Citation: YUAN Jun, LIU Ye, ZHU Can, SHEN Ping, WAN Meixiu, FENG Liuliu, ZOU Yingping. Asymmetric Quinoxaline-Based Polymer for High Efficiency Non-Fullerene Solar Cells[J]. Acta Physico-Chimica Sinica, ;2018, 34(11): 1272-1278. doi: 10.3866/PKU.WHXB201803221 shu

Asymmetric Quinoxaline-Based Polymer for High Efficiency Non-Fullerene Solar Cells

YUAN Jun ¹ ,
LIU Ye ¹ ,
ZHU Can ¹ ,
SHEN Ping ² ,
WAN Meixiu ³ ,
FENG Liuliu ¹ ,
ZOU Yingping ^1,,

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China
2.
College of Chemistry, Xiangtan University, Xiangtan 411105, Hunan Province, P. R. China
3.
Institute of New Energy Technology, College of Information and Technology, Jinan University, Guangzhou 510632, P. R. China

Corresponding author: ZOU Yingping, yingpingzou@csu.edu.cn
Received Date: 22 February 2018
Revised Date: 19 March 2018
Accepted Date: 20 March 2018
Available Online: 22 November 2018
Fund Project: The project was supported by the National Natural Science Foundation of China (51673205, 51173206) and the Science Fund for Distinguished Young Scholars of Hunan Province, China (2017JJ1029)the Science Fund for Distinguished Young Scholars of Hunan Province, China 2017JJ1029the National Natural Science Foundation of China 51173206the National Natural Science Foundation of China 51673205

Polymer solar cells (PSCs) with bulk heterojunction (BHJ) structures have seen rapid development in recent years. In comparison with their inorganic counterparts, PSCs have some advantages such as low cost, light weight, solution processability, and good mechanical flexibility. However, improvement of the power conversion efficiency (PCE) of PSCs is required for commercial applications. In order to achieve high-performance PSCs, active layers, including donor polymers and acceptors, are very important. Several design principles for conjugated donor polymers in PSCs have emerged, including optimization of the conjugated backbone, side-chains, and substituents. In the past few decades, various classes of electron-donating polymers have been reported for PSCs. Among them, quinoxaline (Qx) is a unique building block for the construction of different optoelectronic polymers because of its planar, rigid, and conjugated structure. Qx derivatives have proven interesting and have been widely employed in many fields. Qx-based conjugated polymers (or small molecules) can be easily modified to match with ball-like fullerene derivatives such as PCBM ([6, 6]-phenyl-C₆₁ or C₇₁-butyric acid methyl ester) or weak crystalline non-fullerene acceptors such as 2, 2'-[[6, 6, 12, 12-tetrakis(4-hexylphenyl)-6, 12, -dihydrodithieno[2, 3-d:2', 3'-d']-s-indaceno[1, 2-b:5, 6-b']dithiophene-2, 8-diyl]bis[methylidyne(3-oxo-1H-indene-2, 1(3H)-diylidene)]]bispropanedinitrile (ITIC). Herein, we synthesized a Qx-based polymer with asymmetric side-chains (TPQ-1). The molecular weight, optical properties, molecular energy levels, and mobilities of TPQ-1 were investigated. Furthermore, the blend morphologies and photovoltaic properties of TPQ-1 using a strong crystalline non-fullerene (NF) acceptor (o-IDTBR) were systematically explored. The photovoltaic performance of TPQ-1 and its symmetric side-chain counterpart, HFQx-T, was compared. The introduction of asymmetric side-chains led to a favorable phase separation when blended with o-IDTBR. As expected, the TPQ-1:o-IDTBR-based devices exhibited a high PCE of 8.6% after thermal annealing (TA). In contrast, the HFQx-T:o-IDTBR-based devices showed a moderate PCE of 5.7%, moreover, the PCE was decreased to 4.6% after TA treatment. More importantly, a low bandgap material, PTB7-Th, was specifically selected as a third component to mix with the TPQ-1:o-IDTBR blend to form highly-efficient ternary PSCs. At an optimal weight ratio (15%) of PTB7-Th addition, a PCE of 9.6% was achieved. In the systems that were investigated, TPQ-1 demonstrated significantly better photovoltaic properties than the HFQx-T-based devices. These results indicate that Qx-based polymers with asymmetric side chains have a bright future in photovoltaic devices.
- Non-fullerene solar cells,
- Asymmetric side chain,
- Quinoxaline based polymer,
- Phase separation
1. [1]
  Li, Y. Acc. Chem. Res. 2012, 45, 723. doi: 10.1021/ar2002446 doi: 10.1021/ar2002446
2. [2]
  Lu, L.; Zheng, T.; Wu, Q.; Schneider, A. M.; Zhao, D.; Yu, L. Chem. Rev.2015, 115, 12666. doi: 10.1021/acs.chemrev.5b00098 doi: 10.1021/acs.chemrev.5b00098
3. [3]
  Li, G.; Shrotriya, V.; Huang, J.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y. Nat. Mater. 2005, 4, 864. doi: 10.1038/nmat1500 doi: 10.1038/nmat1500
4. [4]
  Zhou, H.; Yang, L.; You, W. Macromolecules 2012, 45, 607. doi: 10.1021/ma201648t doi: 10.1021/ma201648t
5. [5]
  Lai, Y. Y.; Cheng, Y. J.; Hsu, C. S. Energy Environ. Sci. 2014, 7, 1866. doi: 10.1039/C3EE43080D doi: 10.1039/C3EE43080D
6. [6]
  Günes, S.; Neugebauer, H.; Sariciftci, N. S. Chem. Rev. 2007, 107, 1324. doi: 10.1021/cr050149z doi: 10.1021/cr050149z
7. [7]
  Fu, Y.; Wang, F.; Zhang, Y.; Fang, X.; Lai, W.; Huang, W. Acta Chim. Sin. 2014, 72, 158. doi: 10.6023/A13111142 doi: 10.6023/A13111142
8. [8]
  Xiao, Z.; Jia, X.; Ding, L. Sci. Bull. 2017, 62, 1562. doi: 10.1016/j.scib.2017.11.003 doi: 10.1016/j.scib.2017.11.003
9. [9]
  Dou, C.; Liu, J.; Wang, L. Sci. China Chem. 2017, 60, 450. doi: 10.1007/s11426-016-0503-x doi: 10.1007/s11426-016-0503-x
10. [10]
  Deng, D.; Zhang, Y.; Zhang, J.; Wang, Z.; Zhu, L.; Fang, J.; Xia, B.; Wang, Z.; Lu, K.; Ma, W.; et al. Nat. Commun. 2016, 7, 13740. doi: 10.1038/ncomms13740 doi: 10.1038/ncomms13740
11. [11]
  Zhao, W.; Li, S.; Yao, H.; Zhang, S.; Zhang, Y.; Yang, B.; Hou, J. J. Am. Chem. Soc.2017, 139, 7148. doi: 10.1021/jacs.7b02677 doi: 10.1021/jacs.7b02677
12. [12]
  Wu, Q.; Zhao, D.; Schneider, A. M.; Chen, W.; Yu, L. J. Am. Chem. Soc. 2016, 138, 7248. doi: 10.1021/jacs.6b03562 doi: 10.1021/jacs.6b03562
13. [13]
  Meng, D.; Fu, H.; Xiao, C.; Meng, X.; Winands, T.; Ma, W.; Wei, W.; Fan, B.; Huo, L.; Doltsinis, N. L.; et al. J. Am. Chem. Soc. 2016, 138, 10184. doi: 10.1021/jacs.6b04368 doi: 10.1021/jacs.6b04368
14. [14]
  Liu, Y.; Zhang, Z.; Feng, S.; Li, M.; Wu, L.; Hou, R.; Xu, X.; Chen, X.; Bo, Z. J. Am. Chem. Soc. 2017, 139, 3356. doi: 10.1021/jacs.7b00566 doi: 10.1021/jacs.7b00566
15. [15]
  Lin, Y.; Zhao, F.; He, Q.; Huo, L.; Wu, Y.; Parker, T. C.; Ma, W.; Sun, Y.; Wang, C.; Zhu, D.; et al. J. Am. Chem. Soc. 2016, 138, 4955. doi: 10.1021/jacs.6b02004 doi: 10.1021/jacs.6b02004
16. [16]
  Li, Y.; Lin, J. D.; Che, X.; Qu, Y.; Liu, F.; Liao, L. S.; Forrest, S. R. J. Am. Chem. Soc. 2017, 139, 17114. doi: 10.1021/jacs.7b11278 doi: 10.1021/jacs.7b11278
17. [17]
  Kan, B.; Feng, H.; Wan, X.; Liu, F.; Ke, X.; Wang, Y.; Wang, Y.; Zhang, H.; Li, C.; Hou, J.; et al. J. Am. Chem. Soc. 2017, 139, 4929. doi: 10.1021/jacs.7b01170 doi: 10.1021/jacs.7b01170
18. [18]
  Liu, Y.; Liu, J.; Zhang, L.; Fang, J.; Zhang, W.; Liu, Z. Chin. J. Org. Chem. 2014, 34, 1021. doi: 10.6023/cjoc201311041 doi: 10.6023/cjoc201311041
19. [19]
  Ma, Y.; Zhang, M.; Tang, Y.; Ma, W.; Zheng, Q. Chem. Mater. 2017, 29, 9775. doi: 10.1021/acs.chemmater.7b03770 doi: 10.1021/acs.chemmater.7b03770
20. [20]
  Park, G. E.; Choi, S.; Park, S. Y.; Lee, D. H.; Cho, M. J.; Choi, D. H. Adv. Energy Mater. 2017, 7, 1700566.doi: 10.1002/aenm.201700566 doi: 10.1002/aenm.201700566
21. [21]
  Zhang, K.; Gao, K.; Xia, R.; Wu, Z.; Sun, C.; Cao, J.; Qian, L.; Li, W.; Liu, S.; Huang, F.; et al. Adv. Mater. 2016, 28, 4817. doi: 10.1002/adma.201506270 doi: 10.1002/adma.201506270
22. [22]
  Zhang, G.; Yang, G.; Yan, H.; Kim, J. H.; Ade, H.; Wu, W.; Xu, X.; Duan, Y.; Peng, Q. Adv. Mater. 2017, 29, 1606054. doi: 10.1002/adma.201606054 doi: 10.1002/adma.201606054
23. [23]
  Xu, S. J.; Zhou, Z.; Liu, W.; Zhang, Z.; Liu, F.; Yan, H.; Zhu, X. Adv. Mater. 2017, 29, 1704510. doi: 10.1002/adma.201704510 doi: 10.1002/adma.201704510
24. [24]
  Lin, Y.; Zhao, F.; Wu, Y.; Chen, K.; Xia, Y.; Li, G.; Prasad, S. K.; Zhu, J.; Huo, L.; Bin, H.; et al. Adv. Mater. 2017, 29, 1604155. doi: 10.1002/adma.201604155 doi: 10.1002/adma.201604155
25. [25]
  Cheng, P.; Wang, R.; Zhu, J.; Huang, W.; Chang, S. Y.; Meng, L.; Sun, P.; Cheng, H. W.; Qin, M.; Zhu, C.; et al. Adv. Mater. 2018, 30, 1705243. doi: 10.1002/adma.201705243 doi: 10.1002/adma.201705243
26. [26]
  Fei, Z.; Eisner, F. D.; Jiao, X.; Azzouzi, M.; Rohr, J. A.; Han, Y.; Shahid, M.; Chesman, A. S. R.; Easton, C. D.; McNeill, C. R.; et al. Adv. Mater. 2018, 30, 1705209. doi: 10.1002/adma.201705209 doi: 10.1002/adma.201705209
27. [27]
  Huang, W.; Cheng, P.; Yang, Y. M.; Li, G.; Yang, Y. Adv. Mater. 2018, 30, 1705706. doi: 10.1002/adma.201705706 doi: 10.1002/adma.201705706
28. [28]
  Liu, D.; Wang, J.; Gu, C.; Li, Y.; Bao, X.; Yang, R. Adv. Mater. 2018, 30, 1705870. doi: 10.1002/adma.201705870 doi: 10.1002/adma.201705870
29. [29]
  Luo, Z.; Bin, H.; Liu, T.; Zhang, Z. G.; Yang, Y.; Zhong, C.; Qiu, B.; Li, G.; Gao, W.; Xie, D.; et al. Adv. Mater. 2018, 30, 1706124. doi: 10.1002/adma.201706124 doi: 10.1002/adma.201706124
30. [30]
  Zhu, J.; Ke, Z.; Zhang, Q.; Wang, J.; Dai, S.; Wu, Y.; Xu, Y.; Lin, Y.; Ma, W.; You, W.; et al. Adv. Mater. 2018, 30, 1704713. doi: 10.1002/adma.201704713 doi: 10.1002/adma.201704713
31. [31]
  Qiu, B.; Xue, L.; Yang, Y.; Bin, H.; Zhang, Y.; Zhang, C.; Xiao, M.; Park, K.; Morrison, W.; Zhang, Z. G.; et al. Chem. Mater. 2017, 29, 7543. doi: 10.1021/acs.chemmater.7b02536 doi: 10.1021/acs.chemmater.7b02536
32. [32]
  Feng, G.; Li, J.; Colberts, F. J. M.; Li, M.; Zhang, J.; Yang, F.; Jin, Y.; Zhang, F.; Janssen, R. A. J.; Li, C.; et al. J. Am. Chem. Soc. 2017, 139, 18647. doi: 10.1021/jacs.7b10499 doi: 10.1021/jacs.7b10499
33. [33]
  Yao, Z.; Liao, X.; Gao, K.; Lin, F.; Xu, X.; Shi, X.; Zuo, L.; Liu, F.; Chen, Y.; Jen, A. K. J. Am. Chem. Soc. 2018, 140, 2054. doi: 10.1021/jacs.7b13239 doi: 10.1021/jacs.7b13239
34. [34]
  Fan, B.; Ying, L.; Wang, Z.; He, B.; Jiang, X. F.; Huang, F.; Cao, Y. Energy Environ. Sci. 2017, 10, 1243. doi: 10.1039/C7EE00619E doi: 10.1039/C7EE00619E
35. [35]
  Zhang, X.; Zhan, C.; Yao, J. Chem. Mater. 2015, 27, 166. doi: 10.1021/cm504140c doi: 10.1021/cm504140c
36. [36]
  Guo, B.; Li, W.; Guo, X.; Meng, X.; Ma, W.; Zhang, M.; Li, Y. Adv. Mater. 2017, 29, 1702291. doi: 10.1002/adma.201702291 doi: 10.1002/adma.201702291
37. [37]
  Duan, Y.; Xu, X.; Yan, H.; Wu, W.; Li, Z.; Peng, Q. Adv. Mater. 2017, 29, 1605115. doi: 10.1002/adma.201605115 doi: 10.1002/adma.201605115
38. [38]
  Lin, Y.; Wang, J.; Zhang, Z. G.; Bai, H.; Li, Y.; Zhu, D.; Zhan, X. Adv. Mater. 2015, 27, 1170. doi: 10.1002/adma.201404317 doi: 10.1002/adma.201404317
39. [39]
  Bin, H.; Zhang, Z. G.; Gao, L.; Chen, S.; Zhong, L.; Xue, L.; Yang, C.; Li, Y. J. Am. Chem. Soc., 2016, 138, 4657. doi: 10.1021/jacs.6b01744 doi: 10.1021/jacs.6b01744
40. [40]
  Bin, H.; Gao, L.; Zhang, Z. G.; Yang, Y.; Zhang, Y.; Zhang, C.; Chen, S.; Xue, L.; Yang, C.; Xiao, M.; et al. Nat. Commun. 2016, 7, 13651. doi: 10.1038/ncomms13651 doi: 10.1038/ncomms13651
41. [41]
  Xue, L.; Yang, Y.; Xu, J.; Zhang, C.; Bin, H.; Zhang, Z. G.; Qiu, B.; Li, X.; Sun, C.; Gao, L.; et al. Adv. Mater. 2017, 29, 1703344. doi: 10.1002/adma.201703344 doi: 10.1002/adma.201703344
42. [42]
  Yuan, J.; Qiu, L.; Zhang, Z.; Li, Y.; He, Y.; Jiang, L.; Zou, Y. Chem. Commun. 2016, 52, 6881. doi: 10.1039/C6CC01771A doi: 10.1039/C6CC01771A
43. [43]
  Yuan, J.; Qiu, L.; Zhang, Z. G.; Li, Y.; Chen, Y.; Zou, Y. Nano Energy 2016, 30, 312. doi: 10.1016/j.nanoen.2016.10.008 doi: 10.1016/j.nanoen.2016.10.008
44. [44]
  Yuan, J.; Ouyang, J.; Cimrová, V.; Leclerc, M.; Najari, A.; Zou, Y. J. Mater. Chem. C 2017, 5, 1858. doi: 10.1039/C6TC05381E doi: 10.1039/C6TC05381E
45. [45]
  Gedefaw, D.; Prosa, M.; Bolognesi, M.; Seri, M.; Andersson, M. R. Adv. Energy Mater. 2017, 7, 1700575. doi: 10.1002/aenm.201700575 doi: 10.1002/aenm.201700575
46. [46]
  Liu, M.; Gao, Y.; Zhang, Y.; Liu, Z.; Zhao, L. Polym. Chem. 2017, 8, 4613. doi: 10.1039/C7PY00850C doi: 10.1039/C7PY00850C
47. [47]
  Xu, S.; Feng, L.; Yuan, J.; Zhang, Z. G.; Li, Y.; Peng, H.; Zou, Y. ACS Appl. Mater. Interfaces 2017, 9, 18816. doi: 10.1021/acsami.7b03947 doi: 10.1021/acsami.7b03947
48. [48]
  Zhang, Z.; Feng, L.; Xu, S.; Yuan, J.; Zhang, Z. G.; Peng, H.; Li, Y.; Zou, Y. J. Mater. Chem. A 2017, 5, 11286. doi: 10.1039/C7TA02486J doi: 10.1039/C7TA02486J
49. [49]
  Zhang, Z.; Feng, L.; Xu, S.; Liu, Y.; Peng, H.; Zhang, Z. G.; Li, Y.; Zou, Y. Adv. Sci. 2017, 4, 1700152. doi: 10.1002/advs.201700152 doi: 10.1002/advs.201700152
50. [50]
  Baran, D.; Ashraf, R. S.; Hanifi, D. A.; Abdelsamie, M.; Gasparini, N.; Rohr, J. A.; Holliday, S.; Wadsworth, A.; Lockett, S.; Neophytou, M.; et al. Nat. Mater.2017, 16, 363. doi: 10.1038/nmat4797 doi: 10.1038/nmat4797
51. [51]
  Jia, B.; Wu, Y.; Zhao, F.; Yan, C.; Zhu, S.; Cheng, P.; Mai, J.; Lau, T. K.; Lu, X.; Su, C. J.; et al. Sci. China Chem. 2017, 60, 257. doi: 10.1007/s11426-016-0336-6 doi: 10.1007/s11426-016-0336-6
52. [52]
  Feng, S.; Zhang, C.; Liu, Y.; Bi, Z.; Zhang, Z.; Xu, X.; Ma, W.; Bo, Z. Adv. Mater. 2017, 29, 1703527. doi: 10.1002/adma.201703527 doi: 10.1002/adma.201703527
53. [53]
  Kouijzer, S.; Michels, J. J.; van den Berg, M.; Gevaerts, V. S.; Turbiez, M.; Wienk, M. M.; Janssen, R. A. J. Am. Chem. Soc. 2013, 135, 12057. doi: 10.1021/ja405493j doi: 10.1021/ja405493j
54. [54]
  Li, Z.; Jiang, K.; Yang, G.; Lai, J. Y.; Ma, T.; Zhao, J.; Ma, W.; Yan, H. Nat. Commun. 2016, 7, 13094. doi: 10.1038/ncomms13094 doi: 10.1038/ncomms13094
1. [1]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
2. [2]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
5. [5]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
6. [6]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
7. [7]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
8. [8]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
9. [9]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
10. [10]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
11. [11]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
12. [12]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
13. [13]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
14. [14]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
15. [15]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
16. [16]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
17. [17]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
18. [18]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
19. [19]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
20. [20]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(911)
HTML views(88)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Asymmetric Quinoxaline-Based Polymer for High Efficiency Non-Fullerene Solar Cells

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com