Citation: ZHU Min, LI Manbo, YAO Chuanhao, XIA Nan, ZHAO Yan, YAN Nan, LIAO Lingwen, WU Zhikun. PPh_3: Converts Thiolated Gold Nanoparticles to [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺[J]. Acta Physico-Chimica Sinica, ;2018, 34(7): 792-798. doi: 10.3866/PKU.WHXB201710091 shu

PPh_3: Converts Thiolated Gold Nanoparticles to [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺

ZHU Min ^1,2,† ,
LI Manbo ^1,† ,
YAO Chuanhao ¹ ,
XIA Nan ¹ ,
ZHAO Yan ^1,2 ,
YAN Nan ¹ ,
LIAO Lingwen ¹ ,
WU Zhikun ^1,,

1.
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, P. R. China
2.
University of Science and Technology of China, Hefei 230026, P. R. China

Corresponding author: WU Zhikun, zkwu@issp.ac.cn

^†

Received Date: 12 September 2017
Revised Date: 28 September 2017
Accepted Date: 28 September 2017
Available Online: 9 July 2017
Fund Project: the National Natural Science Foundation of China 21222301the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology 2014FXCX002the National Natural Science Foundation of China 21528303the National Natural Science Foundation of China 21771186The project was supported by the National Natural Science Foundation of China (21222301, 21528303, 21603234, 21771186, 21171170, and 21601193), the National Basic Research Program of China (2013CB934302), the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology (2014FXCX002), and the CAS/SAFEA International Partnership Program for Creative Research Teamsthe National Natural Science Foundation of China 21171170the National Basic Research Program of China 2013CB934302the National Natural Science Foundation of China 21601193the National Natural Science Foundation of China 21603234

Research on gold nanoclusters is at the frontier of nanoscience and nanotechnology. The introduction of the first phosphine-protected gold nanocluster, Au₁₁(PPh₃)₇(SCN)₃ (where PPh₃ stands for triphenylphosphine and Ph stands for benzene), can be dated back to 1969. As research in the field progressed, many structures of phosphine-protected nanoclusters such as Au₅, Au₈, Au₁₃, and Au₃₉ were reported. However, the stability of these phosphine-protected nanoclusters was not satisfactory, which handicapped their research and application. In an attempt to find alternatives for phosphine-protected nanoclusters, thiolated gold nanoclusters have attracted extensive attention in recent years. So far, there has been great progress primarily owing to the development of wet-chemical synthesis techniques, among which the utilization of ligand-exchange has been proved to be very effective to synthesize thiolated gold nanoclusters. It can be easily understood that phosphine in gold nanoclusters can be exchanged with thiolate because the latter has stronger affinity for gold. However, we recently found that the reverse ligand-exchange, i.e., the exchange of thiolate with phosphine, can also take place. Some questions have naturally arisen: Is the reverse ligand-exchange only applicable to superatomic [Au₂₅(SR)₁₈]⁻ (SR: thiolate) nanoclusters? Can it occur in other thiolated gold nanoclusters? If so, is this reverse ligand-exchange also dependent on the starting nanoclusters? These intriguing issues have inspired us to conduct this work. We investigated the reactions of PPh₃ with some thiolated gold nanoparticles, including [Au₂₃(SC₆H₁₁)₁₆]⁻, Au₂₄(SC₂H₄Ph)₂₀, Au₃₆(TBBT)₂₈ (where TBBT stands for 4-(tert-butyl) benzene-1-thiolate), Au₃₈(SC₂H₄Ph)₂₀, mixed nanoclusters, and 3 nm Au nanoparticles. Surprisingly, the experimental results showed that under the action of PPh₃, thiolated gold nanoclusters (or nanoparticles) with different compositions, structures, sizes, and protecting thiolates can be uniformly transformed to [Au₁₁(PPh₃)₈Cl₂]⁺ and then [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺. In other words, PPh₃ is a universal converter for these thiolated gold nanoparticles. However, gold nanoparticles that are protected by polyvinylpyrrolidone (PVP) or citrate and [Ag₂₅(SPhMe₂)₁₈]⁻ particles cannot be transformed to [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺ and [Ag₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺, respectively, under the same conditions, which indicated that the special reactivity with PPh₃ is unique to thiolated gold nanoparticles. Our preliminary investigation on a possible reaction path between thiolated gold nanoparticles and PPh₃ also revealed that the peeling process found in Au₂₅ nanoclusters may be applicable to the conversion of [Au₂₃(SC₆H₁₁)₁₆]⁻, but not other nanoclusters like Au₂₄(SC₂H₄Ph)₂₀ and Au₃₆(TBBT)₂₈. Employing this special chemistry, we synthesized seven [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺ species with various ligands and investigated the effect of the ligand on the luminescence properties of [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺. We found that the luminescence quantum yields decreased in the following order: [Au₂₅(PPh₃)₁₀(SCH₂Ph-t-Bu)₅Cl₂]²⁺ (1.32 × 10⁻⁴) > [Au₂₅(PPh₃)₁₀(SCH₂Ph)₅Cl₂]²⁺ (8.23 × 10⁻⁵) > [Au₂₅(PPh₃)₁₀(SC₂H₄Ph)₅Cl₂]²⁺ (5.35 × 10⁻⁶) > [Au₂₅(PPh₃)₁₀(SC₁₂H₂₅)₅Cl₂]²⁺ (5.02 × 10⁻⁶) > [Au₂₅(PPh₃)₁₀(SPh-t-Bu)₅Cl₂]²⁺ (3.97 × 10⁻⁶) > [Au₂₅(PPh₃)₁₀(SC₆H₁₃)₅Cl₂]²⁺ (3.73 × 10⁻⁶) > [Au₂₅(PPh₃)₁₀(S-c-C₆H₁₁)₅Cl₂]²⁺ (1.53 × 10⁻⁶). Therefore, it can be concluded that SCH₂Ph-t-Bu is the best ligand, while S-c-C₆H₁₁ is the worse one for triggering luminescence from gold nanoparticles in the investigated thiolates. Since such diversity in surface ligands is not found in other nanoclusters (e.g., [Au₂₅(SR)₁₈]⁻), the special chemistry between thiolated gold nanoparticles and PPh₃ provides excellent opportunities to investigate the effect of ligands on the properties of gold nanoparticles and to screen ligands for special applications. In summary, in this work we reveal the unique chemistry of thiolated gold nanoparticles with PPh₃ and provide excellent opportunities for investigating ligand effects of gold nanoparticles and screening ligands for special applications.
- Thiolated gold nanoparticles,
- PPh₃,
- Universal converter,
- Luminescence
1. [1]
  McPartlin, M.; Mason, R.; Malatesta, L. J. Chem. Soc. D 1969, 7, 334. doi: 10.1039/C29690000334 doi: 10.1039/C29690000334
2. [2]
  Bennett, M. A.; Welling, L. L.; Willis, A. C. Inorg. Chem. 1997, 36, 5670. doi: 10.1021/ic9703686 doi: 10.1021/ic9703686
3. [3]
  van der Velden, J. W. A.; Beurskens, P. T.; Bour, J. J.; Bosman, W. P.; Noordik, J. H.; Kolenbrander, M.; Buskes, J. A. K. M. Inorg. Chem. 1984, 23, 146. doi: 10.1021/ic00170a007 doi: 10.1021/ic00170a007
4. [4]
  van der Velden, J. W. A.; Bour, J. J.; Bosman, W. P.; Noordik, J. H. Inorg. Chem. 1983, 22, 1913. doi: 10.1021/ic00155a018 doi: 10.1021/ic00155a018
5. [5]
  Yanagimoto, Y.; Negishi, Y.; Fujihara, H.; Tsukuda, T. J. Phys. Chem. B 2006, 110, 11611. doi: 10.1021/jp061670f doi: 10.1021/jp061670f
6. [6]
  Gutrath, B. S.; Englert, U.; Wang, Y.; Simon, U. Eur. J. Inorg. Chem. 2013, 2013, 2002. doi: 10.1002/ejic.201300148 doi: 10.1002/ejic.201300148
7. [7]
  Shichibu, Y.; Konishi, K. Small2010, 6, 1216. doi: 10.1002/smll.200902398 doi: 10.1002/smll.200902398
8. [8]
  Menard, L. D.; Gao, S.; Xu, H.; Twesten, R. D.; Harper, A. S.; Song, Y.; Wang, G.; Douglas, A. D.; Yang, J. C.; Frenkel, A. I.; et al. J. Phys. Chem. B 2006, 110, 12874. doi: 10.1021/jp060739g doi: 10.1021/jp060739g
9. [9]
  Teo, B. K.; Shi, X.; Zhang, H. J. Am. Chem. Soc. 1992, 114, 2743. doi: 10.1021/ja00033a073 doi: 10.1021/ja00033a073
10. [10]
  Wan, X.; Yuan, S.; Lin, Z.; Wang, Q. Angew. Chem. Int. Ed. 2014, 53, 2967. doi: 10.1002/ange.201308599 doi: 10.1002/ange.201308599
11. [11]
  Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D.J.; Whyman, R. J. Chem. Soc. Chem. Commun. 1994, 3, 801. doi: 10.1039/C39940000801 doi: 10.1039/C39940000801
12. [12]
  Whetten, R. L.; Khoury, J. T.; Alvarez, M. M.; Murthy, S.; Vezmar, I.; Wang, Z. L.; Stephens, P. W.; Cleveland, C. L.; Luedtke, W. D.; Landman, U. Adv. Mater. 1996, 8, 428. doi: 10.1002/adma.19960080513 doi: 10.1002/adma.19960080513
13. [13]
  Chen, S.; Ingram, R. S.; Hostetler, M. J.; Pietron, J. J.; Murray, R. W.; Schaaff, T. G.; Khoury, J. T.; Alvarez, M. M.; Whetten, R. L. Science 1998, 280, 2098. doi: 10.1126/science.280.5372.2098 doi: 10.1126/science.280.5372.2098
14. [14]
  Negishi, Y.; Nobusada, K.; Tsukuda, T. J. Am. Chem. Soc. 2005, 127, 5261. doi: 10.1021/ja042218h doi: 10.1021/ja042218h
15. [15]
  Pei, Y.; Gao, Y.; Zeng, X. J. Am. Chem. Soc. 2008, 130, 7830. doi: 10.1021/ja802975b doi: 10.1021/ja802975b
16. [16]
  Wu, Z.; Suhan, J.; Jin, R. J. Mater. Chem. 2009, 19, 622.doi: 10.1039/B815983A doi: 10.1039/B815983A
17. [17]
  Zhu, Y.; Qian, H.; Drake, B. A.; Jin, R. Angew. Chem. Int. Ed. 2010, 122, 1317. doi: 10.1002/ange.200906249 doi: 10.1002/ange.200906249
18. [18]
  Wu, Z.; Jin, R. Nano Lett. 2010, 10, 2568. doi: 10.1021/nl101225f doi: 10.1021/nl101225f
19. [19]
  Parker, J. F.; Fields-Zinna, C. A.; Murray, R. W. Accounts Chem. Res. 2010, 43, 1289. doi: 10.1021/ar100048c doi: 10.1021/ar100048c
20. [20]
  Varnavski, O.; Ramakrishna, G.; Kim, J.; Lee, D.; Goodson, T. J. Am. Chem. Soc. 2009, 132, 16. doi: 10.1021/ja907984r doi: 10.1021/ja907984r
21. [21]
  Song, Y.; Wang, S.; Zhang, J.; Kang, X.; Chen, S.; Li, P.; Sheng, H.; Zhu, M. J. Am. Chem. Soc. 2014, 136, 2963. doi: 10.1021/ja4131142 doi: 10.1021/ja4131142
22. [22]
  Wu, Z.; Wang, M.; Yang, J.; Zheng, X.; Cai, W.; Meng, G.; Qian, H.; Wang, H.; Jin, R. Small2012, 8, 2028. doi: 10.1002/smll.201102590 doi: 10.1002/smll.201102590
23. [23]
  Dolamic, I.; Knoppe, S.; Dass, A.; Bürgi, T. Nat. Commun. 2012, 3, 798. doi: 10.1038/ncomms1802 doi: 10.1038/ncomms1802
24. [24]
  Lu, Y.; Chen, W. Chem. Soc. Rev. 2012, 41, 3594.doi: 10.1039/C2CS15325D doi: 10.1039/C2CS15325D
25. [25]
  Zeng, C.; Li, T.; Das, A.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 10011. doi: 10.1021/ja404058q doi: 10.1021/ja404058q
26. [26]
  Antonello, S.; Perera, N. V.; Ruzzi, M.; Gascón, J. A.; Maran, F. J. Am. Chem. Soc. 2013, 135, 15585. doi: 10.1021/ja407887d doi: 10.1021/ja407887d
27. [27]
  Liao, L.; Zhuang, S.; Wang, P.; Xu, Y.; Yan, N.; Dong, H.; Wang, C.; Zhao, Y.; Xia, N.; Li, J.; et al. Angew. Chem. Int. Ed. 2017, 56, 12644.doi: 10.1002/anie.201707582 doi: 10.1002/anie.201707582
28. [28]
  Zhang, X.; Luo, Z.; Chen, J.; Shen, X.; Song, S.; Sun, Y.; Fan, S.; Fan, F.; Leong, D. T.; Xie, J. Adv. Mater. 2014, 26, 4565. doi: 10.1002/adma.201400866 doi: 10.1002/adma.201400866
29. [29]
  Luo, Z.; Nachammai, V.; Zhang, B.; Yan, N.; Leong, D. T.; Jiang, D.; Xie, J. J. Am. Chem. Soc. 2014, 136, 10577. doi: 10.1021/ja505429f doi: 10.1021/ja505429f
30. [30]
  Yamazoe, S.; Koyasu, K.; Tsukuda, T. Accounts Chem. Res. 2014, 47, 816. doi: 10.1021/ar400209a doi: 10.1021/ar400209a
31. [31]
  Yu, Y.; Yao, Q.; Cheng, K.; Yuan, X.; Luo, Z.; Xie, J. Part. Part. Syst. Character. 2014, 31, 652. doi: 10.1002/ppsc.201300344 doi: 10.1002/ppsc.201300344
32. [32]
  Jin, R.; Zeng, C.; Zhou, M.; Chen, Y. Chem. Rev. 2016, 116, 10346. doi: 10.1021/acs.chemrev.5b00703 doi: 10.1021/acs.chemrev.5b00703
33. [33]
  Chakraborty, I.; Pradeep, T. Chem. Rev. 2017, 117, 8208. doi: 10.1021/acs.chemrev.6b00769 doi: 10.1021/acs.chemrev.6b00769
34. [34]
  Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Science 2007, 318, 430. doi: 10.1126/science.1148624 doi: 10.1126/science.1148624
35. [35]
  Heaven, M. W.; Dass, A.; White, P. S.; Holt, K. M.; Murray, R. W. J. Am. Chem. Soc. 2008, 130, 3754. doi: 10.1021/ja800561b doi: 10.1021/ja800561b
36. [36]
  Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2008, 130, 5883. doi: 10.1021/ja801173r doi: 10.1021/ja801173r
37. [37]
  Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Whetten, R. L.; Grönbeck, H.; Häkkinen, H. Proc. Natl. Acad. Sci. USA 2008, 105, 9157. doi: 10.1073/pnas.0801001105 doi: 10.1073/pnas.0801001105
38. [38]
  Wu, Z. Angew. Chem. Int. Ed. 2012, 51, 2934. doi: 10.1002/anie.201107822 doi: 10.1002/anie.201107822
39. [39]
  Desireddy, A.; Conn, B. E.; Guo, J.; Yoon, B.; Barnett, R. N.; Monahan, B. M.; Kirschbaum, K.; Griffith, W. P.; Whetten, R. L.; Landman, U.; et al. Nature 2013, 501, 399. doi: 10.1038/nature12523 doi: 10.1038/nature12523
40. [40]
  Tian, S.; Li, Y.; Li, M.; Yuan, J.; Yang, J.; Wu, Z.; Jin, R. Nat. Commun. 2015, 6, 8667. doi: 10.1038/ncomms9667 doi: 10.1038/ncomms9667
41. [41]
  Yang, H.; Wang, Y.; Chen, X.; Zhao, X.; Gu, L.; Huang, H.; Yan, J.; Xu, C.; Li, G.; Wu, J.; et al. Nat. Commun. 2016, 7, 12809. doi: 10.1038/ncomms12809 doi: 10.1038/ncomms12809
42. [42]
  Zeng, C.; Chen, Y.; Kirschbaum, K.; Lambright, K. J.; Jin, R. Science 2016, 354, 1580. doi: 10.1126/science.aak9750 doi: 10.1126/science.aak9750
43. [43]
  Gan, Z.; Chen, J.; Wang, J.; Wang, C.; Li, M.; Yao, C.; Zhuang, S.; Xu, A.; Li, L.; Wu, Z. Nat. Commun.2017, 8, 14739.doi: 10.1038/ncomms14739 doi: 10.1038/ncomms14739
44. [44]
  Chen, T.; Yang, S.; Chai, J.; Song, Y.; Fan, J.; Rao, B.; Sheng, H.; Yu, H.; Zhu, M. Sci. Adv. 2017, 3, e1700956. doi: 10.1126/sciadv.1700956 doi: 10.1126/sciadv.1700956
45. [45]
  Wu, Z. Acta Phys. -Chim. Sin. 2017, 33, 1930. doi: 10.3866/PKU.WHXB201706026 doi: 10.3866/PKU.WHXB201706026
46. [46]
  Xia, N.; Wu, Z. J. Mater. Chem. C 2016, 4, 4125. doi: 10.1039/C6TC00744A doi: 10.1039/C6TC00744A
47. [47]
  Han, S.; Zhang, Z.; Li, S.; Qi, L.; Xu, G. Sci. China Chem. 2016, 59, 794. doi: 10.1007/s11426-016-0043-3 doi: 10.1007/s11426-016-0043-3
48. [48]
  Schmid, G.; Klein, N.; Korste, L.; Kreibig, U.; Schonauer, D. Polyhedron 1988, 7, 605. doi: 10.1016/S0277-5387(00)80366-6 doi: 10.1016/S0277-5387(00)80366-6
49. [49]
  Brown, L. O.; Hutchison, J. E. J. Am. Chem. Soc. 1997, 119, 12384. doi: 10.1021/ja972900u doi: 10.1021/ja972900u
50. [50]
  Woehrle, G. H.; Brown, L. O.; Hutchison, J. E. J. Am. Chem. Soc. 2005, 127, 2172. doi: 10.1021/ja0457718 doi: 10.1021/ja0457718
51. [51]
  Balasubramanian, R.; Guo, R.; Mills, A. J.; Murray, R. W. J. Am. Chem. Soc. 2005, 127, 8126. doi: 10.1021/ja050793v doi: 10.1021/ja050793v
52. [52]
  Shichibu, Y.; Negishi, Y.; Tsukuda, T.; Teranishi, T. J. Am. Chem. Soc. 2005, 127, 13464. doi: 10.1021/ja053915s doi: 10.1021/ja053915s
53. [53]
  Shichibu, Y.; Negishi, Y.; Watanabe, T.; Chaki, N. K.; Kawaguchi, H.; Tsukuda, T. J. Phys. Chem. C 2007, 111, 7845. doi: 10.1021/jp073101t doi: 10.1021/jp073101t
54. [54]
  Caragheorgheopol, A.; Chechik, V. Phys. Chem. Chem. Phys. 2008, 10, 5029. doi: 10.1039/B805551C doi: 10.1039/B805551C
55. [55]
  Knoppe, S.; Dharmaratne, A. C.; Schreiner, E.; Dass, A.; Bürgi, T. J. Am. Chem. Soc. 2010, 132, 16783. doi: 10.1021/ja104641x doi: 10.1021/ja104641x
56. [56]
  Knoppe, S.; Azoulay, R.; Dass, A.; Bürgi, T. J. Am. Chem. Soc. 2012, 134, 20302. doi: 10.1021/ja310330m doi: 10.1021/ja310330m
57. [57]
  Zeng, C.; Qian, H.; Li, T.; Li, G.; Rosi, N. L.; Yoon, B.; Barnett, R. N.; Whetten, R. L.; Landman, U.; Jin, R. Angew. Chem. Int. Ed. 2012, 51, 13114. doi: 10.1002/ange.201207098 doi: 10.1002/ange.201207098
58. [58]
  Li, M.; Tian, S.; Wu, Z.; Jin, R. Chem. Mater. 2016, 28, 1022. doi: 10.1021/acs.chemmater.5b04907 doi: 10.1021/acs.chemmater.5b04907
59. [59]
  Li, M.; Tian, S.; Wu, Z. Chin. J. Chem. 2017, 35, 567. doi: 10.1002/cjoc.201600526 doi: 10.1002/cjoc.201600526
60. [60]
  Gan, Z.; Lin, Y.; Luo, L.; Han, G.; Liu, W.; Liu, Z.; Yao, C.; Weng, L.; Liao, L.; Chen, J.; et al. Angew. Chem. Int. Ed. 2016, 55, 11567. doi: 10.1002/anie.201606661 doi: 10.1002/anie.201606661
61. [61]
  Joshi, C. P.; Bootharaju, M. S.; Alhilaly, M. J.; Bakr, O. M. J. Am. Chem. Soc. 2015, 137, 11578. doi: 10.1021/jacs.5b07088 doi: 10.1021/jacs.5b07088
62. [62]
  Das, A.; Li, T.; Nobusada, K.; Zeng, C.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 18264. doi: 10.1021/ja409177s doi: 10.1021/ja409177s
63. [63]
  Ji, X.; Song, X.; Li, J.; Bai, Y.; Yang, W.; Peng, X. J. Am. Chem. Soc. 2007, 129, 13939. doi: 10.1021/ja074447k doi: 10.1021/ja074447k
64. [64]
  Zhu, H.; Wang, Y.; Chen, C.; Ma, M.; Zeng, J.; Li, S.; Xia, Y.; Gao, M. ACS Nano 2017. doi: 10.1021/acsnano.7b03369 doi: 10.1021/acsnano.7b03369
65. [65]
  Qian, H.; Eckenhoff, W. T.; Bier, M. E.; Pintauer, T.; Jin, R. Inorg. Chem. 2011, 50, 10735. doi: 10.1021/ic2012292 doi: 10.1021/ic2012292
66. [66]
  Li, M.; Tian, S.; Wu, Z. Nanoscale 2014, 6, 5714. doi: 10.1039/c4nr00658e doi: 10.1039/c4nr00658e
67. [67]
  Yao, C.; Chen, J.; Li, M.; Liu, L.; Yang, J.; Wu, Z. Nano Lett. 2015, 15, 1281. doi: 10.1021/nl504477t doi: 10.1021/nl504477t
68. [68]
  Liu, X.; Yuan, J.; Yao, C.; Chen, J.; Li, L.; Bao, X.; Yang, J.; Wu, Z. J. Phys. Chem. C 2017, 121, 13848. doi: 10.1021/acs.jpcc.7b01730 doi: 10.1021/acs.jpcc.7b01730
69. [69]
  Li, G.; Abroshan, H.; Liu, C.; Zhuo, S.; Li, Z.; Xie, Y.; Kim, H. J.; Rosi, N. L.; Jin, R. ACS Nano 2016, 10, 7998. doi: 10.1021/acsnano.6b03964 doi: 10.1021/acsnano.6b03964
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

PPh3: Converts Thiolated Gold Nanoparticles to [Au25(PPh3)10(SR)5Cl2]2+

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通讯作者: 陈斌, bchen63@163.com

PPh_3: Converts Thiolated Gold Nanoparticles to [Au₂₅(PPh₃)₁₀(SR)₅Cl₂]²⁺