Citation: ZHENG Youkun, JIANG Hui, WANG Xuemei. Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters[J]. Acta Physico-Chimica Sinica, ;2018, 34(7): 740-754. doi: 10.3866/PKU.WHXB201712111 shu

Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters

State Key Laboratory of Bioelectronics, National Demonstration Center for Experimental Biomedical Engineering Education, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, P. R. China

Author Bio:

WANG Xuemei is currently a full professor of Biomedical Engineering, Southeast University. She obtained her PhD in Chemistry from Nanjing University, China in 1994 and became a lecturer in Nanjing University in 1995. She was an Alexander von Humboldt Fellow in the Chemistry Department, University of Saarland, Germany, before she joined the State Key Laboratory of Bioelectronics, Southeast University in 1998. Her research focuses on bioelectronics and biosensors, biomaterials for multimode bioimaging and nanomedicine
Corresponding author: WANG Xuemei, xuewang@seu.edu.cn
Received Date: 9 November 2017
Revised Date: 7 December 2017
Accepted Date: 7 December 2017
Available Online: 11 July 2017
Fund Project: the National Natural Science Foundation of China 81325011The project was supported by the National High Technology Research and Development Program of China 2015AA020502the National Key Research and Development Program of China 2017YFA0205300the National Natural Science Foundation of China 21175020The project was supported by the National High Technology Research and Development Program of China (2015AA020502), the National Key Research and Development Program of China (2017YFA0205300) and the National Natural Science Foundation of China (81325011, 21175020)

Alloy metal nanoclusters (NCs), including bimetallic and multimetallic clusters, have recently emerged as a novel class of multifunctional nanomaterials. They are widely used in catalysis, optical sensing, and biological imaging due to their excellent physicochemical properties such as unique electronic structure, ultrasmall size, strong photoluminescence, and rich surface chemistry. Although much progress has been made in the development of NCs, a major challenge in the synthesis of the relevant multifunctional nanomaterial is to achieve the synthetic methodological breakthrough, especially for controlling the synthesis and structure of NCs with atomic precision. It is evident that by realizing controlled synthesis and structural regulation at the atomic scale, we can better understand and tune the fundamental properties of NCs for efficient use in various application areas; this could also shed light on the development of new functionalized nanomaterials. Most of the recent research on the controlled synthesis and structural characterization of metal clusters with atomic precision has focused on monometallic NCs, and significant progress has been realized with respect to alloy metal NCs. A number of synthetic strategies have been developed for synthesizing high-quality alloy NCs with well-defined compositions, sizes, and architectures. In this review, we have highlighted some recent advances in strategies for the precise synthesis of ligands-protected alloy metal NCs, especially thiolate-stabilized gold-based alloy NCs. We classified the synthetic strategies for alloy NCs into several strategies, which include one-pot synthesis, metal exchange, ligand exchange, chemical etching, intercluster reactions, surface motif exchange reaction, and in situ two-phase ligand exchange strategy. One-pot synthesis is facile and widely used as a synthetic strategy for monodisperse alloy NCs with well-defined compositions, sizes, architectures, and surface chemistries. However, the alloy NCs obtained through the one-pot strategy often exhibits a relatively somber fluorescence. Therefore, other synthesis strategies have been exploited that can fabricate alloy NCs exhibiting strong photoluminescence. Among them, the surface motif exchange reaction is expected to be extended to the fabrication of new binary alloy NCs with precise alloy sites to broaden the physicochemical properties of the NCs; intercluster reactions has been explored as an emerging and efficient strategy to fabricate atomically precise alloy NCs. It is noted that the two or multiple metal species incorporated in a single alloy NC usually show unexpected synergistic properties like adjustable electronic structures and strong photoluminescence. Such unique properties have rapidly motivated the research community to use alloy NCs in many applications such as catalysis, biosensors, and biomedicine.
- Alloy nanoclusters,
- Atomically precise,
- Synthetic strategy,
- Crystal structure
1. [1]
  Zhang, L.; Wang, E. Nano Today 2014, 9, 132. doi: 10.1016/j.nantod.2014.02.010 doi: 10.1016/j.nantod.2014.02.010
2. [2]
  Tao, Y.; Li, M.; Ren, J.; Qu, X.Chem. Soc. Rev. 2015, 44, 8636. doi: 10.1039/C5CS00607D doi: 10.1039/C5CS00607D
3. [3]
  Yang, X.; Yang, M.; Pang, B.; Vara, M.; Xia, Y. Chem. Rev. 2015, 115, 10410. doi: 10.1021/acs.chemrev.5b00193 doi: 10.1021/acs.chemrev.5b00193
4. [4]
  Zheng, Y.; Lai, L.; Liu, W.; Jiang, H.; Wang, X. Adv. Colloid Interface Sci. 2017, 242, 1. doi: 10.1016/j.cis.2017.02.005 doi: 10.1016/j.cis.2017.02.005
5. [5]
  Liu, P.; Qin, R.; Fu, G.; Zheng, N. J. Am. Chem. Soc. 2017, 139, 2122. doi: 10.1021/jacs.6b10978 doi: 10.1021/jacs.6b10978
6. [6]
  Tian, Z.; Cheng, L. Nanoscale 2016, 8, 826. doi: 10.1039/C5NR05020K doi: 10.1039/C5NR05020K
7. [7]
  Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2008, 130, 5883. doi: 10.1021/ja801173r doi: 10.1021/ja801173r
8. [8]
  Zhu, M.; Aikens, C. M.; Hendrich, M. P.; Gupta, R.; Qian, H.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2009, 131, 2490. doi: 10.1021/ja809157f doi: 10.1021/ja809157f
9. [9]
  Luo, Z.; Yuan, X.; Yu, Y.; Zhang, Q.; Leong, D. T.; Lee, J. Y.; Xie, J. J. Am. Chem. Soc. 2012, 134, 16662. doi: 10.1021/ja306199p doi: 10.1021/ja306199p
10. [10]
  Xie, J.; Zheng, Y.; Ying, J. Y. J. Am. Chem. Soc. 2009, 131, 888. doi: 10.1021/ja806804u doi: 10.1021/ja806804u
11. [11]
  Jiang, H.; Su, X.; Zhang, Y.; Zhou, J.; Fang, D.; Wang, X. Anal. Chem. 2016, 88, 4766. doi: 10.1021/acs.analchem.6b00112 doi: 10.1021/acs.analchem.6b00112
12. [12]
  Jiang, H.; Liu, L.; Wang, X. Nanoscale 2017, 9, 9792. doi: 10.1039/C7NR03382F doi: 10.1039/C7NR03382F
13. [13]
  Zhu, Y.; Qian, H.; Jin, R. J. Mater. Chem. 2011, 21, 6793. doi: 10.1039/C1JM10082C doi: 10.1039/C1JM10082C
14. [14]
  Wang, C.; Li, J.; Amatore, C.; Chen, Y.; Jiang, H.; Wang, X. Angew. Chem. Int. Ed. 2011, 50, 11644. doi: 10.1002/anie.201105573 doi: 10.1002/anie.201105573
15. [15]
  Zhang, Y.; Jiang, H.; Wang, X. Anal. Chim. Acta 2015, 870, 1. doi: 10.1016/j.aca.2015.01.016 doi: 10.1016/j.aca.2015.01.016
16. [16]
  Su, X.; Jiang, H.; Wang, X. Anal. Chem. 2015, 87, 10230. doi: 10.1021/acs.analchem.5b02559 doi: 10.1021/acs.analchem.5b02559
17. [17]
  Chen, Y. S.; Kamat, P. V. J. Am. Chem. Soc. 2014, 136, 6075. doi: 10.1021/ja5017365 doi: 10.1021/ja5017365
18. [18]
  Jin, R.; Zeng, C.; Zhou, M.; Chen, Y. Chem. Rev. 2016, 116, 10346. doi: 10.1021/acs.chemrev.5b00703 doi: 10.1021/acs.chemrev.5b00703
19. [19]
  Wang, X.; Cai, X.; Hu, J.; Shao, N.; Wang, F.; Zhang, Q.; Xiao, J.; Cheng, Y. J. Am. Chem. Soc. 2013, 135, 9805. doi: 10.1021/ja402903h doi: 10.1021/ja402903h
20. [20]
  Chen, D.; Luo, Z.; Li, N.; Lee, J. Y.; Xie, J.; Lu, J. Adv. Funct. Mater. 2013, 23, 4324. doi: 10.1002/adfm.201300411 doi: 10.1002/adfm.201300411
21. [21]
  Gottlieb, E.; Qian, H.; Jin, R. Chem. Eur. J. 2013, 19, 4238. doi: 10.1002/chem.201203158 doi: 10.1002/chem.201203158
22. [22]
  Li, Q.; Wang, S.; Kirschbaum, K.; Lambright, K. J.; Das, A.; Jin, R. Chem. Commun. 2016, 52, 5194. doi: 10.1039/C6CC01243D doi: 10.1039/C6CC01243D
23. [23]
  Kang, X.; Zhou, M.; Wang, S.; Jin, S.; Sun, G.; Zhu, M.; Jin, R. Chem. Sci. 2017, 8, 2581. doi: 10.1039/C6SC05104A doi: 10.1039/C6SC05104A
24. [24]
  Li, G., Jin, R. Catal. Today 2016, 278, 187. doi: 10.1016/j.cattod.2015.11.019 doi: 10.1016/j.cattod.2015.11.019
25. [25]
  Yan, J.; Su, H.; Yang, H.; Hu, C.; Malola, S.; Lin, S.; Teo, B. K.; H kkinen, H.; Zheng, N. J. Am. Chem. Soc. 2016, 138, 12751. doi: 10.1021/jacs.6b08100 doi: 10.1021/jacs.6b08100
26. [26]
  Zhang, Y.; Jiang, H.; Ge, W.; Li, Q.; Wang, X. Langmuir 2014, 30, 10910. doi: 10.1021/la5028702 doi: 10.1021/la5028702
27. [27]
  Huang, J.; Zhu, Y.; Lin, M.; Wang, Q.; Zhao, L.; Yang, Y.; Yao, K.; Han, Y. J. Am. Chem. Soc. 2013, 135, 8552. doi: 10.1021/ja4004602 doi: 10.1021/ja4004602
28. [28]
  Wang, S.; Meng, X.; Das, A.; Li, T.; Song, Y.; Cao, T.; Zhu, X.; Zhu, M.; Jin, R. Angew. Chem. Int. Ed. 2014, 53, 2376. doi: 10.1002/anie.201307480 doi: 10.1002/anie.201307480
29. [29]
  Wang, D.; Li, Y. Adv. Mater.2011, 23, 1044. doi: 10.1002/adma.201003695 doi: 10.1002/adma.201003695
30. [30]
  Qian, H.; Jiang, D. E.; Li, G.; Gayathri, C.; Das, A.; Gil, R. R.; Jin, R. J. Am. Chem. Soc. 2012, 134, 16159. doi: 10.1021/ja307657a doi: 10.1021/ja307657a
31. [31]
  Jin, R.; Nobusada, K. Nano Res. 2014, 7, 285. doi: 10.1007/s12274-014-0403-5 doi: 10.1007/s12274-014-0403-5
32. [32]
  Jin, R.; Zhao, S.; Xing, Y.; Jin, R. CrystEngComm 2016, 18, 3996. doi: 10.1039/C5CE02494C doi: 10.1039/C5CE02494C
33. [33]
  Zhang, H.; Watanabe, T.; Okumura, M.; Haruta, M.; Toshima, N. Nat. Mater. 2012, 11, 49. doi: 10.1038/NMAT3143 doi: 10.1038/NMAT3143
34. [34]
  Yang, H.; Wang, Y.; Huang, H.; Gell, L.; Lehtovaara, L.; Malola, S.; H kkinen, H.; Zheng, N. Nat. Commun.2013, 4, 2422. doi: 10.1038/ncomms3422 doi: 10.1038/ncomms3422
35. [35]
  Chakraborty, I.; Pradeep, T. Chem. Rev. 2017, 117, 8208. doi: 10.1021/acs.chemrev.6b00769 doi: 10.1021/acs.chemrev.6b00769
36. [36]
  Kurashige, W.; Niihori, Y.; Sharma, S.; Negishi, Y. Coord. Chem. Rev. 2016, 320, 238. doi: 10.1016/j.ccr.2016.02.013 doi: 10.1016/j.ccr.2016.02.013
37. [37]
  Sun, G.; Kang, X.; Jin, S.; Li, X.; Hu, D.; Wang, S.; Zhu, M. Acta Phys.-Chim. Sin. 2018, 34(7), 799. doi: 10.3866/PKU.WHXB201710124
38. [38]
  Kumara, C.; Dass, A. Nanoscale 2012, 4, 4084. doi: 10.1039/c2nr11781a doi: 10.1039/c2nr11781a
39. [39]
  Qian, H.; Barry, E.; Zhu, Y.; Jin, R. Acta Phys.-Chim. Sin. 2011, 27, 513. doi: 10.3866/PKU.WHXB20110304 doi: 10.3866/PKU.WHXB20110304
40. [40]
  Wan, X. K.; Cheng, X. L.; Tang, Q.; Han, Y. Z.; Hu, G.; Jiang, D. E.; Wang, Q. M. J. Am. Chem. Soc. 2017, 139, 9451. doi: 10.1021/jacs.7b04622 doi: 10.1021/jacs.7b04622
41. [41]
  Bootharaju, M. S.; Kozlov, S. M.; Cao, Z.; Harb, M.; Maity, N.; Shkurenko, A.; Parida, M. R.; Hedhili, M. N.; Eddaoudi, M.; Mohammed, O. F.; et al. J. Am. Chem. Soc. 2017, 139, 1053. doi: 10.1021/jacs.6b11875 doi: 10.1021/jacs.6b11875
42. [42]
  Yamazoe, S.; Kurashige, W.; Nobusada, K.; Negishi, Y.; Tsukuda, T. J. Phys. Chem. C 2014, 118, 25284. doi: 10.1021/jp5085372 doi: 10.1021/jp5085372
43. [43]
  Yang, S.; Wang, S.; Jin, S.; Chen, S.; Sheng, H.; Zhu, M. Nanoscale 2015, 7, 10005. doi: 10.1039/c5nr01965f doi: 10.1039/c5nr01965f
44. [44]
  Kwak, K.; Choi, W.; Tang, Q.; Kim, M.; Lee, Y.; Jiang, D. E.; Lee, D. Nat. Commun. 2017, 8, 14723. doi: 10.1038/ncomms14723 doi: 10.1038/ncomms14723
45. [45]
  Chai, J.; Lv, Y.; Yang, S.; Song, Y.; Zan, X.; Li, Q.; Yu, H.; Wu, M.; Zhu, M. J. Phys. Chem. C, 2017, 121, 21665. doi: 10.1021/acs.jpcc.7b05074 doi: 10.1021/acs.jpcc.7b05074
46. [46]
  Kumara, C.; Gagnon, K. J.; Dass, A. J. Phys. Chem. Lett. 2015, 6, 1223. doi: 10.1021/acs.jpclett.5b00270 doi: 10.1021/acs.jpclett.5b00270
47. [47]
  Kumara, C.; Dass, A. Nanoscale 2011, 3, 3064. doi: 10.1039/C1NR10429B doi: 10.1039/C1NR10429B
48. [48]
  Koivisto, J.; Malola, S.; Kumara, C.; Dass, A.; Häkkinen, H.; Pettersson, M. J. Phys. Chem. Lett.2012, 3, 3076. doi: 10.1021/jz301261x doi: 10.1021/jz301261x
49. [49]
  Sharma, S.; Kurashige, W.; Nobusada, K.; Negishi, Y. Nanoscale 2015, 7, 10606. doi: 10.1039/c5nr01491c doi: 10.1039/c5nr01491c
50. [50]
  Yan, J.; Su, H.; Yang, H.; Malola, S.; Lin, S.; Häkkinen, H.; Zheng, N. J. Am. Chem. Soc. 2015, 137, 11880. doi: 10.1021/jacs.5b07186 doi: 10.1021/jacs.5b07186
51. [51]
  Wang, Y.; Su, H.; Xu, C.; Li, G.; Gell, L.; Lin, S.; Tang, Z.; Häkkinen, H.; Zheng, N. J. Am. Chem. Soc. 2015, 137, 4324. doi: 10.1021/jacs.5b01232 doi: 10.1021/jacs.5b01232
52. [52]
  Bhat, S.; Baksi, A.; Mudedla, S. K.; Natarajan, G.; Subramanian, V.; Pradeep, T. J. Phys. Chem. Lett. 2017, 8, 2787. doi: 10.1021/acs.jpclett.7b01052 doi: 10.1021/acs.jpclett.7b01052
53. [53]
  Yan, N.; Liao, L.; Yuan, J.; Lin, Y. J.; Weng, L. H.; Yang, J.; Wu, Z. Chem. Mater. 2016, 28, 8240. doi: 10.1021/acs.chemmater.6b03132 doi: 10.1021/acs.chemmater.6b03132
54. [54]
  Zeng, J. L.; Guan, Z. J.; Du, Y.; Nan, Z. A.; Lin, Y. M.; Wang, Q. M. J. Am. Chem. Soc. 2016, 138, 7848. doi: 10.1021/jacs.6b04471 doi: 10.1021/jacs.6b04471
55. [55]
  Biltek, S. R.; Reber, A. C.; Khanna, S. N.; Sen, A. J. Phys. Chem. A 2017, 121, 5324. doi: 10.1021/acs.jpca.7b04669 doi: 10.1021/acs.jpca.7b04669
56. [56]
  Yao, C.; Lin, Y. J.; Yuan, J.; Liao, L.; Zhu, M.; Weng, L.; Yang, J.; Wu, Z. J. Am. Chem. Soc. 2015, 137, 15350. doi: 10.1021/jacs.5b09627 doi: 10.1021/jacs.5b09627
57. [57]
  Tofanelli, M. A.; Ni, T. W.; Phillips, B. D.; Ackerson, C. J. Inorg. Chem. 2016, 55, 999. doi: 10.1021/acs.inorgchem.5b02106 doi: 10.1021/acs.inorgchem.5b02106
58. [58]
  Fernández, E. J.; Laguna, A.; López-de-Luzuriaga, J. M.; Monge, M.; Olmos, M. E.; Puelles, R. C. J. Phys. Chem. B 2005, 109, 20652. doi: 10.1021/jp055007n doi: 10.1021/jp055007n
59. [59]
  Negishi, Y.; Iwai, T.; Ide, M. Chem. Commun. 2010, 46, 4713. doi: 10.1039/c0cc01021a doi: 10.1039/c0cc01021a
60. [60]
  Kauffman, D. R.; Alfonso, D.; Matranga, C.; Qian, H.; Jin, R. J. Phys. Chem. C 2013, 117, 7914. doi: 10.1021/jp4013224 doi: 10.1021/jp4013224
61. [61]
  Dou, X.; Yuan, X.; Yao, Q.; Luo, Z.; Zheng, K.; Xie, J. Chem. Commun. 2014, 50, 7459. doi: 10.1039/C4CC02261K doi: 10.1039/C4CC02261K
62. [62]
  Yuan, X.; Zhang, B.; Luo, Z.; Yao, Q.; Leong, D. T.; Yan, N.; Xie, J. Angew. Chem. Int. Ed. 2014, 126, 4711. doi: 10.1002/ange.201311177 doi: 10.1002/ange.201311177
63. [63]
  Chen, T.; Yang, S.; Chai, J.; Song, Y.; Fan, J.; Rao, B.; Sheng, H.; Yu, H.; Zhu, M. Sci. Adv. 2017, 3, e1700956. doi: 10.1126/sciadv.1700956 doi: 10.1126/sciadv.1700956
64. [64]
  Wang, Z.; Senanayake, R.; Aikens, C. M.; Chen, W. M.; Tung, C. H.; Sun, D. Nanoscale 2016, 8, 18905. doi: 10.1039/c6nr06615a doi: 10.1039/c6nr06615a
65. [65]
  Wang, Y.; Wan, X. K.; Ren, L.; Su, H.; Li, G.; Malola, S.; Lin, S.; Tang, Z.; Häkkinen, H.; Teo, B. K.; et al. J. Am. Chem. Soc. 2016, 138, 3278. doi: 10.1021/jacs.5b12730 doi: 10.1021/jacs.5b12730
66. [66]
  Wang, S.; Jin, S.; Yang, S.; Chen, S.; Song, Y.; Zhang, J.; Zhu, M. Sci. Adv. 2015, 1, e1500441. doi: 10.1126/sciadv.1500441 doi: 10.1126/sciadv.1500441
67. [67]
  Ataee-Esfahani, H.; Wang, L.; Nemoto, Y.; Yamauchi, Y. Chem. Mater. 2010, 22, 6310. doi: 10.1021/cm102074w doi: 10.1021/cm102074w
68. [68]
  Crooks, R. M.; Zhao, M.; Sun, L.; Chechik, V.; Yeung, L. K. Acc. Chem. Res. 2011, 34, 181. doi: 10.1021/ar000110 doi: 10.1021/ar000110
69. [69]
  Formo, E.; Lee, E.; Campbell, D.; Xia, Y. Nano Lett. 2008, 8, 668. doi: 10.1021/nl073163v doi: 10.1021/nl073163v
70. [70]
  Christensen, S. L.; MacDonald, M. A.; Chatt, A.; Zhang, P.; Qian, H.; Jin, R. J. Phys. Chem. C 2012, 116, 26932. doi: 10.1021/jp310183x doi: 10.1021/jp310183x
71. [71]
  Kwak, K.; Tang, Q.; Kim, M.; Jiang, D. E.; Lee, D. J. Am. Chem. Soc. 2015, 137, 10833. doi: 10.1021/jacs.5b06946 doi: 10.1021/jacs.5b06946
72. [72]
  Zhao, Y.; Ye, C.; Liu, W.; Chen, R.; Jiang, X. Angew. Chem. Int. Ed. 2014, 53, 8127. doi: 10.1002/anie.201401035 doi: 10.1002/anie.201401035
73. [73]
  Zhou, M.; Qian, H.; Sfeir, M. Y.; Nobusada, K.; Jin, R. Nanoscale 2016, 8, 7163. doi: 10.1039/c6nr01008c doi: 10.1039/c6nr01008c
74. [74]
  Negishi, Y.; Kurashige, W.; Niihori, Y.; Iwasa, T.; Nobusada, K. Phys. Chem. Chem. Phys. 2010, 12, 6219. doi: 10.1039/b927175a doi: 10.1039/b927175a
75. [75]
  Negishi, Y.; Kurashige, W.; Kobayashi, Y.; Yamazoe, S.; Kojima, N.; Seto, M.; Tsukuda, T. J. Phys. Chem. Lett. 2013, 4, 3579. doi: 10.1021/jz402030n doi: 10.1021/jz402030n
76. [76]
  Negishi, Y.; Igarashi, K.; Munakata, K.; Ohgake, W.; Nobusada, K. Chem. Commun. 2012, 48, 660. doi: 10.1039/c1cc15765e doi: 10.1039/c1cc15765e
77. [77]
  Kang, X.; Xiang, J.; Lv, Y.; Du, W.; Yu, H.; Wang, S.; Zhu, M. Chem. Mater. 2017, 29, 6856. doi: 10.1021/acs.chemmater.7b02015 doi: 10.1021/acs.chemmater.7b02015
78. [78]
  Kurashige, W.; Negishi, Y. J. Clust. Sci. 2012, 23, 365. doi: 10.1007/s10876-011-0437-8 doi: 10.1007/s10876-011-0437-8
79. [79]
  Baksi, A.; Pradeep, T. Nanoscale 2013, 5, 12245. doi: 10.1039/C3NR04257J doi: 10.1039/C3NR04257J
80. [80]
  Kurashige, W.; Munakata, K.; Nobusada, K.; Negishi, Y. Chem. Commun. 2013, 49, 5447. doi: 10.1039/C3CC41210E doi: 10.1039/C3CC41210E
81. [81]
  Dharmaratne, A. C.; Dass, A. Chem. Commun. 2014, 50, 1722. doi: 10.1039/c3cc47060a doi: 10.1039/c3cc47060a
82. [82]
  Negishi, Y.; Munakata, K.; Ohgake, W.; Nobusada, K. J. Phys. Chem. Lett. 2012, 3, 2209. doi: 10.1021/jz300892w doi: 10.1021/jz300892w
83. [83]
  Yang, H.; Wang, Y.; Lei, J.; Shi, L.; Wu, X.; Mäkinen, V.; Lin, S.; Tang, Z.; He, J.; Häkkinen, H.; et al. J. Am. Chem. Soc. 2013, 135, 9568. doi: 10.1021/ja402249s doi: 10.1021/ja402249s
84. [84]
  Yang, H.; Wang, Y.; Yan, J.; Chen, X.; Zhang, X.; Häkkinen, H.; Zheng, N. J. Am. Chem. Soc. 2014, 136, 7197. doi: 10.1021/ja501811j doi: 10.1021/ja501811j
85. [85]
  Shen, H.; Mizuta, T. Chem.-Asian J., 2017, doi: 10.1002/asia.201701337 doi: 10.1002/asia.201701337
86. [86]
  Biltek, S. R.; Mandal, S.; Sen, A.; Reber, A. C.; Pedicini, A. F.; Khanna, S. N. J. Am. Chem. Soc. 2012, 135, 26. doi: 10.1021/ja308884s doi: 10.1021/ja308884s
87. [87]
  Liu, X.; Astruc, D. Adv. Mater. 2017, 29, 1605305. doi: 10.1002/adma.201605305 doi: 10.1002/adma.201605305
88. [88]
  Oh, M. H.; Yu, T.; Yu, S. H.; Lim, B.; Ko, K. T.; Willinger, M. G.; Seo, D. H.; Kim, B. H.; Cho, M. G.; Park, J. H.; et al. Science 2013, 340, 964. doi: 10.1126/science.1234751 doi: 10.1126/science.1234751
89. [89]
  Zhang, H.; Jin, M.; Wang, J.; Li, W.; Camargo, P. H.; Kim, M. J.; Yang, D.; Xie, Z.; Xia, Y. J. Am. Chem. Soc. 2011, 133, 6078. doi: 10.1021/ja201156s doi: 10.1021/ja201156s
90. [90]
  Murugadoss, A.; Kai, N.; Sakurai, H. Nanoscale 2012, 4, 1280. doi: 10.1039/c2nr11727d doi: 10.1039/c2nr11727d
91. [91]
  Mohanty, J. S.; Xavier, P. L.; Chaudhari, K.; Bootharaju, M. S.; Goswami, N.; Pal, S. K.; Pradeep, T. Nanoscale2012, 4, 4255. doi: 10.1039/c2nr30729d doi: 10.1039/c2nr30729d
92. [92]
  Bootharaju, M. S.; Joshi, C. P.; Parida, M. R.; Mohammed, O. F.; Bakr, O. M. Angew. Chem. Int. Ed. 2016, 55, 922. doi: 10.1002/anie.201509381 doi: 10.1002/anie.201509381
93. [93]
  Udayabhaskararao, T.; Sun, Y.; Goswami, N.; Pal, S. K.; Balasubramanian, K.; Pradeep, T. Angew. Chem. Int. Ed. 2012, 51, 2155. doi: 10.1002/anie.201107696 doi: 10.1002/anie.201107696
94. [94]
  Du, W.; Jin, S.; Xiong, L.; Chen, M.; Zhang, J.; Zou, X.; Pei, Y.; Wang, S.; Zhu, M. J. Am. Chem. Soc. 2017, 139, 1618. doi: 10.1021/jacs.6b11681 doi: 10.1021/jacs.6b11681
95. [95]
  Kang, X.; Xiong, L.; Wang, S.; Yu, H.; Jin, S.; Song, Y.; Chen, T.; Zheng, L.; Pan, C.; Pei, Y.; et al.Chem.-Eur. J. 2016, 22, 17145. doi: 10.1002/chem.201603893 doi: 10.1002/chem.201603893
96. [96]
  Choi, J. P.; Fields-Zinna, C. A.; Stiles, R. L.; Balasubramanian, R.; Douglas, A. D.; Crowe, M. C.; Murray, R. W. J. Phys. Chem. C 2010, 114, 15890. doi: 10.1021/jp9101114 doi: 10.1021/jp9101114
97. [97]
  Wu, Z. Angew. Chem. Int. Ed. 2012, 51, 2934. doi: 10.1002/anie.201107822 doi: 10.1002/anie.201107822
98. [98]
  Wang, S.; Song, Y.; Jin, S.; Liu, X.; Zhang, J.; Pei, Y.; Meng, X.; Chen, M.; Li, P.; Zhu, M. J. Am. Chem. Soc. 2015, 137, 4018. doi: 10.1021/ja511635g doi: 10.1021/ja511635g
99. [99]
  Li, Q.; Luo, T. Y.; Taylor, M. G.; Wang, S.; Zhu, X.; Song, Y.; Mpourmpakis, G.; Rosi, N. L.; Jin, R. Sci. Adv. 2017, 3, e1603193. doi: 10.1126/sciadv.1603193 doi: 10.1126/sciadv.1603193
100. [100]
  Yang, S.; Chai, J.; Chen, T.; Rao, B.; Pan, Y.; Yu, H.; Zhu, M. Inorg. Chem. 2017, 56, 1771. doi: 10.1021/acs.inorgchem.6b02016 doi: 10.1021/acs.inorgchem.6b02016
101. [101]
  Kang, X.; Silalai, C.; Lv, Y.; Sun, G.; Chen, S.; Yu, H.; Xu, F.; Zhu, M. Eur. J. Inorg. Chem. 2017, 2017, 1414. doi: 10.1002/ejic.201601513 doi: 10.1002/ejic.201601513
102. [102]
  Wang, M.; Wu, Z.; Chu, Z.; Yang, J.; Yao, C. Chem.-Asian J. 2014, 9, 1006. doi: 10.1002/asia.201301562 doi: 10.1002/asia.201301562
103. [103]
  Tian, S.; Yao, C.; Liao, L.; Xia, N.; Wu, Z. Chem. Commun. 2015, 51, 11773. doi: 10.1039/c5cc03267a doi: 10.1039/c5cc03267a
104. [104]
  Lin, C. A. J.; Yang, T. Y.; Lee, C. H.; Huang, S. H.; Sperling, R. A.; Zanella, M.; Li, J. K.; Shen, J. L.; Wang, H. H.; Yeh, H. I.; et al. ACS Nano 2009, 3, 395. doi: 10.1021/nn800632j doi: 10.1021/nn800632j
105. [105]
  Shang, L.; Dong, S.; Nienhaus, G. Nano Today 2011, 6, 401. doi: 10.1016/j.nantod.2011.06.004 doi: 10.1016/j.nantod.2011.06.004
106. [106]
  Wu, Z.; Jin, R. Nano Lett.2010, 10, 2568. doi: 10.1021/nl101225f doi: 10.1021/nl101225f
107. [107]
  Xiang, J.; Li, P.; Song, Y.; Liu, X.; Chong, H.; Jin, S.; Pei, Y.; Yuan, X.; Zhu, M. Nanoscale 2015, 7, 18278. doi: 10.1039/c5nr05131b doi: 10.1039/c5nr05131b
108. [108]
  Fan, J.; Song, Y.; Chai, J.; Yang, S.; Chen, T.; Rao, B.; Yu, H.; Zhu, M. Nanoscale 2016, 8, 15317. doi: 10.1039/c6nr04255d doi: 10.1039/c6nr04255d
109. [109]
  Li, Q.; Taylor, M. G.; Kirschbaum, K.; Lambright, K. J.; Zhu, X.; Mpourmpakis, G.; Jin, R. J. Colloid Interface Sci. 2017, 505, 1202. doi: 10.1016/j.jcis.2017.06.049 doi: 10.1016/j.jcis.2017.06.049
110. [110]
  Sels, A.; Salassa, G.; Pollitt, S.; Guglieri, C.; Rupprechter, G.; Barrabés, N.; Bürgi, T. J. Phys. Chem. C 2017, 121, 10919. doi: 10.1021/acs.jpcc.6b12066 doi: 10.1021/acs.jpcc.6b12066
111. [111]
  Niihori, Y.; Kikuchi, Y.; Kato, A.; Matsuzaki, M.; Negishi, Y. ACS Nano 2015, 9, 9347. doi: 10.1021/acsnano.5b03435 doi: 10.1021/acsnano.5b03435
112. [112]
  Kothalawala, N.; Kumara, C.; Ferrando, R.; Dass, A. Chem. Commun. 2013, 49, 10850. doi: 10.1039/c3cc45669b doi: 10.1039/c3cc45669b
113. [113]
  Jupally, V. R.; Dass, A. Phys. Chem. Chem. Phys. 2014, 16, 10473. doi: 10.1039/c3cp54343a doi: 10.1039/c3cp54343a
114. [114]
  Krishnadas, K. R.; Ghosh, A.; Baksi, A.; Chakraborty, I.; Natarajan, G.; Pradeep, T. J. Am. Chem. Soc.2015, 138, 140. doi: 10.1021/jacs.5b09401 doi: 10.1021/jacs.5b09401
115. [115]
  Krishnadas, K. R.; Baksi, A.; Ghosh, A.; Natarajan, G.; Pradeep, T. Nat. Commun. 2016, 7, 13447. doi: 10.1038/ncomms13447 doi: 10.1038/ncomms13447
116. [116]
  Krishnadas, K. R.; Baksi, A.; Ghosh, A.; Natarajan, G.; Pradeep, T. ACS Nano 2017, 11, 6015. doi: 10.1021/acsnano.7b01912 doi: 10.1021/acsnano.7b01912
117. [117]
  Krishnadas, K. R.; Baksi, A.; Ghosh, A.; Natarajan, G.; Som, A.; Pradeep, T. Acc. Chem. Res. 2017, 50, 1988. doi: 10.1021/acs.accounts.7b00224 doi: 10.1021/acs.accounts.7b00224
118. [118]
  Krishnadas, K. R.; Ghosh, D.; Ghosh, A.; Natarajan, G.; Pradeep, T. J. Phys. Chem. C 2017, 121, 23224. doi: 10.1021/acs.jpcc.7b07605 doi: 10.1021/acs.jpcc.7b07605
119. [119]
  Yang, S.; Chai, J.; Song, Y.; Fan, J.; Chen, T.; Wang, S.; Yu, H.; Li, X.; Zhu, M. J. Am. Chem. Soc. 2017, 139, 5668. doi: 10.1021/jacs.7b00668 doi: 10.1021/jacs.7b00668
120. [120]
  Chai, J.; Lv, Y.; Yang, S.; Song, Y.; Zan, X.; Li, Q.; Yu, H.; Wu, M.; Zhu, M. J. Phys. Chem. C 2017, 121, 21665. doi: 10.1021/acs.jpcc.7b05074 doi: 10.1021/acs.jpcc.7b05074
121. [121]
  Yao, Q.; Feng, Y.; Fung, V.; Yu, Y.; Jiang, D. E.; Yang, J.; Xie, J. Nat. Commun. 2017, 8, 1555. doi: 10.1038/s41467-017-01736-5 doi: 10.1038/s41467-017-01736-5
1. [1]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
2. [2]
  Tiantian Li , Ruochen Jin , Bin Wu , Dongming Lan , Yunjian Ma , Yonghua Wang . A novel insight of enhancing the hydrogen peroxide tolerance of unspecific peroxygenase from Daldinia caldariorum based on structure. Chinese Chemical Letters, 2024, 35(4): 108701-. doi: 10.1016/j.cclet.2023.108701
3. [3]
  Peng Chen , Lijuan Liang , Yufei Zhu , Zhimin Xing , Zhenhua Jia , Teck-Peng Loh . Strategies for constructing seven-membered rings: Applications in natural product synthesis. Chinese Chemical Letters, 2024, 35(6): 109229-. doi: 10.1016/j.cclet.2023.109229
4. [4]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
5. [5]
  Xinyi Cao , Yucheng Jin , Hailong Wang , Xu Ding , Xiaolin Liu , Baoqiu Yu , Xiaoning Zhan , Jianzhuang Jiang . A tetraaldehyde-derived porous organic cage and covalent organic frameworks: Syntheses, structures, and iodine vapor capture. Chinese Chemical Letters, 2024, 35(9): 109201-. doi: 10.1016/j.cclet.2023.109201
6. [6]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
7. [7]
  Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
8. [8]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
9. [9]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
10. [10]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
11. [11]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
12. [12]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
13. [13]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
14. [14]
  Zhaojun Liu , Zerui Mu , Chuanbo Gao . Alloy nanocrystals: Synthesis paradigms and implications. Chinese Journal of Structural Chemistry, 2023, 42(11): 100156-100156. doi: 10.1016/j.cjsc.2023.100156
15. [15]
  Shehla Khalid , Muhammad Bilal , Nasir Rasool , Muhammad Imran . Photochemical reactions as synthetic tool for pharmaceutical industries. Chinese Chemical Letters, 2024, 35(9): 109498-. doi: 10.1016/j.cclet.2024.109498
16. [16]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
17. [17]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
18. [18]
  Rakesh Kumar Gupta , Zhi Wang , Di Sun . Shining bright: Revolutionary near-unity NIR phosphorescent metal nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(11): 100417-100417. doi: 10.1016/j.cjsc.2024.100417
19. [19]
  Chunqing Ou , Meijia Xiao , Xinyue Zheng , Xianzhou Huang , Suleixin Yang , Yingying Leng , Xiaowei Liu , Xiuqi Liang , Linjiang Song , Yanjie You , Shaohua Yao , Changyang Gong . Programmable double-unlock nanocomplex self-supplies phenylalanine ammonia-lyase for precise phenylalanine deprivation of tumors. Chinese Chemical Letters, 2024, 35(8): 109275-. doi: 10.1016/j.cclet.2023.109275
20. [20]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2023.100197

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(566)
HTML views(80)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142