Citation: VON SZENTPÁLY László. Multiply Charged Anions, Maximum Charge Acceptance, and Higher Electron Affinities of Molecules, Superatoms, and Clusters[J]. Acta Physico-Chimica Sinica, ;2018, 34(6): 675-682. doi: 10.3866/PKU.WHXB201801021 shu

Multiply Charged Anions, Maximum Charge Acceptance, and Higher Electron Affinities of Molecules, Superatoms, and Clusters

VON SZENTPÁLY László ^,

Institut für Theoretische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

Corresponding author: VON SZENTPÁLY László, lszentpaly@yahoo.com
Received Date: 30 October 2017
Revised Date: 25 December 2017
Accepted Date: 25 December 2017
Available Online: 2 June 2018

The addition of electrons to form gas-phase multiply charged anions (MCAs) normally requires sophisticated experiments or calculations.In this work, the factors stabilizing the MCAs, the maximum electron uptake of gas-phase molecules, X, and the electronic stability of MCAs X^Q^-, are discussed. The drawbacks encountered when applying computational and/or conceptual density functional theory (DFT) to MCAs are highlighted. We develop and test a different model based on the valence-state concept. As in DFT, the electronic energy, E(N, v_ex), is a continuous function of the average electron number, N, and the external potential, v_ex, of the nuclei. The valence-state-parabola is a second-order polynomial that allows extending E(N, v_ex) to dianions and higher MCAs. The model expresses the maximum electron acceptance, Q_max, and the higher electron affinities, A_Q, as simple functions of the first electron affinity, A₁, and the ionization energy, I, of the "ancestor" system. Thus, the maximum electron acceptance is Q_{max, calc} = 1 + 12A₁/7(I -A₁). The ground-state parabola model of the conceptual DFT yields approximately half of this value, and it is termed Q_{max, GS} = \begin{document}${}^{1}\!\!\diagup\!\!{}_{2}\; $\end{document} + A₁/(I -A₁). A large variety of molecules are evaluated including fullerenes, metal clusters, super-pnictogens, super-halogens (OF₃), super-alkali species (OLi₃), and neutral or charged transition-metal complexes, AB_mL_n^0/+/-. The calculated second electron affinity A_{2, calc} = A₁-(7/12)(I -A₁) is linearly correlated to the literature references A_{2, lit} with a correlation coefficient R = 0.998. A₂ or A₃ values are predicted for further 24 species. The appearance sizes, n_ap^3-, of triply charged anionic clusters and fullerenes are calculated in agreement with the literature.
1. [1]
  Pearson, R. G. Chemical Hardness; Wiley-VCH: Weinheim, Germany, 1997. doi: 10.1002/3527606173 doi: 10.1002/3527606173
2. [2]
  Sommerfeld, T.; Weber, R. J. J. Phys. Chem. A 2011, 115, 6675. doi: 10.1021/jp202817d doi: 10.1021/jp202817d
3. [3]
  Walters, T.; Wang, X. B.; Wang, L. -S. Coord. Chem. Rev. 2007, 251, 474. doi:10.1016/j.ccr.2006.04.010 doi: 10.1016/j.ccr.2006.04.010
4. [4]
  Herlert, A.; Kruckeberg, S.; Schweikhard, L.; Vogel, M.; Walther, C. Phys. Scr 1999, T80, 200. doi: 10.1238/Physica.Topical.080a00200 doi: 10.1238/Physica.Topical.080a00200
5. [5]
  Franzreb, K.; Wiliams, P. J. Chem. Phys. 2005, 123, 224312. doi: 10.1063/1.2136154 doi: 10.1063/1.2136154
6. [6]
  Walsh, N.; Martinez, F.; Marx, G., Schweikhard, L., Ziegler, F. J. Chem. Phys. 2010, 132, 014308. doi:10.1063/1.3270153 doi: 10.1063/1.3270153
7. [7]
  Wong, A. Y.; Mamas, D. L.; Arnush, D. Phys. Fluids 1975, 18, 1489. doi: 10.1063/1.861034 doi: 10.1063/1.861034
8. [8]
  Wang, X. B.; Wang, L. S. Photoelectron Spectroscopy of Multiply Charged Anions. In Annual Review Physical Chemistry; Annual Reviews Inc.: Palo Alto, CA, USA, 2009; Vol. 60, pp. 105-126.
9. [9]
  Langer, P.; Freiberg, W. Chem. Rev. 2004, 104, 4125. doi: 10.1021/cr010203l doi: 10.1021/cr010203l
10. [10]
  Tallgren, L. Acta Med. Scand. Suppl. 1980, 640, 1.
11. [11]
  Lee, A.; Dawson, P. A.; Markovich, D. Int. J. Biochem. Cell Biol. 2005, 37, 1350. doi: 10.1016/j.biocel.2005.02.013 doi: 10.1016/j.biocel.2005.02.013
12. [12]
  Ramanathan, V.; Crutzen, P. J.; Kiehl, J. T.; Rosenfeld, D. Science 2001, 294, 2119. doi: 10.1126/science.1064034 doi: 10.1126/science.1064034
13. [13]
  Scheller, M. K.; Compton, R. N.; Cederbaum, L. S. Science 1995, 270, 1160. doi: 10.1126/science.270.5239.1160 doi: 10.1126/science.270.5239.1160
14. [14]
  Boldyrev, A. I.; Gutowski, M.; Simons, J. Acc. Chem. Res. 1996, 29, 497. doi: 10.1021/ar960147o doi: 10.1021/ar960147o
15. [15]
  Dreuw, A.; Cederbaum, L. S. Chem. Rev. 2002, 102, 181. doi: 10.1021/cr0104227 doi: 10.1021/cr0104227
16. [16]
  Feuerbacher, S.; Cederbaum, L. S. J. Phys. Chem. A 2005, 109, 11401. doi: 10.1021/jp053305e doi: 10.1021/jp053305e
17. [17]
  von Szentpály, L. J. Phys. Chem. A 2010, 114, 10891. doi: 10.1021/jp107177d doi: 10.1021/jp107177d
18. [18]
  Parr, R. G.; Yang, W. Density-Functional Theory of Atoms and Molecules; Oxford University Press: Oxford, UK, 1989.
19. [19]
  Parr, R. G.; Pearson, R. G. J. Am. Chem. Soc. 1983, 105, 7512. doi: 10.1021/ja00364a005 doi: 10.1021/ja00364a005
20. [20]
  Cohen, A. J.; Mori-Sánchez, P.; Yang, W. Chem. Rev. 2012, 112, 289. doi: 10.1021/cr200107z doi: 10.1021/cr200107z
21. [21]
  Parr, R. G.; von Szentpály, L.; Liu, S. J. Am. Chem. Soc. 1999, 121, 1922. doi: 10.1021/ja983494x doi: 10.1021/ja983494x
22. [22]
  Bergmann, D.; Hinze, J. Angew. Chem. Int. Ed. 1996, 35, 150; with earlier references quoted therein. doi: 10.1002/anie.199601501 doi: 10.1002/anie.199601501
23. [23]
  von Szentpály, L. J. Mol. Struct. THEOCHEM 1991, 233, 71. doi: 10.1016/0166-1280(91)85055-C doi: 10.1016/0166-1280(91)85055-C
24. [24]
  von Szentpály, L. Int. J. Quantum Chem. 2000, 76, 222. doi: 10.1002/(SICI)1097-461X(2000)76:2 < 222::AID-QUA11 > 3.0.CO; 2-6 doi: 10.1002/(SICI)1097-461X(2000)76:2<222::AID-QUA11>3.0.CO;2-6
25. [25]
  Glasser, L.; von Szentpály, L. J. Am. Chem. Soc. 2006, 128, 12314. doi: 10.1021/ja063812p doi: 10.1021/ja063812p
26. [26]
  Datta, D.; Shee, N. K.; von Szentpály, L. J. Phys. Chem. A 2013, 117, 200. doi: 10.1021/jp3103386 doi: 10.1021/jp3103386
27. [27]
  von Szentpály, L. J. Phys. Chem. A 2015, 119, 1715. doi: 10.1021/jp5084345 doi: 10.1021/jp5084345
28. [28]
  Sen, K. D.; Boehm, M. C.; Schmidt, P. C. Structure and Bonding; Springer-Verlag: Berlin, Germany, 1987; Vol. 66, p. 99.
29. [29]
  Janak, J. F. Phys. Rev. B 1978, 18, 7165. doi: 10.1103/PhysRevB.18.7165 doi: 10.1103/PhysRevB.18.7165
30. [30]
  Jensen, F. J. Chem. Theory Comput. 2010, 6, 2736. doi: 10.1021/ct1003548 doi: 10.1021/ct1003548
31. [31]
  Kim, M. -C.; Sim, E.; Burke, K. J. Chem. Phys. 2011, 134, 171103. doi: 10.1063/1.3590364 doi: 10.1063/1.3590364
32. [32]
  Wade, K. Chem. Commun. 1971, 792. doi: 10.1039/c29710000792 doi: 10.1039/c29710000792
33. [33]
  Mingos, D. M. P. Acc. Chem. Res. 1984, 17, 311. doi: 10.1021/ar00105a003 doi: 10.1021/ar00105a003
34. [34]
  Zhao, T.; Zhou, J.; Wang, Q.; Jena, P. Angew. Chem. Int. Ed. 2017, 56, 13421. doi: 10.1002/anie.201706764. doi: 10.1002/anie.201706764
35. [35]
  Herlert, A.; Schweighardt, L. Int. J. Mass Spectrom. 2003, 229, 19. doi: 10.1016/S1387-3806(03)00251-3 doi: 10.1016/S1387-3806(03)00251-3
36. [36]
  Yannouleas, C.; Landman, U. Chem. Phys. Lett. 1993, 210, 437. doi: 10.1016/0009-2614(93)87050-D doi: 10.1016/0009-2614(93)87050-D
37. [37]
  de Heer, W. A. Rev. Mod. Phys. 1993, 65, 611. doi: 10.1103/RevModPhys.65.611 doi: 10.1103/RevModPhys.65.611
38. [38]
  Gutsev, G. L. Chem. Phys. Lett. 1991, 184, 305. doi: 10.1016/0009-2614(91)85128-J doi: 10.1016/0009-2614(91)85128-J
39. [39]
  Pernpointner, M.; Cederbaum, L. S. J. Chem. Phys. 2007, 126, 144310. doi: 10.1063/1.2721531 doi: 10.1063/1.2721531
40. [40]
  Wesendrup, R.; Schwerdtfeger, P. Inorg. Chem. 2001, 40, 3351. doi: 10.1021/ic010169t doi: 10.1021/ic010169t
41. [41]
  Craciun, R.; Picone, D.; Long, R. T.; Li, S.; Dixon, D. A.; Peterson, K. A.; Christe, K. O. Inorg. Chem. 2010, 49, 1056. doi: 10.1021/ic901967h doi: 10.1021/ic901967h
42. [42]
  Craciun, R.; Long, R. T.; Dixon, D. A.; Christe, K. O. J. Phys. Chem. A 2010, 114, 7571. doi: 10.1021/jp1022949 doi: 10.1021/jp1022949
43. [43]
  Macgregor, S.A.; Moock, K. H. Inorg. Chem. 1998, 37, 3284. doi: 10.1021/ic9605736 doi: 10.1021/ic9605736
44. [44]
  Seppelt, K. Chem. Rev. 2015, 115, 1296. doi: 10.1021/cr5001783 doi: 10.1021/cr5001783
45. [45]
  Pradhan, K.; Gutsev, G. L.; Weatherford, C. A.; Jena, P. J. Chem. Phys. 2011, 134, 144305. doi: 10.1063/1.3570578 doi: 10.1063/1.3570578
46. [46]
  Uzunova, E. L. J. Phys. Chem. A 2011, 115, 10665. doi: 10.1021/jp2034888 doi: 10.1021/jp2034888
47. [47]
  Zhou, M.; Andrews, L.; Ismail, N.; Marsden, C. J. Phys. Chem. 2000, 104, 5495. doi: 10.1021/jp000292q doi: 10.1021/jp000292q
48. [48]
  Zein, S.; Ortiz, J. V. J. Chem. Phys. 2011, 135, 164307. doi: 10.1063/1.3636082 doi: 10.1063/1.3636082
49. [49]
  Zein, S.; Ortiz, J. V. J. Chem. Phys. 2012, 136, 224305. doi: 10.1063/1.4728073 doi: 10.1063/1.4728073
50. [50]
  Anusiewicz, I.; Freza, S.; Sikorska, C.; Skurski, P. Chem. Phys. Lett. 2010, 493, 234. doi: 10.1016/j.cplett.2010.05.058 doi: 10.1016/j.cplett.2010.05.058
51. [51]
  Boltanina, O. V.; Ioffé, I. N.; Sidorov, L. N.; Seifert, G.; Vietze, K. J. Am. Chem. Soc. 2000, 122, 9745. doi: 10.1021/ja000734b doi: 10.1021/ja000734b
52. [52]
  Hampe, O.; Neumaier, M.; Blom, M. N.; Kappes, M. M. Chem. Phys. Lett. 2002, 354, 303. doi: 10.1016/S0009-2614(02)00124-0 doi: 10.1016/S0009-2614(02)00124-0
53. [53]
  Wang, X. -B.; Woo, H. -K.; Yang, J.; Kappes, M. M.; Wang, L. -S. J. Phys. Chem. C 2007, 111, 17684. doi: 10.1021/jp0703861 doi: 10.1021/jp0703861
54. [54]
  Wang, X. -B.; Woo, H. -K.; Huang, X.; Kappes, M. M.; Wang, L. -S. Phys. Rev. Lett. 2006, 96, 143002. doi: 10.1103/PhysRevLett.96.143002 doi: 10.1103/PhysRevLett.96.143002
55. [55]
  Nasibullaev, S. K.; Davletbaeva, G. D.; Vasil'ev, Z. V.; Nasibullayev, I. S. Fuller. Nanotub. Carbon Nanostruct. 2004, 12, 491. doi: 10.1081/FST-120027212 doi: 10.1081/FST-120027212
56. [56]
  Wang, X. -B.; Chi, C.; Zhou, M.; Kuvychko, I. V.; Seppelt, K.; Popov, A. A.; Strauss, S. H., Boltalina, O.; Wang, L. -S. J. Phys. Chem. A 2010, 114, 1756. doi: 10.1021/jp9097364 doi: 10.1021/jp9097364
57. [57]
  Caddeo, C.; Malloci, G.; De Angelis, F.; Colombo, L.; Mattoni, A. Phys. Chem. Chem. Phys. 2012, 14, 14293. doi: 10.1039/c2cp42037f doi: 10.1039/c2cp42037f
58. [58]
  Belau, L.; Wheeler, S. W.; Ticknor, B. W.; Ahmed, M.; Leone, S. R.; Allen, W. D., Schaefer, H. F.; Duncan, M. A. J. Am. Chem. Soc. 2007, 129, 10229. doi: 10.1021/ja072526q doi: 10.1021/ja072526q
59. [59]
  Ortíz, J. V.; Zakrzewski, V. G. J. Chem. Phys. 1994, 100, 6614. doi: 10.1063/1.467071 doi: 10.1063/1.467071
60. [60]
  Ortíz, J. V.; Zakrzewski, V. G. J. Chem. Phys. 1995, 102, 294. doi: 10.1063/1.469402 doi: 10.1063/1.469402
61. [61]
  Sommerfeld, T. J. Phys. Chem. A 2000, 104, 8806. doi: 10.1021/jp0017590 doi: 10.1021/jp0017590
62. [62]
  Wang, J.; Yang, M.; Jellinek, J.; Wang, G. Phys. Rev. 2006, A74, 023202. doi: 10.1103/PhysRevA.74.023202 doi: 10.1103/PhysRevA.74.023202
63. [63]
  Kostko, O. Photoelectron Spectroscopy of Mass-selected Sodium, Coinage Metal and Divalent Metal Cluster Anions; Ph. D. Thesis, Universität Freiburg: Freiburg, Germany, 2007. www.freidok.uni-freiburg.de
64. [64]
  Yannouleas, C.; Landman, U. Phys. Rev. B 2000, 61, R10587. doi: 10.1103/PhysRevB.61.15895 doi: 10.1103/PhysRevB.61.15895
65. [65]
  Berkowitz, J.; Lifshitz, G. J. Chem. Phys. 1968, 48, 4346. doi: 10.1063/1.1667997 doi: 10.1063/1.1667997
66. [66]
  Jin, Y.; Maroulis, G.; Kuang, X.; Ding, L.; Lu, C.; Wang, J.; Lv, J.; Zhang, C.; Ju, M. Phys. Chem. Chem. Phys. 2015, 17, 13590. doi: 10.1039/c5cp00728c doi: 10.1039/c5cp00728c
67. [67]
  Zakrzewski, V. C.; von Niessen, W. Theor. Chim. Acta 1994, 88, 75. doi: 10.1007/BF01113735 doi: 10.1007/BF01113735
68. [68]
  Berghof, V; Sommerfeld, T; Cederbaum, L. S. J. Phys. Chem. A 1998, 102, 5100. doi: 10.1021/jp9808375 doi: 10.1021/jp9808375
69. [69]
  Kaplan, I. G.; Dolgounitcheva, O.; Watts, J. D.; Ortiz, J. V. J. Chem. Phys. 2002, 117, 3687. doi: 10.1063/1.1494801 doi: 10.1063/1.1494801
70. [70]
  Roy, D. R.; Chattaraj, P. K. J. Phys. Chem. A 2008, 112, 1612. doi: 10.1021/jp710820c doi: 10.1021/jp710820c
71. [71]
  von Szentpály, L. J. Mol. Model 2017, 23, 217. doi: 10.1007/s00894-017-3383-z doi: 10.1007/s00894-017-3383-z
72. [72]
  Sabzyan, H.; Noorisafa, Z.; Keshavarz, E. Spectrochim. Acta A 2014, 117, 95. doi: 10.1016/j.saa.2013.07.111 doi: 10.1016/j.saa.2013.07.111
73. [73]
  Zakrzewski, V. G.; Dolgounitcheva, O.; Ortiz, J. V. J. Chem. Phys. 1996, 105, 5872. doi: 10.1063/1.472428 doi: 10.1063/1.472428
74. [74]
  Zhu, G. -Z. Wang, L. -S. J. Chem. Phys. 2015, 143, 221102. doi: 10.1063/1.4937761 doi: 10.1063/1.4937761
75. [75]
  Nielsen, S. B.; Nielsen, M. B. J. Chem. Phys. 2003, 119, 10069. doi: 10.1063/1.1618216 doi: 10.1063/1.1618216
76. [76]
  Assadollahzadeh, B.; Thierfelder, C.; Schwerdtfeger, P. Phys. Rev. B 2008, 78, 245423. doi: 10.1103/PhysRevB.78.245423 doi: 10.1103/PhysRevB.78.245423
77. [77]
  Haynes, W. M.; Lide, R. D. Handbook of Chemistry and Physics, 92nd ed.; CRC Press: Boca Raton, FL, USA, 2011-2012.
78. [78]
  Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. Ion Energetics Data in NIST Chemistry Webbook; NIST Standard Reference Database Number 69; National Institute of Standards and Technology: Gaithersburg, Maryland, USA, 2015.
79. [79]
  Richard, R. M.; Marshall, M. S.; Dolgounitcheva, O.; Ortiz, J. V.; Brédas, J. -L.; Marom, N.; Sherrill, C. D. J. Chem. Theory Comput. 2016, 12, 595. doi: 10.1021/acs.jctc.5b00875 doi: 10.1021/acs.jctc.5b00875
80. [80]
  Wang, X. B.; Wang, L. -S. J. Phys. Chem. A 2000, 104, 4429. doi: 10.1021/jp000362t doi: 10.1021/jp000362t
81. [81]
  Gutsev, G. L.; Boldyrev, A. I. Mol. Phys. 1984, 53, 23. doi: 10.1080/00268978400102111 doi: 10.1080/00268978400102111
82. [82]
  von Szentpály, L. J. Phys. Chem. A 2011, 115, 8528. doi: 10.1021/jp203319y doi: 10.1021/jp203319y
83. [83]
  Walsh, N. Multiply-Negatively Charged Aluminum Clusters and Fullerenes; Ph. D. Thesis, Universität Greifswald, Greifswald, Germany, 2008. ub-ed.ub.unigreifswald.de/opus/volltexte/2008/.../ Diss_Walsh.pdf
84. [84]
  Taylor, K. J.; Pettiette-Hall, C. L.; Chesnovsky, O.; Smalley, R. E. J. Chem. Phys. 1992, 96, 3319. doi: 10.1063/1.461927 doi: 10.1063/1.461927
1. [1]
  Jiajia Lv , Jie Gao , Hongyu Li , Zeli Yuan , Nan Dong . Rational design of hydroxytricyanopyrrole-based probes with high affinity and rapid visualization for amyloid-β aggregates in vitro and in vivo. Chinese Chemical Letters, 2024, 35(5): 108940-. doi: 10.1016/j.cclet.2023.108940
2. [2]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
3. [3]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
4. [4]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
5. [5]
  Jiale Zheng , Mei Chen , Huadong Yuan , Jianmin Luo , Yao Wang , Jianwei Nai , Xinyong Tao , Yujing Liu . Electron-microscopical visualization on the interfacial and crystallographic structures of lithium metal anode. Chinese Chemical Letters, 2024, 35(6): 108812-. doi: 10.1016/j.cclet.2023.108812
6. [6]
  Chao Ma , Peng Guo , Zhongmin Liu . DNL-16: A new zeolitic layered silicate unraveled by three-dimensional electron diffraction. Chinese Journal of Structural Chemistry, 2024, 43(4): 100235-100235. doi: 10.1016/j.cjsc.2024.100235
7. [7]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
8. [8]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
9. [9]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
10. [10]
  Wenxiang Ma , Xinyu He , Tianyi Chen , De-Li Ma , Hongzheng Chen , Chang-Zhi Li . Near-infrared non-fused electron acceptors for efficient organic photovoltaics. Chinese Chemical Letters, 2024, 35(4): 109099-. doi: 10.1016/j.cclet.2023.109099
11. [11]
  Shaonan Liu , Shuixing Dai , Minghua Huang . The impact of ester groups on 1,8-naphthalimide electron transport material in organic solar cells. Chinese Journal of Structural Chemistry, 2024, 43(6): 100277-100277. doi: 10.1016/j.cjsc.2023.100277
12. [12]
  Panke Zhou , Hong Yu , Mun Yin Chee , Tao Zeng , Tianli Jin , Hongling Yu , Shuo Wu , Wen Siang Lew , Xiong Chen . Electron push-pull effects induced performance promotion in covalent organic polymer thin films-based memristor for neuromorphic application. Chinese Chemical Letters, 2024, 35(5): 109279-. doi: 10.1016/j.cclet.2023.109279
13. [13]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
14. [14]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
15. [15]
  Tingting Huang , Zhuanlong Ding , Hao Liu , Ping-An Chen , Longfeng Zhao , Yuanyuan Hu , Yifan Yao , Kun Yang , Zebing Zeng . Electron-transporting boron-doped polycyclic aromatic hydrocarbons: Facile synthesis and heteroatom doping positions-modulated optoelectronic properties. Chinese Chemical Letters, 2024, 35(4): 109117-. doi: 10.1016/j.cclet.2023.109117
16. [16]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
17. [17]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
18. [18]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
19. [19]
  Ze-Yuan Ma , Mei Xiao , Cheng-Kun Li , Adedamola Shoberu , Jian-Ping Zou . S-(1,3-Dioxoisoindolin-2-yl)O,O-diethyl phosphorothioate (SDDP): A practical electrophilic reagent for the phosphorothiolation of electron-rich compounds. Chinese Chemical Letters, 2024, 35(5): 109076-. doi: 10.1016/j.cclet.2023.109076
20. [20]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(226)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142