Citation: HUANG Zhijuan, YU Zhinong, LI Yan, WANG Jizheng. ZnO Ultraviolet Photodetector Modified with Graphdiyne[J]. Acta Physico-Chimica Sinica, ;2018, 34(9): 1088-1094. doi: 10.3866/PKU.WHXB201801251 shu

ZnO Ultraviolet Photodetector Modified with Graphdiyne

HUANG Zhijuan ¹ ,
YU Zhinong ^1,, ,
LI Yan ¹ ,
WANG Jizheng ^2,,

1.
Beijing Engineering Research Center of Mixed Reality and Advanced Display, School of Optoelectronics, Beijing Institute of Technology, Beijing 100081, P.R.China
2.
Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R.China

Corresponding author: YU Zhinong, znyu@bit.edu.cn WANG Jizheng, jizheng@iccas.ac.cn
Received Date: 14 December 2017
Revised Date: 22 January 2018
Accepted Date: 22 January 2018
Available Online: 25 September 2018
Fund Project: The project was supported by the National Natural Science Foundation of China (61675024)the National Natural Science Foundation of China 61675024

ZnO is an ideal material for ultraviolet (UV) detection due to its wide direct-bandgap, high exciton binding energy, and high internal photoconductive gain.However, ZnO UV detectors have the disadvantages of slow response speed and low detectivity.Graphdiyne (GD) is a novel carbonaceous allotrope, and possesses excellent electronic performance in air.In this study, the metal-semiconductor-metal (MSM) structured lateral ZnO UV detectors were prepared, and GD was employed to modify the ZnO surface.The effects of GD deposited 1–3 times (viz.1T, 2T, and 3T GD) on the performance of ZnO ultraviolet detector were carefully investigated.The results show that the dark current of the bare ZnO detector is 24 μA under a bias of 10 V, while that of the graphdiyne-modified detector is ~0.34 μA (about two orders of magnitude reduction).The dark current remains almost the same for the 1T, 2T and 3T GD films.The photocurrents of 1–3T GD-modified detectors were 0.21, 0.32, 0.27 mA, respectively.The device modified with 2T GD displays the highest photocurrent, which is significantly enhanced in comparison to the unmodified device (0.08 mA) under a 365-nm UV radiation of 100 μW·cm⁻².Meanwhile, the responsivity and detectivity are improved remarkably.Under a bias of 10 V, the 2T-GD-modified detector displays high responsivity of 1759 A·W⁻¹ and detectivity of 4.23×10¹⁵ Jones.The detectivity is thus far the highest for ZnO UV detectors prepared by the sol-gel method.The improved performance of the GD-modified detector is attributed to the p-n junction formed between the GD and the ZnO film.At dark, the p-n junction is formed between the ZnO film and the GD, which greatly decreases the dark current of the detector.Under UV illumination, photogenerated holes accumulate in the GD, reducing electron-hole recombination; thus, the photocurrent is significantly increased.Furthermore, desorption and absorption of oxygen on the ZnO surface are much reduced due to the GD attached on the ZnO surface, thus improving the response speed of the detector.However, the intensive distribution of GD slightly hinders the UV absorption of ZnO thin films, reducing the responsivity of the detector.Careful optimization shows that the use of 2T GD gives the best output, and the corresponding ZnO UV detector exhibits very good performance.Overall, this study demonstrates that using GD can effectively improve the performance of ZnO UV detector.
- Graphdiyne,
- Zinc oxide,
- Ultraviolet detector,
- Responsivity,
- Detectivity
1. [1]
  Moon, T. H.; Jeong, M. C.; Lee, W.; Myoung, J. M. Appl. Surf. Sci. 2005, 240, 280. doi:10.1016/j.apsusc.2004.06.149 doi: 10.1016/j.apsusc.2004.06.149
2. [2]
  Lin, P.; Yan, X. Q.; Zhang, Z.; Shen, Y. W.; Zhao, Y. G.; Bai, Z. M.; Zhang, Y. ACS Appl. Mater. Inter. 2013, 5, 3671. doi:10.1021/am4008775 doi: 10.1021/am4008775
3. [3]
  Boruah, B. D.; Mukherjee, A.; Sridhar, S.; Misra, A. ACS Appl. Mater. Inter. 2015, 7, 10606. doi:10.1021/acsami.5b02403 doi: 10.1021/acsami.5b02403
4. [4]
  Hwang, J. D.; Wang, F. H.; Kung, C. Y.; Lai, M. J.; Chan, M. C. J. Appl. Phys. 2014, 115, 173110.doi:10.1063/1.4875657 doi: 10.1063/1.4875657
5. [5]
  Jin, Z. W.; Gao. L.; Zhou, Q.; Wang, J. Z. Sci. Rep. 2014, 4, 4268. doi:10.1038/srep04268 doi: 10.1038/srep04268
6. [6]
  Wang, X.; Liu, K. W.; Chen, X.; Li, B. H.; Jiang, M. M.; Zhang, Z. Z.; Zhao, H. F.; Shen, D. Z. ACS Appl. Mater. Inter. 2017, 9, 5574. doi:10.1021/acsami.6b14430 doi: 10.1021/acsami.6b14430
7. [7]
  Zhou, H.; Mei, J.; Gui, P. B.; Tao, P.; Song, Z. H.; Wang, H.; Fang, G. J. Mat. Sci. Semicon. Proc. 2015, 38, 67. doi:10.1016/j.mssp.2015.04.005 doi: 10.1016/j.mssp.2015.04.005
8. [8]
  Shahid, M. U.; Deen, K. M.; Ahmad, A.; Akram, M. A.; Aslam, M.; Akhtar, W. Appl. Nanosci. 2016, 6, 235. doi:10.1007/s13204-015-0425-7 doi: 10.1007/s13204-015-0425-7
9. [9]
  Chang, H. X.; Sun, Z. H.; Ho, K. Y.; Tao, X. M.; Yan, F.; Kwok, W.; Zheng, Z. Z. Nanoscale 2011, 3, 258. doi:10.1039/c0nr00588f doi: 10.1039/c0nr00588f
10. [10]
  Nie, B.; Hu, J. G.; Luo, L. B.; Xie, C.; Zeng, L. H.; Lv, P.; Li, F. Z.; Jie, J. S.; Feng, M.; Wu, C. Y.; Yu, Y. Q.; Yu, S. H. Small 2013, 9, 2872. doi:10.1002/smll.201203188 doi: 10.1002/smll.201203188
11. [11]
  Guo, D. Y.; Shan, C. X.; Qu, S. N.; Shen, D. Z. Sci. Rep. 2014, 4, 7469. doi:10.1038/srep07469 doi: 10.1038/srep07469
12. [12]
  Li, G. X.; Li, Y. L.; Liu, H. B.; Guo, Y. B; Li, Y. J.; Zhu, D. B. Chem. Comm. 2010, 46, 3256. dio:10.1039/b922733d doi: 10.1039/b922733d
13. [13]
  Jin, Z. W.; Yuan, M. J.; Li, H.; Yang, H.; Zhou, Q.; Liu, H. B.; Lan, X. Z.; Liu, M. X.; Wang, J. Z.; Sargent, E. H.; Li, Y. L. Adv. Funct. Mater. 2016, 26, 5284. doi:10.1002/adfm.201601570 doi: 10.1002/adfm.201601570
14. [14]
  Long, M. Q.; Tang, L.; Wang, D.; Li, Y. L.; Shuai, Z. G. ACS Nano 2011, 5, 2593. doi:10.1021/nn102472s doi: 10.1021/nn102472s
15. [15]
  Qian, X. M.; Liu, H. B.; Huang, C. H.; Chen, S. H.; Zhang, L.; Li, Y. J.; Wang, J. Z.; Li, Y. L. Sci. Rep. 2015, 5, 7756. doi:10.1038/srep07756 doi: 10.1038/srep07756
16. [16]
  Chen, Y. H.; Liu, H. B.; Li, Y. L. Chin. Sci. Bull. 2016, 61, 2901. doi: 10.1360/N972016-00483
17. [17]
  Basak, D.; Amin, G.; Mallik, B.; Paul, G. K.; Sen, S. K. J. Cryst. Growth 2003, 256, 73. doi:10.1016/S0022-0248(03)01304-6 doi: 10.1016/S0022-0248(03)01304-6
18. [18]
  Kumar, V.; Singh, N.; Kapoor, A.; Ntwaeaborwa, O. M.; Swart, H. C. Mater. Res. Bull. 2013, 48, 4596. doi:10.1016/j.materresbull.2013.07.061 doi: 10.1016/j.materresbull.2013.07.061
19. [19]
  Kumar, V.; Kumar, V.; Som, S.; Yousif, A.; Singh, N.; Ntwaeaborwa, O. M.; Kapoor, A.; Swart, H. C. J. Colloid Interface Sci. 2014, 428, 8. doi:10.1016/j.jcis.2014.04.035. doi: 10.1016/j.jcis.2014.04.035
20. [20]
  Zhang, D. Z.; Jin, F. Y.; Gao, F. L.; Shen, L.; Su, D. M.; Zhou, J. R.; Chen, Y.; Ruan, S. P. RSC Adv. 2017, 5, 83795. doi:10.1039/c5ra17023k doi: 10.1039/c5ra17023k
21. [21]
  Kind, H.; Yan, H.; Messer, B.; Law, M.; Yang, P. D. Adv. Mater. 2002, 14, 158. doi:10.1002/1521-4095(20020116)14:23.0.CO;2-W doi: 10.1002/1521-4095(20020116)14:23.0.CO;2-W
22. [22]
  Takahashi, Y.; Kanamori, M.; Kondoh, A.; Minoura, H.; Ohya, Y. Jpn. J. Appl. Phys. 1994, 33, 6611. doi:10.1143/JJAP.33.6611 doi: 10.1143/JJAP.33.6611
23. [23]
  Dijken, A.; Meulenkamp, E. A.; Vanmaekelbergh, D.; Meijerink, A. J. Appl. Phys. B 2000, 104, 4355. doi:10.1021/jp993998x doi: 10.1021/jp993998x
24. [24]
  Wu, J. M.; Chang, W. E. ACS Appl. Mater. Inter. 2014, 6, 14286. doi:10.1021/am503598g doi: 10.1021/am503598g
25. [25]
  Boruah, B. D.; Ferry, D. B.; Mukherjee, A.; Misra, A. Nanotechnology 2015, 26, 235703. doi:10.1088/0957-4484/26/23/235703 doi: 10.1088/0957-4484/26/23/235703
1. [1]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
2. [2]
  Yuhang Zhang , Weiwei Zhao , Hongwei Liu , Junpeng Lü . 基于低维材料的自供电光电探测器研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2310004-. doi: 10.3866/PKU.WHXB202310004
3. [3]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
4. [4]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
5. [5]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305
6. [6]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
7. [7]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
8. [8]
  Qinghong Pan , Huafang Zhang , Qiaoling Liu , Donghong Huang , Da-Peng Yang , Tianjia Jiang , Shuyang Sun , Xiangrong Chen . A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification. Chinese Chemical Letters, 2025, 36(1): 110169-. doi: 10.1016/j.cclet.2024.110169
9. [9]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
10. [10]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
11. [11]
  Pengyu Chen , Beibei Chen , Man He , Yuxi Zhou , Lei Lei , Jian Han , Bingsheng Zhou , Ligang Hu , Bin Hu . Nanoplastics and nano-ZnO facilitate Cd accumulation in zebrafish larvae via a distinct pathway: Revelation by LA-ICP-MS imaging. Chinese Chemical Letters, 2025, 36(2): 109908-. doi: 10.1016/j.cclet.2024.109908
12. [12]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
13. [13]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041
14. [14]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
15. [15]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
16. [16]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
17. [17]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
18. [18]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
19. [19]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
20. [20]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(547)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142