Citation: XU Wenwu, GAO Yi. Thiolate-Protected Hollow Gold Nanospheres[J]. Acta Physico-Chimica Sinica, ;2018, 34(7): 770-775. doi: 10.3866/PKU.WHXB201711061 shu

Thiolate-Protected Hollow Gold Nanospheres

XU Wenwu ,
GAO Yi ^,

Division of Interfacial Water and Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, P. R. China

Corresponding author: GAO Yi, gaoyi@sinap.ac.cn
Received Date: 11 October 2017
Revised Date: 1 November 2017
Accepted Date: 2 November 2017
Available Online: 6 July 2017
Fund Project: the National Natural Science Foundation of China 21773287the National Natural Science Foundation of China 11504396The project was supported by the National Natural Science Foundation of China (11504396, 21773287)

We present the atomic structure of thiolate-protected hollow Au nanosphere (HAuNS), Au₆₀(SR)₂₀, with high symmetry and stability based on the grand unified model (GUM; Nat. Commun. 2016, 7, 13574) and density-functional theory (DFT) calculations. Using C₂₀ fullerene (with I_h symmetry) as a template, 20 tetrahedral Au₄ units were used to replace the C atoms of C₂₀, and three Au atoms of each Au₄ were fused with three neighboring Au₄ units by sharing one Au atom to form an icosahedral Au₅₀ fullerene cage as the inner core. Subsequently, the unfused Au atom in each Au₄ was bonded with the [―RS―Au―SR―] staple to form the completely hollow Au₆₀(SR)₂₀ nanosphere. Therefore, the Au₆₀(SR)₂₀ is composed of an icosahedral Au₅₀ fullerene hollow cage (constructed by fusing 20 tetrahedral Au₄ units) with 10 [―RS―Au―SR―] staples, obeying the "divide and protect" rule. Each Au₄ unit has 2e valence electrons, namely, the tetrahedral Au₄(2e) elementary block in the grand unified model. The DFT calculations showed that this hollow Au₆₀(SR)₂₀ nanosphere had a large HOMO–LUMO (HOMO: the highest occupied molecular orbital; LUMO: the lowest unoccupied molecular orbital) gap (1.3 eV) and a negative nucleus-independent chemical shift (NICS) value (−5) at the center of the hollow cage, indicating its high chemical stability. Furthermore, the NICS values in the center of the tetrahedral Au₄ units were much more negative than that in the center of the hollow cage, revealing that the overall stability of Au₆₀(SR)₂₀ likely stemmed from the local stability of each tetrahedral Au₄ unit. The harmonic vibrational frequencies were all positive, suggesting that the HAuNS corresponded to the local minimum of the potential energy surface. In addition, the bilayer HAuNS was designed by fusing the tetrahedral Au₄ layers, indicating the feasibility of tuning the thickness of the shell of HAuNS. In bilayer HAuNS, each tetrahedral Au₄ unit in the first layer shared four Au atoms, while those in the second layer shared one Au atom. The other three Au atoms of each tetrahedral unit bonded with the SR groups, demonstrating that each tetrahedral Au₄ unit has 2e valence electrons (namely the tetrahedral Au₄(2e) elementary block in GUM). The HOMO-LUMO gap of the bilayer Au₁₄₀(SH)₆₀ nanosphere is 1.5 eV, indicating its chemical stability. The thicknesses of the shells in monolayer and bilayer HAuNS are about 0.2 and 0.4 nm, respectively. This process could be easily understood in terms of the local stabilities of the tetrahedral Au₄(2e) elementary block in GUM. Finally, the design of larger HAuNS, Au₁₈₀(SR)₆₀, has also been presented. The HOMO-LUMO gap of Au₁₈₀(SH)₆₀ was 0.9 eV, which showed that it was also a stable HAuNS. This work provides a new strategy to controllably design the HAuNS.
- Thiolate-protected hollow Au nanosphere,
- Density-functional theory,
- Grand unified model,
- "Divide and protect" rule,
- Nucleus-independent chemical shift
1. [1]
  Skrabalak, S. E.; Chen, J.; Sun, Y.; Lu, X.; Au, L.; Cobley, C. M.; Xia, Y. Acc. Chem. Res. 2008, 41, 1587. doi: 10.1021/ar800018v doi: 10.1021/ar800018v
2. [2]
  Dreaden, E. C.; Mackey, M. A.; Huang, X.; Kangy, B.; El-Sayed, M. A. Chem. Soc. Rev. 2010, 40, 3391. doi: 10.1039/C0CS00180E doi: 10.1039/C0CS00180E
3. [3]
  Kennedy, L. C.; Bickford, L. R.; Lewinski, N. A.; Coughlin, A. J.; Hu, Y.; Day, E. S.; West, J. L.; Drezek, R. A. Small 2011, 7, 169. doi: 10.1002/smll.201000134 doi: 10.1002/smll.201000134
4. [4]
  Melancon, M. P.; Zhou, M.; Li, C. Acc. Chem. Res. 2011, 44, 947. doi: 10.1021/ar200022e doi: 10.1021/ar200022e
5. [5]
  Dreaden, E. C.; Alkilany, A. M.; Huang, X.; Murphy, C. J.; El-Sayed, M. A. Chem. Soc. Rev. 2012, 41, 2740. doi: 10.1021/ar200022e doi: 10.1021/ar200022e
6. [6]
  Doane, T. L.; Burda, C. Chem. Soc. Rev. 20] 41, 2885. doi: 10.1039/C2CS15260F doi: 10.1039/C2CS15260F
7. [7]
  Johansson, M. P.; Sundholm, D.; Vaara, J. Angew. Chem. Int. Ed. 2004, 43, 2678. doi: 10.1039/C2CS15260F doi: 10.1039/C2CS15260F
8. [8]
  Gao, Y.; Zeng, X. C. J. Am. Chem. Soc. 2005, 127, 3698. doi: 10.1021/ja050435s doi: 10.1021/ja050435s
9. [9]
  Bulusu, S.; Li, X.; Wang, L. S.; Zeng, X. C. Proc. Natl. Acad. Sci. USA 2006, 103, 8326. doi: 10.1021/ja050435s doi: 10.1021/ja050435s
10. [10]
  Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Science 2007, 318, 430. doi: 10.1126/science.1148624 doi: 10.1126/science.1148624
11. [11]
  Das, A.; Liu, C.; Byun, H. Y.; Nobusada, K.; Zhao, S.; Rosi, N. L.; Jin, R. Angew. Chem. Int. Ed. 2015, 54, 3140. doi: 10.1002/ange.201410161 doi: 10.1002/ange.201410161
12. [12]
  Chen, S.; Wang, S.; Zhong, J.; Song, Y.; Zhang, J.; Sheng, H.; Pei, Y.; Zhu, M. Angew. Chem. Int. Ed. 2015, 54, 3145. doi: 10.1002/anie.201410295 doi: 10.1002/anie.201410295
13. [13]
  Zeng, C.; Liu, C.; Chen, Y.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2014, 136, 11922. doi: 10.1021/ja506802n doi: 10.1021/ja506802n
14. [14]
  Das, A.; Li, T.; Nobusada, K.; Zeng, C.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 18264. doi: 10.1021/ja409177s doi: 10.1021/ja409177s
15. [15]
  Crasto, D.; Barcaro, G.; Stener, M.; Sementa, L.; Fortunelli, A.; Dass, A. J. Am. Chem. Soc. 2014, 136, 14933. doi: 10.1021/ja507738e doi: 10.1021/ja507738e
16. [16]
  Das, A.; Li, T.; Li, G.; Nobusada, K.; Zeng, C.; Rosi, N. L.; Jin, R. Nanoscale 2014, 6, 6458. doi: 10.1039/C4NR01350F doi: 10.1039/C4NR01350F
17. [17]
  Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2008, 130, 5883. doi: 10.1021/ja801173r doi: 10.1021/ja801173r
18. [18]
  Heaven, M. W.; Dass, A.; White, P. S.; Holt, K. M.; Murray, R. W. J. Am. Chem. Soc. 2008, 130, 3754. doi: 10.1021/ja800561b doi: 10.1021/ja800561b
19. [19]
  Zeng, C.; Li, T.; Das, A.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 10011. doi: 10.1021/ja404058q doi: 10.1021/ja404058q
20. [20]
  Chen, Y.; Liu, C.; Tang, Q.; Zeng, C.; Higaki, T.; Das, A.; Jiang, D.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2016, 138, 1482. doi: 10.1021/ja404058q doi: 10.1021/ja404058q
21. [21]
  Crasto, D.; Malola, S.; Brosofsky, G.; Dass, A.; Häkkinen, H. J. Am. Chem. Soc. 2014, 136, 5000. doi: 10.1021/ja412141j doi: 10.1021/ja412141j
22. [22]
  Zeng, C.; Qian, H.; Li, T.; Li, G.; Rosi, N. L.; Yoon, B.; Barnett, R. N.; Whetten, R. L.; Landman, U.; Jin, R. Angew. Chem. Int. Ed. 2012, 51, 13114. doi: 10.1002/ange.201207098 doi: 10.1002/ange.201207098
23. [23]
  Qian, H.; Eckenhoff, W. T.; Zhu, Y.; Pintauer, T.; Jin, R. J. Am. Chem. Soc. 2010, 132, 8280. doi: 10.1002/ange.201207098 doi: 10.1002/ange.201207098
24. [24]
  Tian, S.; Li, Y.; Li, M.; Yuan, J.; Yang, J.; Wu, Z.; Jin, R. Nat. Commun. 2015, 6, 8667. doi: 10.1038/ncomms9667 doi: 10.1038/ncomms9667
25. [25]
  Zeng, C.; Chen, Y.; Liu, C.; Nobusada, K.; Rosi, N. L.; Jin, R. Sci. Adv. 2015, 1, e1500425. doi: 10.1126/sciadv.1500425 doi: 10.1126/sciadv.1500425
26. [26]
  Chen, Y.; Zeng, C.; Liu, C.; Kirschbaum, K.; Gayathri, C.; Gil, R. R.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2015, 137, 10076. doi: 10.1021/jacs.5b05378 doi: 10.1021/jacs.5b05378
27. [27]
  Dass, A.; Theivendran, S.; Nimmala, P. R.; Kumara, C.; Jupally, V. R.; Fortunelli, A.; Sementa, L.; Barcaro, G.; Zuo, X.; Noll, B. C. J. Am. Chem. Soc. 2015, 137, 4610. doi: 10.1021/ja513152h doi: 10.1021/ja513152h
28. [28]
  Zeng, C.; Chen, Y.; Kirschbaum, K.; Appavoo, K.; Sfeir, M. Y.; Jin, R. Sci. Adv. 2015, 1, e1500045. doi: 10.1126/sciadv.1500045 doi: 10.1126/sciadv.1500045
29. [29]
  Zeng, C.; Chen, Y.; Kirschbaum, K.; Lambright, K.; Jin, R. Science 2016, 354, 1580. doi: 10.1126/science.aak9750 doi: 10.1126/science.aak9750
30. [30]
  Häkkinen, H.; Walter, M.; Gronbeck, H. J. Phys. Chem. B 2006, 110, 9927. doi: 10.1021/jp0619787 doi: 10.1021/jp0619787
31. [31]
  Häkkinen, H. Nat. Chem. 2012, 4, 443. doi: 10.1021/jp0619787 doi: 10.1021/jp0619787
32. [32]
  Pei, Y.; Zeng, X. C. Nanoscale 2012, 4, 4054. doi: 10.1039/C2NR30685A doi: 10.1039/C2NR30685A
33. [33]
  Jin, R. Nanoscale 2015, 7, 1549. doi: 10.1039/C4NR05794E doi: 10.1039/C4NR05794E
34. [34]
  Liu, C.; Pei, Y.; Sun, H.; Ma, J. J. Am. Chem. Soc. 2015, 137, 15809. doi: 10.1021/jacs.5b09466 doi: 10.1021/jacs.5b09466
35. [35]
  Jiang, D.; Overbury, S. H.; Dai, S. J. Am. Chem. Soc. 2013, 135, 8786. doi: 10.1021/ja402680c doi: 10.1021/ja402680c
36. [36]
  Pei, Y.; Gao, Y.; Shao, N.; Zeng, X. C. J. Am. Chem. Soc. 2009, 131, 13619. doi: 10.1021/ja905359b doi: 10.1021/ja905359b
37. [37]
  Pei, Y.; Tang, J.; Tang, X.; Huang, Y.; Zeng, X. C. J. Phys. Chem. Lett. 2015, 6, 1390. doi: 10.1021/acs.jpclett.5b00364 doi: 10.1021/acs.jpclett.5b00364
38. [38]
  Pei, Y.; Pal, R.; Liu, C.; Gao, Y.; Zhang, Z.; Zeng, X. C. J. Am. Chem. Soc. 2012, 134, 3015. doi: 10.1021/ja208559y doi: 10.1021/ja208559y
39. [39]
  Akola, J.; Walter, M.; Whetten, R. L.; Häkkinen, H.; Grönbeck, H. J. Am. Chem. Soc. 2008, 130, 3756. doi: 10.1021/ja800594p doi: 10.1021/ja800594p
40. [40]
  Pei, Y.; Gao, Y.; Zeng, X. C. J. Am. Chem. Soc. 2008, 130, 7830. doi: 10.1021/ja802975b doi: 10.1021/ja802975b
41. [41]
  Malola, S.; Lehtovaara, L.; Knoppe, S.; Hu, K.; Palmer, R. E.; Bürgi, T.; Häkkinen, H. J. Am. Chem. Soc. 2012, 134, 19560. doi: 10.1021/ja309619n doi: 10.1021/ja309619n
42. [42]
  Pei, Y.; Lin, S. S.; Su, J.; Liu, C. J. Am. Chem. Soc. 2013, 135, 19060. doi: 10.1021/ja409788k doi: 10.1021/ja409788k
43. [43]
  Xu, W. W.; Gao, Y.; Zeng, X. C. Sci. Adv. 2015, 1, e1400211. doi: 10.1126/sciadv.1400211 doi: 10.1126/sciadv.1400211
44. [44]
  Zhou, Y.; Li, Z. M.; Zheng, K.; Li, G. Acta Phys. -Chim. Sin. 2018, 34(7), 786. doi: 10.3866/PKU.WHXB201709292
45. [45]
  Zhu, M.; Li, M. B.; Yao, C. H.; Xia, N.; Zhao, Y.; Yan, N.; Liao, L. W.; Wu, Z. Acta Phys. -Chim. Sin. 2018, 34(7), 792. doi: 10.3866/PKU.WHXB201710091
46. [46]
  Sun, G. D.; Kang, X.; Jin, S.; Li, X. W.; Hu, D. Q.; Wang, S. X.; Zhu, M. Z. Acta Phys. -Chim. Sin. 2018, 34(7), 799. doi: 10.3866/PKU.WHXB201710124
47. [47]
  Tominaga, C.; Hikosou, D.; Osaka, I.; Kawasak, H. Acta Phys. -Chim. Sin. 2018, 34(7), 805. doi: 10.3866/PKU.WHXB201710271 doi: 10.3866/PKU.WHXB201710271
48. [48]
  Liu, M. H. Acta Phys. -Chim. Sin. 2018, 34(6), 553. doi: 10.3866/PKU.WHXB201710301
49. [49]
  Xu, W. W.; Zhu, B.; Zeng, X. C.; Gao, Y. Nat. Commun. 2016, 7, 13574. doi: 10.1038/ncomms13574 doi: 10.1038/ncomms13574
50. [50]
  Xu, W. W.; Zeng, X. C.; Gao, Y. Chem. Phys. Lett. 2017, 675, 35. doi: 10.1016/j.cplett.2017.03.001 doi: 10.1016/j.cplett.2017.03.001
51. [51]
  Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; et al. Gaussian 09, revision A.02; Gaussian, Inc.: Wallingford, CT, 2009.
52. [52]
  Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865. doi: 10.1103/PhysRevLett.77.3865 doi: 10.1103/PhysRevLett.77.3865
53. [53]
  Lee, C.; Yang, W.; Parr, R. G. Phys. Re v. B 1988, 37, 785. doi: 10.1103/PhysRevB.37.785 doi: 10.1103/PhysRevB.37.785
54. [54]
  Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270. doi: 10.1063/1.448799 doi: 10.1063/1.448799
55. [55]
  Wadt, W. R.; Hay, P. J. J. Chem. Phys. 1985, 82, 284. doi: 10.1063/1.448800 doi: 10.1063/1.448800
56. [56]
  Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299. doi: 10.1063/1.448975 doi: 10.1063/1.448975
57. [57]
  Von Ragué Schleyer, P.; Maerker, C.; Dransfeld, A.; Jiao, H.; van Eikema Hommes, N. J. R. J. Am. Chem. Soc. 1996, 118, 6317. doi: 10.1021/ja960582d doi: 10.1021/ja960582d
58. [58]
  Cheng, L.; Yuan, Y.; Zhang, X.; Yang, J. Angew. Chem. Int. Ed. 2013, 52, 9035. doi: 10.1002/anie.201302926 doi: 10.1002/anie.201302926
59. [59]
  Xu, W. W.; Li, Y.; Gao, Y.; Zeng, X. C. Nanoscale 2016, 8, 7396. doi: 10.1039/C6NR00272B doi: 10.1039/C6NR00272B
60. [60]
  Delley, B. J. Chem. Phys. 1990, 92, 508. doi: 10.1063/1.458452 doi: 10.1063/1.458452
61. [61]
  Delley, B. J. Chem. Phys. 2003, 113, 7756. doi: 10.1063/1.1316015 doi: 10.1063/1.1316015
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