Central Universities, China (JB2015RCY03)The project was supported by the National Natural Science Foundation of China 91545122The project was supported by the National Natural Science Foundation of China 11774429the Fundamental Research Funds for the Central Universities, China JB2015RCY03

The activation of methane (CH₄) is a key step in its conversion to more valuable products. The activation mechanisms of CH₄ on catalyst surfaces have been widely studied using gas-phase cluster models, which can be operated on systems with a precise number of atoms and determined structures. Herein, we have used MV₃O_y^q (M = Au/Ag, y = 6–8, q = 0 or ±1) clusters, in which a single Au or Ag atom was supported on vanadium oxide clusters, as simple models to mimic the properties of newly developed single-atom catalysts. The adsorption and activation of CH₄ on these MV₃O_y^q clusters were systematically studied via density functional theory calculations at the B3LYP/Def2-TZVP level, which provided insights into the geometric structures, adsorption energies, and charge distributions of the adsorption systems. Five Au-containing clusters, AuV₃O₆, AuV₃O₇, AuV₃O₈, AuV₃O₆⁺, and AuV₃O₇⁺, were able to activate CH₄, while other clusters, including all Ag-containing clusters, were inert. In the active clusters, all Au atoms were adsorbed on the O-atom sites of the supporting V₃O_y^q cluster and served as the active sites for CH₄ activation. The activation of CH₄ was characterized by the lengthened C―H bond (approximately 115 pm), short distances between CH₄ and Au (approximately 184 pm), relatively high adsorption energies of CH₄ (~0.590–1.145 eV), and significant electron transfer from CH₄ to the clusters (above 0.08e). In particular, AuV₃O₈, which is a neutral cluster with a close-shell electronic state, can activate CH₄ with a C―H bond length of 115 pm, Au―H bond length of 183 pm, the adsorption energy of CH₄ of 0.853 eV, and the charge on CH₄ of +0.088e. The charge state of the cluster has a significant effect on the activation ability: cationic clusters are the most active, followed by neutral clusters, while anionic clusters have the lowest activities toward CH₄. Consistently, the local charge on the M atom has a positive correction with the activation ability of MV₃O_y^q clusters with a certain M. However, as compared to Au-containing clusters, Ag-containing clusters have lower activities despite the higher local charges on Ag in each MV₃O_y^q cluster. The results indicate that the inclusion of D3 dispersion correction has a small effect on structures and energies. This study may serve as a foundation for further research on the activation of CH₄ on single-atom catalysts and provides useful information on rational designing of single-atom catalysts for CH₄ conversion at low temperatures.
- Methane activation,
- Metal oxide clusters,
- Noble metal,
- Single-atom catalysis,
- Density functional theory
1. [1]
  Mundhwa, M.; Thurgood, C. P. Fuel Process. Technol. 2017, 168, 27. doi: 10.1016/j.fuproc.2017.08.031 doi: 10.1016/j.fuproc.2017.08.031
2. [2]
  Dang, T. T. H.; Seeburg, D.; Radnik, J.; Kreyenschulte, C.; Atia, H.; Vu, T. T. H.; Wohlrab, S. Catal. Commun. 2018, 103, 56. doi: 10.1016/j.catcom.2017.09.004 doi: 10.1016/j.catcom.2017.09.004
3. [3]
  Burch, R.; Chalker, S.; Loader, P.; Thomas, J. M.; Ueda, W. Appl. Catal. A: Gen. 1992, 82, 77. doi: 10.1016/0926-860X(92)80007-Y doi: 10.1016/0926-860X(92)80007-Y
4. [4]
  Schwarz, H. Angew. Chem. Int. Ed. 2011, 50, 10096. doi: 10.1002/anie.201006424 doi: 10.1002/anie.201006424
5. [5]
  Tang, W.; Hu, Z.; Wang, M.; Stucky, G. D.; Metiu, H.; McFarland, E. W. J. Catal. 2010, 273, 125. doi: 10.1016/j.jcat.2010.05.005 doi: 10.1016/j.jcat.2010.05.005
6. [6]
  Ashcroft, A. T.; Cheetham, A. K.; Green, M. L. H.; Vernon, P. D. F. Nature 1991, 352, 225. doi: 10.1038/352225a0 doi: 10.1038/352225a0
7. [7]
  Enger, B. C.; Lodeng, R.; Holmen, A. Appl. Catal. A: Gen. 2008, 346, 1. doi: 10.1016/j.apcata.2008.05.018 doi: 10.1016/j.apcata.2008.05.018
8. [8]
  Zhu, Q.; Zhao, X.; Deng, Y. J. Nat. Gas Chem. 2004, 13, 191.
9. [9]
  Bawornruttanaboonya, K.; Devahastin, S.; Mujumdar, A. S.; Laosiripojana, N. Int. J. Heat Mass Tran. 2017, 115, 174. doi: 10.1016/j.ijheatmasstransfer.2017.08.027 doi: 10.1016/j.ijheatmasstransfer.2017.08.027
10. [10]
  Chai, R. J.; Zhang, Z. Q.; Chen, P. J.; Zhao, G. F.; Liu, Y.; Lu, Y. Microporous Mesoporous Mat. 2017, 253, 123. doi: 10.1016/j.micromeso.2017.07.005 doi: 10.1016/j.micromeso.2017.07.005
11. [11]
  Cihlar, J.; Vrba, R.; Castkova, K.; Cihlar, J. Int. J. Hydrog. Energy 2017, 42, 19920. doi: 10.1016/j.ijhydene.2017.06.075 doi: 10.1016/j.ijhydene.2017.06.075
12. [12]
  Zavyalova, U.; Holena, M.; Schlögl, R.; Baerns, M. ChemCatChem 2011, 3, 1935. doi: 10.1002/cctc.201100186 doi: 10.1002/cctc.201100186
13. [13]
  Wei, Q. H.; Gao, X. H.; Liu, G. G.; Yang, R. Q.; Zhang, H. B.; Yang, G. H.; Yoneyama, Y.; Tsubaki, N. Fuel 2018, 211, 1. doi: 10.1016/j.fuel.2017.08.093 doi: 10.1016/j.fuel.2017.08.093
14. [14]
  Wang, S.; Gao, D. N.; Zhang, C. X.; Yuan, Z. S.; Zhang, P.; Wang, S. D. Prog. Chem. 2008, 20, 789.
15. [15]
  Gao, J.; Guo, J. Z.; Liang, D.; Hou, Z. Y.; Fei, J. H.; Zheng, X. M. Int. J. Hydrog. Energy 2008, 33, 5493. doi: 10.1016/j.ijhydene.2008.07.040 doi: 10.1016/j.ijhydene.2008.07.040
16. [16]
  Tompos, A.; Margitfalvi, J. L.; Hegedus, M.; Szegedi, A.; Fierro, J. L. G.; Rojas, S. Comb. Chem. High T. Scr. 2007, 10, 71. doi: 10.2174/138620707779802841 doi: 10.2174/138620707779802841
17. [17]
  Launay, H.; Loridant, S.; Nguyen, D. L.; Volodin, A. M.; Dubois, J. L.; Millet, J. M. M. Catal. Today 2007, 128, 176. doi: 10.1016/j.cattod.2007.07.014 doi: 10.1016/j.cattod.2007.07.014
18. [18]
  Wang, X.; Qi, G.; Xu, J.; Li, B.; Wang, C.; Deng, F. Angew. Chem. Int. Ed. 2012, 51, 3850. doi: 10.1002/anie.201108634 doi: 10.1002/anie.201108634
19. [19]
  He, J. L.; Xu, T.; Wang, Z. H.; Zhang, Q. H.; Deng, W. P.; Wang, Y. Angew. Chem. Int. Ed. 2012, 51, 2438. doi: 10.1002/anie.201104071 doi: 10.1002/anie.201104071
20. [20]
  Guo, X.; Fang, G.; Li, G.; Ma, H.; Fan, H.; Yu, L.; Ma, C.; Wu, X.; Deng, D.; Wei, M.; et al. Science 2014, 344, 616. doi: 10.1126/science.1253150 doi: 10.1126/science.1253150
21. [21]
  Schlangen, M.; Schwarz, H. Catal. Lett. 2012, 142, 1265. doi: 10.1007/s10562-012-0892-3 doi: 10.1007/s10562-012-0892-3
22. [22]
  Lang, S. M.; Frank, A.; Bernhardt, T. M. J. Phys. Chem. C 2013, 117, 9791. doi: 10.1021/jp312852r doi: 10.1021/jp312852r
23. [23]
  Zhou, S.; Yue, L.; Schlangen, M.; Schwarz, H. Angew. Chem. Int. Ed. 2017, 56, 14297. doi: 10.1002/anie.201704979 doi: 10.1002/anie.201704979
24. [24]
  Schwarz, H.; Shaik, S.; Li, J. J. Am. Chem. Soc. 2017, 139, 17201. doi: 10.1021/jacs.7b10139 doi: 10.1021/jacs.7b10139
25. [25]
  Ding, X. L.; Wu, X. N.; Zhao, Y. X.; He, S. G. Acc. Chem. Res. 2012, 45, 382. doi: 10.1021/ar2001364 doi: 10.1021/ar2001364
26. [26]
  Zhao, Y. X.; Wu, X. N.; Ma, J. B.; He, S. G.; Ding, X. L. Phys. Chem. Chem. Phys. 2011, 13, 1925. doi: 10.1039/c0cp01171a doi: 10.1039/c0cp01171a
27. [27]
  Ding, X. L.; Zhao, Y. X.; Wu, X. N.; Wang, Z. C.; Ma, J. B.; He, S. G. Chem. Eur. J. 2010, 16, 11463. doi: 10.1002/chem.201001297 doi: 10.1002/chem.201001297
28. [28]
  Wu, X. N.; Ding, X. L.; Li, Z. Y.; Zhao, Y. X.; He, S. G. J. Phys. Chem. C 2014, 118, 24062. doi: 10.1021/jp5059403 doi: 10.1021/jp5059403
29. [29]
  Lang, S. M.; Bernhardt, T. M.; Chernyy, V.; Bakker, J. M.; Barnett, R. N.; Landman, U. Angew. Chem. Int. Ed. 2017, 56, 13406. doi: 10.1002/anie.201706009 doi: 10.1002/anie.201706009
30. [30]
  Qiao, B.; Wang, A.; Yang, X.; Allard, L. F.; Jiang, Z.; Cui, Y.; Liu, J.; Li, J.; Zhang, T. Nat. Chem. 2011, 3, 634. doi: 10.1038/Nchem.1095 doi: 10.1038/Nchem.1095
31. [31]
  Zhou, X.; Shen, Q.; Yuan, K.; Yang, W.; Chen, Q.; Geng, Z.; Zhang, J.; Shao, X.; Chen, W.; Xu, G.; et al. J. Am. Chem. Soc. 2018, 140, 554. doi: 10.1021/jacs.7b10394 doi: 10.1021/jacs.7b10394
32. [32]
  Sun, W.; Shi, R. N.; Wang, X. H.; Liu, S. S.; Han, X. X.; Zhao, C. F.; Li, Z.; Ren, J. Appl. Surf. Sci. 2017, 425, 291. doi: 10.1016/j.apsusc.2017.07.002 doi: 10.1016/j.apsusc.2017.07.002
33. [33]
  Yuan, J.; Zhang, W.; Li, X.; Yang, J. Chem. Commun. 2018, 54, 2284. doi: 10.1039/c7cc08713f doi: 10.1039/c7cc08713f
34. [34]
  Wu, X. N.; Li, X. N.; Ding, X. L.; He, S. G.Angew. Chem. Int. Ed. 2013, 52, 2444. doi: 10.1002/anie.201207016 doi: 10.1002/anie.201207016
35. [35]
  Ding, X. L.; Wang, D.; Li, R. J.; Liao, H. L.; Zhang, Y.; Zhang, H. Y. Phys. Chem. Chem. Phys.2016, 18, 9497. doi: 10.1039/c6cp00808a doi: 10.1039/c6cp00808a
36. [36]
  Ding, X. L.; Li, Z. Y.; Meng, J. H.; Zhao, Y. X.; He, S. G. J. Chem. Phys.2012, 137, 214311. doi: 10.1063/1.4769282 doi: 10.1063/1.4769282
37. [37]
  Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98, 11623. doi: 10.1021/j100096a001 doi: 10.1021/j100096a001
38. [38]
  Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; et al., Gaussian 09, Revision D.01; Gaussian, Inc.: Wallingford CT, 2009.
39. [39]
  Asmis, K. R.; Wende, T.; Brummer, M.; Gause, O.; Santambrogio, G.; Stanca-Kaposta, E. C.; Dobler, J.; Niedziela, A.; Sauer, J. Phys. Chem. Chem. Phys. 2012, 14, 9377. doi: 10.1039/C2cp40245a doi: 10.1039/C2cp40245a
40. [40]
  Asmis, K. R.; Sauer, J. Mass Spectrom. Rev. 2007, 26, 542. doi: 10.1002/mas.20136 doi: 10.1002/mas.20136
41. [41]
  Santambrogio, G.; Brümmer, M.; Wöste, L.; Döbler, J.; Sierka, M.; Sauer, J.; Meijer, G.; Asmis, K. R. Phys. Chem. Chem. Phys. 2008, 10, 3992. doi: 10.1039/b803492c doi: 10.1039/b803492c
42. [42]
  Fielicke, A.; Mitrić, R.; Meijer, G.; Bonačić-Koutecký, V.; von Helden, G. J. Am. Chem. Soc. 2003, 125, 15716. doi: 10.1021/ja036264d doi: 10.1021/ja036264d
43. [43]
  Bell, R. C.; Zemski, K. A.; Justes, D. R.; Castleman, A. W., Jr. J. Chem. Phys. 2001, 114, 798. doi: 10.1063/1.1329643 doi: 10.1063/1.1329643
44. [44]
  Zhang, X. H.; Schwarz, H. Chem. Eur. J. 2010, 16, 1163. doi: 10.1002/chem.200902810 doi: 10.1002/chem.200902810
45. [45]
  Rozanska, X.; Fortrie, R.; Sauer, J. J. Phys. Chem. C 2007, 111, 6041. doi: 10.1021/jp071409e doi: 10.1021/jp071409e
46. [46]
  Döbler, J.; Pritzsche, M.; Sauer, J. J. Phys. Chem. C 2009, 113, 12454. doi: 10.1021/jp901774t doi: 10.1021/jp901774t
47. [47]
  Ding, X. L.; Xue, W.; Ma, Y. P.; Zhao, Y. X.; Wu, X. N.; He, S. G. J. Phys. Chem. C 2010, 114, 3161. doi: 10.1021/jp9112415 doi: 10.1021/jp9112415
48. [48]
  Ma, J. B.; Wu, X. N.; Zhao, Y. X.; Ding, X. L.; He, S. G. Phys. Chem. Chem. Phys. 2010, 12, 12223. doi: 10.1039/C0CP00360C doi: 10.1039/C0CP00360C
49. [49]
  Ma, J. B.; Meng, J. H.; He, S. G. Dalton Trans. 2015, 44, 3128. doi: 10.1039/c4dt03398a doi: 10.1039/c4dt03398a
50. [50]
  Ma, J. B.; Wu, X. N.; Zhao, Y. X.; He, S. G.; Ding, X. L. Acta Phys. -Chim. Sin. 2010, 26, 1761. doi: 10.3866/pku.whxb20100737
51. [51]
  Weigend, F.; Ahlrichs, R. Phys. Chem. Chem. Phys. 2005, 7, 3297. doi: 10.1039/b508541a doi: 10.1039/b508541a
52. [52]
  Zhao, Y. X.; Ding, X. L.; Ma, Y. P.; Wang, Z. C.; He, S. G. Theor. Chem. Acc. 2010, 127, 449. doi: 10.1007/s00214-010-0732-8 doi: 10.1007/s00214-010-0732-8
53. [53]
  Grimme, S. WIREs Comput. Mol. Sci. 2011, 1, 211. doi: 10.1002/wcms.30 doi: 10.1002/wcms.30
54. [54]
  Goerigk, L.; Grimme, S. Phys. Chem. Chem. Phys. 2011, 13, 6670. doi: 10.1039/C0cp02984j doi: 10.1039/C0cp02984j
55. [55]
  Lu, T.; Chen, F. J. Mol. Model. 2013, 19, 5387. doi: 10.1007/s00894-013-2034-2 doi: 10.1007/s00894-013-2034-2
56. [56]
  Grimme, S.; Ehrlich, S.; Goerigk, L. J. Comput. Chem. 2011, 32, 1456. doi: 10.1002/jcc.21759 doi: 10.1002/jcc.21759
1. [1]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
2. [2]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
3. [3]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
4. [4]
  Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, 2025, 40(3): 62-67. doi: 10.12461/PKU.DXHX202404045
5. [5]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
6. [6]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
7. [7]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
8. [8]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
9. [9]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
10. [10]
  Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, 2025, 40(3): 148-152. doi: 10.12461/PKU.DXHX202405166
11. [11]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
12. [12]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
13. [13]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
14. [14]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
15. [15]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
16. [16]
  Tingting XU , Wenjing ZHANG , Yongbo SONG . Research advances of atomic precision coinage metal nanoclusters in tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2275-2285. doi: 10.11862/CJIC.20240229
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
19. [19]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
20. [20]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(522)
HTML views(109)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Methane Activation on (Au/Ag)1-Doped Vanadium Oxide Clusters

Metrics

通讯作者: 陈斌, bchen63@163.com

Methane Activation on (Au/Ag)₁-Doped Vanadium Oxide Clusters