Citation: LUO Pan, SUN Fang, DENG Ju, XU Haitao, ZHANG Huijuan, WANG Yu. Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction[J]. Acta Physico-Chimica Sinica, ;2018, 34(12): 1397-1404. doi: 10.3866/PKU.WHXB201804022 shu

Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction

The State Key Laboratory of Power Transmission Equipment and System Security, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China

Corresponding author: ZHANG Huijuan, zhanghj@cqu.edu.cn WANG Yu, wangy@cqu.edu.cn
Received Date: 8 March 2018
Revised Date: 27 March 2018
Accepted Date: 29 March 2018
Available Online: 2 December 2018
Fund Project: the National Natural Science Foundation of China 21373280The project was supported by the Fundamental Research Funds for the Central Universities, China (0301005202017), the Thousand Young Talents Program of the Chinese Central Government (0220002102003), the National Natural Science Foundation of China (21373280, 21403019), the Beijing National Laboratory for Molecular Sciences, China, the Hundred Talents Program at Chongqing University, China (0903005203205), and the State Key Laboratory of Mechanical Transmissions Project, China (SKLMT-ZZKT-2017M11)the Fundamental Research Funds for the Central Universities, China 0301005202017the State Key Laboratory of Mechanical Transmissions Project, China SKLMT-ZZKT-2017M11the Thousand Young Talents Program of the Chinese Central Government 0220002102003the Hundred Talents Program at Chongqing University, China 0903005203205the National Natural Science Foundation of China 21403019

In the past decade, fossil fuel resources have been exploited and utilized extensively, which could lead to increasing environmental crises, like greenhouse effect, water pollution, etc. Accordingly, many coping strategies have been put forward, such as water electrolysis, metal-air batteries, fuel cell, etc. Among the strategies mentioned above, water electrolysis is one of the most promising. Water splitting, which can achieve sustainable hydrogen production, is a favorable strategy due to the abundance of water resources. Splitting of water includes two half reactions integral to its operation: hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). However, its practical application is mainly impeded by the sluggish anode reaction. Simultaneously, noble metal oxides (IrO₂ and RuO₂) and Pt-based catalysts have been recognized as typical OER catalysts; however, the scarcity of noble metals greatly limits their development. Hence, designing an alternative electrocatalyst plays a vital role in the development of OER. However, exploring a highly active electrocatalyst for OER is still difficult. Herein, a miraculous construction of a tree-like array of NiS/Ni₃S₂ heterostructure, which is directly grown on Ni foam substrate, is synthesized via one-step hydrothermal process. Since NiS and Ni₃S₂ have shown great OER performance in previous investigations, this novel NiS-Ni₃S₂/Nikel foam (NF) heterostructure array has tremendous potential as a practical OER catalyst. Upon application in OER, the NiS-Ni₃S₂/NF heterostructure array catalyst exhibits excellent activity and stability. More specifically, this novel tree-like NiS-Ni₃S₂ heterostructure array shows extremely low overpotential (269 mV to achieve a current density of 10 mA·cm^-2) and small Tafel slope for OER. It also shows extraordinary stability in alkaline electrolytes. Compared with the Ni₃S₂ nanorods array, the NiS-Ni₃S₂ heterostructure array has a synergistic effect that can improve the OER performance. Due to the secondary structure (Ni₃S₂ nanosheets), the tree-like NiS-Ni₃S₂ array provides more active sites could have higher specific surface area. The greater activity of the NiS/Ni₃S₂ heterostructure may also stem from the tight conjunction between tree-like NiS/Ni₃S₂ and the Ni foam substrate, which is beneficial for electronic transmission. Hydroxy groups can accumulate in large amounts on the surface of the tree-like array, and it also generates some Ni-based oxides that are favorable to OER. Moreover, the synergistic effect of such heterostructure can intrinsically improve the OER activity. The unique tree-like NiS-Ni₃S₂ heterostructure array has great potential as an alternative OER electrocatalyst.
- Heterostructure,
- Tree-like array,
- NiS-Ni₃S₂,
- Oxygen evolution reaction
1. [1]
  Wang, F.; Shifa, T. A.; Zhan, X.; Huang, Y.; Liu, K.; Cheng, Z.; Jiang, C.; He, J. Nanoscale 2015, 7 (47), 19764. doi: 10.1039/c5nr06718a doi: 10.1039/c5nr06718a
2. [2]
  Yan, Y.; Xia, B. Y.; Zhao, B.; Wang, X. J. Mater. Chem. A 2016, 4 (45), 17587. doi: 10.1039/c6ta08075h doi: 10.1039/c6ta08075h
3. [3]
  Gao, M. R.; Xu, Y. F.; Jiang, J.; Yu, S. H. Chem. Soc. Rev. 2013, 42 (7), 2986. doi: 10.1039/C2CS35310e doi: 10.1039/C2CS35310e
4. [4]
  Zhou, W.; Wu, X. J.; Cao, X.; Huang, X.; Tan, C.; Tian, J.; Liu, H.; Wang, J.; Zhang, H. Energy Environ. Sci. 2013, 6 (10), 2921. doi: 10.1039/c3ee41572d doi: 10.1039/c3ee41572d
5. [5]
  Dou, Y. H.; Liao, T.; Ma, Z. Q.; Tian, D. L.; Liu, Q. N.; Xiao, F.; Sun, Z. Q.; Kim, J. H.; Dou, S. X. Nano Energy 2016, 30, 267. doi: 10.1016/j.nanoen.2016.10.020 doi: 10.1016/j.nanoen.2016.10.020
6. [6]
  Jin, C.; Lu, F. L.; Cao, X. C.; Yang, Z. R.; Yang, R. Z. J. Mater. Chem. A 2013, 1 (39), 12170. doi: 10.1039/c3ta12118f doi: 10.1039/c3ta12118f
7. [7]
  Cheng, N.; Liu, Q.; Tian, J.; Sun, X.; He, Y.; Zhai, S.; Asiri, A. M. Int. J. Hydrog. Energy 2015, 40 (32), 9866. doi: 10.1016/j.ijhydene.2015.06.105 doi: 10.1016/j.ijhydene.2015.06.105
8. [8]
  Dong, B.; Zhao, X.; Han, G. Q.; Li, X.; Shang, X.; Liu, Y. R.; Hu, W. H.; Chai, Y. M.; Zhao, H.; Liu, C. G. J. Mater. Chem. A 2016, 4 (35), 13499. doi: : 10.1039/c6ta03177c doi: 10.1039/C6TA03177C
9. [9]
  Liang, H.; Meng, F.; Cabán-Acevedo, M.; Li, L.; Forticaux, A.; Xiu, L.; Wang, Z.; Jin, S. Nano Lett. 2015, 15 (2), 1421. doi: 10.1021/nl504872s doi: 10.1021/nl504872s
10. [10]
  Gao, M. R.; Cao, X.; Gao, Q.; Xu, Y. F.; Zheng, Y. R.; Jiang, J.; Yu, S. H. ACS Nano 2014, 8 (4), 3970. doi: 10.1021/nn500880v doi: 10.1021/nn500880v
11. [11]
  Swesi, A. T.; Masud, J.; Nath, M. Energy Environ. Sci. 2016, 9 (5), 1771. doi: 10.1039/c5ee02463c doi: 10.1039/c5ee02463c
12. [12]
  Chen, J. S.; Ren, J.; Shalom, M.; Fellinger, T.; Antonietti, M. ACS Appl. Mater. Interfaces 2016, 8 (8), 5509. doi: 10.1021/acsami.5b10099 doi: 10.1021/acsami.5b10099
13. [13]
  Chen, P. Z.; Xu, K.; Tong, Y.; Li, X. L.; Tao, S.; Fang, Z. W.; Chu, W. S.; Wu, X. J.; Wu, C. Z. Inorg. Chem. Front. 2016, 3 (2), 236. doi: 10.1039/C5QI00197H doi: 10.1039/C5QI00197H
14. [14]
  Yang, L.; Gao, M. G.; Dai, B.; Guo, X. H.; Liu, Z. Y.; Peng, B. H. Electrochim. Acta 2016, 191, 813. doi: 10.1016/j.electacta.2016.01.160 doi: 10.1016/j.electacta.2016.01.160
15. [15]
  Li, T. T.; Zuo, Y. P.; Lei, X. M.; Li, N.; Liu, J. W.; Han, H. Y. J. Mater. Chem. A 2016, 4 (21), 8029. doi: 10.1039/C6TA01547F doi: 10.1039/C6TA01547F
16. [16]
  Zhang, Z.; Zhao, H.; Xia, Q.; Allen, J.; Zeng, Z.; Gao, C.; Li, Z.; Du, X.; Świerczek, K. Electrochim. Acta 2016, 211, 761. doi: 10.1016/j.electacta.2016.06.103 doi: 10.1016/j.electacta.2016.06.103
17. [17]
  Feng, L. L.; Yu, G.; Wu, Y.; Li, G. D.; Li, H.; Sun, Y.; Asefa, T.; Chen, W.; Zou, X. J. Am. Chem. Soc. 2015, 137 (44), 14023. doi: 10.1021/jacs.5b08186 doi: 10.1021/jacs.5b08186
18. [18]
  Zhou, X.; Liu, Y.; Ju, H.; Pan, B.; Zhu, J.; Ding, T.; Wang, C.; Yang, Q. Chem. Mater. 2016, 28 (6), 1838. doi: 10.1021/acs.chemmater.5b05006 doi: 10.1021/acs.chemmater.5b05006
19. [19]
  Zhang, J.; Wang, T.; Pohl, D.; Rellinghaus, B.; Dong, R.; Liu, S.; Zhuang, X.; Feng, X. Angew. Chem. Int. Ed. 2016, 55 (23), 6702. doi: 10.1002/anie.201602237 doi: 10.1002/anie.201602237
20. [20]
  Duan, X. D.; Wang, C.; Shaw, J. C.; Cheng, R.; Chen, Y.; Li, H. L.; Wu, X. P.; Tang, Y.; Zhang, Q. L.; Pan, A. L.; et al. Nat. Nanotechnol. 2014, 9 (12), 1024. doi: 10.1038/nnano.2014.222 doi: 10.1038/nnano.2014.222
21. [21]
  Lee, D. K.; Ahn, C. W.; Jeon, H. J. Microelectron. Eng. 2016, 166, 1. doi: 10.1016/j.mee.2016.09.003 doi: 10.1016/j.mee.2016.09.003
22. [22]
  Zhao, Y.; Zhang, Y.; Zhao, H.; Li, X.; Li, Y.; Wen, L.; Yan, Z.; Huo, Z. Nano Res. 2015, 8 (8), 2763. doi: 10.1007/s12274-015-0783-1 doi: 10.1007/s12274-015-0783-1
23. [23]
  Jeong, Y. U.; Manthiram, A. Inorg. Chem. 2001, 40 (1), 73. doi: 10.1021/ic000819d doi: 10.1021/ic000819d
24. [24]
  Huang, S.; Harris, K. D.; Lopez-Capel, E.; Manning, D. A.; Rickard, D. Inorg. Chem. 2009, 48 (24), 11486. doi: 10.1021/ic901512z doi: 10.1021/ic901512z
25. [25]
  Zheng, J.; Zhou, W.; Liu, T.; Liu, S.; Wang, C.; Guo, L. Nanoscale 2017, 9 (13), 4409. doi: 10.1039/c6nr07953a doi: 10.1039/c6nr07953a
26. [26]
  Xu, K.; Chen, P.; Li, X.; Tong, Y.; Ding, H.; Wu, X.; Chu, W.; Peng, Z.; Wu, C.; Xie, Y. J. Am. Chem. Soc. 2015, 137 (12), 4119. doi: 10.1021/ja5119495 doi: 10.1021/ja5119495
27. [27]
  Zhu, T.; Zhu, L. L.; Wang, J.; Ho, G. W. J. Mater. Chem. A 2016, 4 (36), 13916. doi: 10.1039/c6ta05618k doi: 10.1039/c6ta05618k
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Tree-Like NiS-Ni3S2/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction

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Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction