Citation: HAN Xue, YANG Jin, LIU Yingying, MA Jianfang. Syntheses and Luminescent Properties of Coordination Polymers Based on 1, 2, 4-Triazole-Substituted Resorcin[4]arene[J]. Acta Physico-Chimica Sinica, ;2018, 34(5): 476-482. doi: 10.3866/PKU.WHXB201709151 shu

Syntheses and Luminescent Properties of Coordination Polymers Based on 1, 2, 4-Triazole-Substituted Resorcin[4]arene

Key Laboratory of Polyoxometalate Science, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

Corresponding author: YANG Jin, yangj808@nenu.edu.cn MA Jianfang, majf247@yahoo.com
Received Date: 14 August 2017
Revised Date: 11 September 2017
Accepted Date: 12 September 2017
Available Online: 15 May 2017
Fund Project: the National Natural Science Foundation of China 21471029The project was supported by the National Natural Science Foundation of China (21471029)

Two new coordination polymers, namely, [[Zn₂(TTR4A)(L)₂]·DMF·4H₂O]_n (compound 1) and [[Co(TTR4A)Cl₂]·DMA·H₂O]_n (compound 2), have been synthesized under solvothermal conditions (TTR4A = tetrakis(1, 2, 4-triazol-ylmethylresorcin[4]arene), L = 4, 4'-biphenyldicarboxylic acid, DMF = N, N-dimethylformamide and DMA = N, N-dimethylacetamide). Crystal structures of the coordination compounds 1 and 2 were determined by single-crystal X-ray diffraction analyses, and further characterized by infrared spectra, elemental analyses, powder X-ray diffraction, and thermogravimetric analyses. In coordination compound 1, four L ligands bridge four adjacent Zn(Ⅱ) atoms to generate macrocyclic Zn₄L₄ units, which are further linked by the TTR4A ligands into a one-dimensional chain structure. In coordination compound 2, four 1, 2, 4-triazole groups of each TTR4A ligand bridge four Co(Ⅱ) atoms to form a two-dimensional layer structure. Furthermore, studies on the luminescent properties of compound 1 in solid state at room temperature reveal that it exhibits an intense emission peak. Luminescent-sensing detections for Fe³⁺, Cr₂O₇²⁻, and nitrobenzene solvents were also investigated by using compound 1 as the potential luminescent sensor.
- Resorcin[4]arene,
- Crystal structure,
- Coordination polymer,
- Fluorescence,
- Fluorescent response
1. [1]
  Baeyer, A. Chem. Ber. 1872, 5(2), 1094. doi: 10.1002/cber.187200502157 doi: 10.1002/cber.187200502157
2. [2]
  Gutsche, C. D. J. Org. Chem. 1978, 43(25), 4905. doi: 10.1021/jo00419a052 doi: 10.1021/jo00419a052
3. [3]
  Andreetti, G. D.; Ungaro, R.; Pochini, A. J. Chem. Soc., Chem. Comm. 1979, No. 22, 1005. doi: 10.1039/c39790001005 doi: 10.1039/c39790001005
4. [4]
  Tunstad, L. M.; Tucker, J.A.; Dalcanale, E.; Weiser, J.; Bryant, J.A.; Sgerman, J. C.; Helgeson, R. C.; Knobler, C. B.; Cram, D. J. J. Org. Chem. 1989, 54(6), 1305. doi: 10.1021/jo00267a015 doi: 10.1021/jo00267a015
5. [5]
  Zhao, S. S.; Yang, J.; Liu, Y. Y.; Ma, J. F. Inorg. Chem. 2016, 55(5), 2261. doi: 10.1021/acs.inorgchem.5b02666 doi: 10.1021/acs.inorgchem.5b02666
6. [6]
  Zhang, S. T.; Yang, J.; Wu, H.; Liu, Y. Y; Ma, J. F. Chem. Eur. J. 2015, 21(44), 1. doi: 10.1002/chem.201501976 doi: 10.1002/chem.201501976
7. [7]
  Sanz, S.; Ferreira, K.; Mcintosh, R. D.; Dalgarno, S. J.; Brechin, E. K. Chem. Commun. 2011, 47(32), 9042. doi: 10.1039/C1CC13055B doi: 10.1039/C1CC13055B
8. [8]
  Dong, Y. B.; Shi, H. Y.; Yang, J.; Liu, Y. Y.; Ma, J. F. Cryst. Growth Des. 2015, 15(3), 1546. doi: 10.1021/acs.cgd.5b00099 doi: 10.1021/acs.cgd.5b00099
9. [9]
  Cook, T. R.; Zheng, Y. R.; Stang, P. J. Chem. Rev. 2013, 113(1), 734. doi: 10.1021/cr3002824 doi: 10.1021/cr3002824
10. [10]
  Pei, W. Y.; Xu, G.; Yang, J.; Wu, H.; Chen, B.; Zhou, W.; Ma, J. F. J. Am. Chem. Soc. 2017, 139(22), 7648. doi: 10.1021/jacs.7b03169 doi: 10.1021/jacs.7b03169
11. [11]
  Lv, L. L.; Yang, J.; Zhang, H. M.; Liu, Y. Y.; Ma, J. F. Inorg. Chem. 2015, 54(4), 1744. doi: 10.1021/ic502686b doi: 10.1021/ic502686b
12. [12]
  Kovačević, N.; Kokalj, A. J. Phys. Chem. C 2011, 115(49), 24189. doi: 10.1021/jp207076w doi: 10.1021/jp207076w
13. [13]
  Liu, B.; Yang, J.; Yang, G. C.; Ma, J. F. Inorg. Chem. 2013, 52(1), 84. doi: 10.1021/ic301257k doi: 10.1021/ic301257k
14. [14]
  Clainche, L. L.; Giorgi, M.; Reinaud, O. Eur. J. Inorg. Chem. 2000, 2000(9), 1931. doi: 10.1002/1099-0682(200009)2000:9<1931::AID-EJIC1931>3.0.CO;2-H doi: 10.1002/1099-0682(200009)2000:9<1931::AID-EJIC1931>3.0.CO;2-H
15. [15]
  Memon, S.; Bhatti, A. A.; Bhatti, A. A.; Ocak, Ü.; Ocak, M. J. Iran. Chem. Soc. 2015, 12(10), 1739. doi: 10.1007/s13738-015-0648-2 doi: 10.1007/s13738-015-0648-2
16. [16]
  Hu, Z.; Lustig, W. P.; Zhang, J.; Zhang, H.; Wang, H; Teat, S. J.; Gong, Q.; Rudd, N. D.; Li, J. J. Am. Chem. Soc. 2015, 137(51), 16209. doi: 10.1021/jacs.5b10308 doi: 10.1021/jacs.5b10308
17. [17]
  Zhou, J.; Li, H.; Zhang, H.; Li, H.; Shi, W.; Cheng, P. Adv. Mater. 2015, 27(44), 7072. doi: 10.1002/adma.201502760 doi: 10.1002/adma.201502760
18. [18]
  Gao, R. C.; Guo, F. S.; Bai, N. N.; Long, Y. L.; Yang, F.; Liang, J. Y.; Li, Z. J.; Wang Y. Y. Inorg. Chem. 2016, 55(21), 11323. doi: 10.1021/acs.inorgchem.6b01899 doi: 10.1021/acs.inorgchem.6b01899
19. [19]
  Chen, F.; Wang, Z. Y.; Zhang, Y. Y., Yu. K. H.; Weng, L. X.; Wei, W. Acta phys. -Chem. Sin. 2017, 33(7), 1446. doi: 10.3866/PKU.WHXB201704102
20. [20]
  Wang, H.; Wang, X. M. Acta Phys. -Chim. Sin. 2016, 32(5), 1267. doi: 10.3866/PKU.WHXB201603014
21. [21]
  Wen, G. X.; Wu, Y. P.; Dong, W. W.; Zhao, J.; Li, D. S.; Zhang, J. Inorg. Chem. 2016, 55(20), 10114. doi: 10.1021/acs.inorgchem.6b01876 doi: 10.1021/acs.inorgchem.6b01876
22. [22]
  Hu, Y. J.; Yang. J.; Liu, Y. Y.; Song. S.; Ma. J. F. Cryst. Growth Des. 2015, 15(8), 3822. doi: 10.1021/acs.cgd.5b00469 doi: 10.1021/acs.cgd.5b00469
23. [23]
  Sheldrick G. M. SHELXL-97, Programs for X-ray Crystal Structure Solution: University of Gttingen, Gttingen[J]. Germany, 1997.
24. [24]
  Sheldrick G. M. SHELXL-97, Programs for X-ray Crystal Structure Reﬁnement; University of Gttingen, Gttingen[J]. Germany, 1997.
25. [25]
  Spek, A. L. J. Appl. Crystallogr. 2003, 36, 7. doi: 10.1107/s0021889802022112. doi: 10.1107/s0021889802022112
26. [26]
  Ding, C.; Li, X.; Ding, Y.; Li, X.; Ng, S. W.; Xie, Y. Cryst. Growth Des. 2012, 12(7), 3465. doi: 10.1021/cg201655n doi: 10.1021/cg201655n
27. [27]
  Zeng, F.; Ni, J.; Wang, Q.; Ding, Y.; Ng, S. W.; Zhu, W.; Xie, Y. Cryst. Growth Des. 2010, 10(4), 1611. doi: 10.1021/cg901182c doi: 10.1021/cg901182c
28. [28]
  Zha, Q.; Ding, C.; Rui, X.; Xie, Y. Cryst. Growth Des. 2013, 13(10), 4583. doi: 10.1021/cg4011289 doi: 10.1021/cg4011289
29. [29]
  Zheng, Q.; Yang, F.; Deng, M.; Ling, Y.; Liu, X.; Chen, Z.; Wang, Y.; Weng, L.; Zhou, Y. Inorg. Chem. 2013, 52(18), 10368. doi: 10.1021/ic401092j doi: 10.1021/ic401092j
30. [30]
  Qu, K.; Wang, J.; Ren, J.; Qu. X. Chem. Eur. J. 2013, 19(22), 7243. doi: 10.1002/chem.201300042 doi: 10.1002/chem.201300042
31. [31]
  Wang, J.; Li, Y.; Patel, N. G.; Zhang, G.; Zhou, D.; Pang, Y. Chem. Commun. 2014, 50(82), 12258. doi: 10.1039/c4cc04731a doi: 10.1039/c4cc04731a
32. [32]
  Xu, H.; Hu, Z. C.; Cao, C. S.; Zhao, B. Inorg. Chem. 2015, 54(10), 4585. doi: 10.1021/acs.inorgchem.5b00113 doi: 10.1021/acs.inorgchem.5b00113
33. [33]
  Jin, S. S.; Han X.; Yang, J.; Zhang, H. M.; Liu, X. L.; Ma, J. F. J. Lumin. 2017, 188, 346. doi: 10.1016/j.jlumin.2017.04.048 doi: 10.1016/j.jlumin.2017.04.048
34. [34]
  Zhou, Y.; Allen, B.; Reed, J. M.; Zou, S. J. Phys. Chem. A 2014, 118(39), 8971. doi: 10.1021/jp501996f doi: 10.1021/jp501996f
35. [35]
  Hao, Z.; Song, X.; Zhu, M.; Meng, X.; Zhao, S.; Su, S, Yang, W.; Song, S.; Zhang, H. J. Mater. Chem. A 2013, 1(36), 11043. doi: 10.1039/C3TA12270k doi: 10.1039/C3TA12270k
36. [36]
  Tian, D.; Li, Y.; Chen, R. Y.; Chang, Z.; Wang, G. Y.; Bu, X. H. J. Mater. Chem. A 2014, 2(5), 1465. doi: 10.1039/C3TA13983B doi: 10.1039/C3TA13983B
1. [1]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
2. [2]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
10. [10]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
11. [11]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
12. [12]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
13. [13]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
14. [14]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
15. [15]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
16. [16]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
17. [17]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
18. [18]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
19. [19]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
20. [20]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(403)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142