Citation: HUANG Zhijuan, YU Zhinong, LI Yan, WANG Jizheng. ZnO Ultraviolet Photodetector Modified with Graphdiyne[J]. Acta Physico-Chimica Sinica, ;2018, 34(9): 1088-1094. doi: 10.3866/PKU.WHXB201801251 shu

ZnO Ultraviolet Photodetector Modified with Graphdiyne

HUANG Zhijuan ¹ ,
YU Zhinong ^1,, ,
LI Yan ¹ ,
WANG Jizheng ^2,,

1.
Beijing Engineering Research Center of Mixed Reality and Advanced Display, School of Optoelectronics, Beijing Institute of Technology, Beijing 100081, P.R.China
2.
Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R.China

Corresponding author: YU Zhinong, znyu@bit.edu.cn WANG Jizheng, jizheng@iccas.ac.cn
Received Date: 14 December 2017
Revised Date: 22 January 2018
Accepted Date: 22 January 2018
Available Online: 25 September 2018
Fund Project: The project was supported by the National Natural Science Foundation of China (61675024)the National Natural Science Foundation of China 61675024

ZnO is an ideal material for ultraviolet (UV) detection due to its wide direct-bandgap, high exciton binding energy, and high internal photoconductive gain.However, ZnO UV detectors have the disadvantages of slow response speed and low detectivity.Graphdiyne (GD) is a novel carbonaceous allotrope, and possesses excellent electronic performance in air.In this study, the metal-semiconductor-metal (MSM) structured lateral ZnO UV detectors were prepared, and GD was employed to modify the ZnO surface.The effects of GD deposited 1–3 times (viz.1T, 2T, and 3T GD) on the performance of ZnO ultraviolet detector were carefully investigated.The results show that the dark current of the bare ZnO detector is 24 μA under a bias of 10 V, while that of the graphdiyne-modified detector is ~0.34 μA (about two orders of magnitude reduction).The dark current remains almost the same for the 1T, 2T and 3T GD films.The photocurrents of 1–3T GD-modified detectors were 0.21, 0.32, 0.27 mA, respectively.The device modified with 2T GD displays the highest photocurrent, which is significantly enhanced in comparison to the unmodified device (0.08 mA) under a 365-nm UV radiation of 100 μW·cm⁻².Meanwhile, the responsivity and detectivity are improved remarkably.Under a bias of 10 V, the 2T-GD-modified detector displays high responsivity of 1759 A·W⁻¹ and detectivity of 4.23×10¹⁵ Jones.The detectivity is thus far the highest for ZnO UV detectors prepared by the sol-gel method.The improved performance of the GD-modified detector is attributed to the p-n junction formed between the GD and the ZnO film.At dark, the p-n junction is formed between the ZnO film and the GD, which greatly decreases the dark current of the detector.Under UV illumination, photogenerated holes accumulate in the GD, reducing electron-hole recombination; thus, the photocurrent is significantly increased.Furthermore, desorption and absorption of oxygen on the ZnO surface are much reduced due to the GD attached on the ZnO surface, thus improving the response speed of the detector.However, the intensive distribution of GD slightly hinders the UV absorption of ZnO thin films, reducing the responsivity of the detector.Careful optimization shows that the use of 2T GD gives the best output, and the corresponding ZnO UV detector exhibits very good performance.Overall, this study demonstrates that using GD can effectively improve the performance of ZnO UV detector.
- Graphdiyne,
- Zinc oxide,
- Ultraviolet detector,
- Responsivity,
- Detectivity
1. [1]
  Moon, T. H.; Jeong, M. C.; Lee, W.; Myoung, J. M. Appl. Surf. Sci. 2005, 240, 280. doi:10.1016/j.apsusc.2004.06.149 doi: 10.1016/j.apsusc.2004.06.149
2. [2]
  Lin, P.; Yan, X. Q.; Zhang, Z.; Shen, Y. W.; Zhao, Y. G.; Bai, Z. M.; Zhang, Y. ACS Appl. Mater. Inter. 2013, 5, 3671. doi:10.1021/am4008775 doi: 10.1021/am4008775
3. [3]
  Boruah, B. D.; Mukherjee, A.; Sridhar, S.; Misra, A. ACS Appl. Mater. Inter. 2015, 7, 10606. doi:10.1021/acsami.5b02403 doi: 10.1021/acsami.5b02403
4. [4]
  Hwang, J. D.; Wang, F. H.; Kung, C. Y.; Lai, M. J.; Chan, M. C. J. Appl. Phys. 2014, 115, 173110.doi:10.1063/1.4875657 doi: 10.1063/1.4875657
5. [5]
  Jin, Z. W.; Gao. L.; Zhou, Q.; Wang, J. Z. Sci. Rep. 2014, 4, 4268. doi:10.1038/srep04268 doi: 10.1038/srep04268
6. [6]
  Wang, X.; Liu, K. W.; Chen, X.; Li, B. H.; Jiang, M. M.; Zhang, Z. Z.; Zhao, H. F.; Shen, D. Z. ACS Appl. Mater. Inter. 2017, 9, 5574. doi:10.1021/acsami.6b14430 doi: 10.1021/acsami.6b14430
7. [7]
  Zhou, H.; Mei, J.; Gui, P. B.; Tao, P.; Song, Z. H.; Wang, H.; Fang, G. J. Mat. Sci. Semicon. Proc. 2015, 38, 67. doi:10.1016/j.mssp.2015.04.005 doi: 10.1016/j.mssp.2015.04.005
8. [8]
  Shahid, M. U.; Deen, K. M.; Ahmad, A.; Akram, M. A.; Aslam, M.; Akhtar, W. Appl. Nanosci. 2016, 6, 235. doi:10.1007/s13204-015-0425-7 doi: 10.1007/s13204-015-0425-7
9. [9]
  Chang, H. X.; Sun, Z. H.; Ho, K. Y.; Tao, X. M.; Yan, F.; Kwok, W.; Zheng, Z. Z. Nanoscale 2011, 3, 258. doi:10.1039/c0nr00588f doi: 10.1039/c0nr00588f
10. [10]
  Nie, B.; Hu, J. G.; Luo, L. B.; Xie, C.; Zeng, L. H.; Lv, P.; Li, F. Z.; Jie, J. S.; Feng, M.; Wu, C. Y.; Yu, Y. Q.; Yu, S. H. Small 2013, 9, 2872. doi:10.1002/smll.201203188 doi: 10.1002/smll.201203188
11. [11]
  Guo, D. Y.; Shan, C. X.; Qu, S. N.; Shen, D. Z. Sci. Rep. 2014, 4, 7469. doi:10.1038/srep07469 doi: 10.1038/srep07469
12. [12]
  Li, G. X.; Li, Y. L.; Liu, H. B.; Guo, Y. B; Li, Y. J.; Zhu, D. B. Chem. Comm. 2010, 46, 3256. dio:10.1039/b922733d doi: 10.1039/b922733d
13. [13]
  Jin, Z. W.; Yuan, M. J.; Li, H.; Yang, H.; Zhou, Q.; Liu, H. B.; Lan, X. Z.; Liu, M. X.; Wang, J. Z.; Sargent, E. H.; Li, Y. L. Adv. Funct. Mater. 2016, 26, 5284. doi:10.1002/adfm.201601570 doi: 10.1002/adfm.201601570
14. [14]
  Long, M. Q.; Tang, L.; Wang, D.; Li, Y. L.; Shuai, Z. G. ACS Nano 2011, 5, 2593. doi:10.1021/nn102472s doi: 10.1021/nn102472s
15. [15]
  Qian, X. M.; Liu, H. B.; Huang, C. H.; Chen, S. H.; Zhang, L.; Li, Y. J.; Wang, J. Z.; Li, Y. L. Sci. Rep. 2015, 5, 7756. doi:10.1038/srep07756 doi: 10.1038/srep07756
16. [16]
  Chen, Y. H.; Liu, H. B.; Li, Y. L. Chin. Sci. Bull. 2016, 61, 2901. doi: 10.1360/N972016-00483
17. [17]
  Basak, D.; Amin, G.; Mallik, B.; Paul, G. K.; Sen, S. K. J. Cryst. Growth 2003, 256, 73. doi:10.1016/S0022-0248(03)01304-6 doi: 10.1016/S0022-0248(03)01304-6
18. [18]
  Kumar, V.; Singh, N.; Kapoor, A.; Ntwaeaborwa, O. M.; Swart, H. C. Mater. Res. Bull. 2013, 48, 4596. doi:10.1016/j.materresbull.2013.07.061 doi: 10.1016/j.materresbull.2013.07.061
19. [19]
  Kumar, V.; Kumar, V.; Som, S.; Yousif, A.; Singh, N.; Ntwaeaborwa, O. M.; Kapoor, A.; Swart, H. C. J. Colloid Interface Sci. 2014, 428, 8. doi:10.1016/j.jcis.2014.04.035. doi: 10.1016/j.jcis.2014.04.035
20. [20]
  Zhang, D. Z.; Jin, F. Y.; Gao, F. L.; Shen, L.; Su, D. M.; Zhou, J. R.; Chen, Y.; Ruan, S. P. RSC Adv. 2017, 5, 83795. doi:10.1039/c5ra17023k doi: 10.1039/c5ra17023k
21. [21]
  Kind, H.; Yan, H.; Messer, B.; Law, M.; Yang, P. D. Adv. Mater. 2002, 14, 158. doi:10.1002/1521-4095(20020116)14:23.0.CO;2-W doi: 10.1002/1521-4095(20020116)14:23.0.CO;2-W
22. [22]
  Takahashi, Y.; Kanamori, M.; Kondoh, A.; Minoura, H.; Ohya, Y. Jpn. J. Appl. Phys. 1994, 33, 6611. doi:10.1143/JJAP.33.6611 doi: 10.1143/JJAP.33.6611
23. [23]
  Dijken, A.; Meulenkamp, E. A.; Vanmaekelbergh, D.; Meijerink, A. J. Appl. Phys. B 2000, 104, 4355. doi:10.1021/jp993998x doi: 10.1021/jp993998x
24. [24]
  Wu, J. M.; Chang, W. E. ACS Appl. Mater. Inter. 2014, 6, 14286. doi:10.1021/am503598g doi: 10.1021/am503598g
25. [25]
  Boruah, B. D.; Ferry, D. B.; Mukherjee, A.; Misra, A. Nanotechnology 2015, 26, 235703. doi:10.1088/0957-4484/26/23/235703 doi: 10.1088/0957-4484/26/23/235703
1. [1]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
2. [2]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
3. [3]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
4. [4]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
5. [5]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
6. [6]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
7. [7]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
8. [8]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
9. [9]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Di WU , Ruimeng SHI , Zhaoyang WANG , Yuehua SHI , Fan YANG , Leyong ZENG . Construction of pH/photothermal dual-responsive delivery nanosystem for combination therapy of drug-resistant bladder cancer cell. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1679-1688. doi: 10.11862/CJIC.20240135
12. [12]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
15. [15]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
16. [16]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
17. [17]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
18. [18]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
19. [19]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
20. [20]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(459)
HTML views(47)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142