Citation: XU Jiale, HU Lei, WANG Lu, DENG Jinxia, CHEN Jun, XING Xianran. Controllable Thermal Expansion and Crystal Structure of (Fe_1-xNi_x)ZrF₆ Solid Solutions[J]. Acta Physico-Chimica Sinica, ;2018, 34(4): 339-343. doi: 10.3866/PKU.WHXB201709081 shu

Controllable Thermal Expansion and Crystal Structure of (Fe_1-xNi_x)ZrF₆ Solid Solutions

Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, P. R. China

Corresponding author: CHEN Jun, Junchen@ustb.edu.cn
Received Date: 9 August 2017
Revised Date: 6 September 2017
Accepted Date: 7 September 2017
Available Online: 8 April 2017
Fund Project: the National Natural Science Foundation of China 21231001the Fundamental Research Funds for the Central Universities, China FRF-TP-14-012C1the National Natural Science Foundation of China 91422301The project was supported by the National Natural Science Foundation of China (91422301, 21231001) and the Fundamental Research Funds for the Central Universities, China (FRF-TP-14-012C1)

Most materials expand on heating and contract on cooling. In the recent years, however, some compounds have been found to exhibit abnormal negative thermal expansion (NTE) behavior; this presents an opportunity to adjust the coefficient of thermal expansion (CTE) of such materials. It is especially important to obtain controllable thermal expansion in isotropic compounds. Herein, we report the preparation, crystal structure, and controllable thermal expansion in double ReO₃-type (Fe_1-xNi_x)ZrF₆ solid solutions. (Fe_1-xNi_x)ZrF₆ exhibits full range solubility. A controllable thermal expansion of (Fe_1-xNi_x)ZrF₆ could be achieved by the chemical substitution of Ni²⁺ for Fe²⁺ over a wide range of CTE from −3.24 × 10⁻⁶ to +18.23 × 10⁻⁶ K⁻¹ (300–675 K). In particular, zero thermal expansion was obtained for the composition (Fe_0.5Ni_0.5)ZrF₆. As a kind of typical framework structure, the transverse thermal vibrations of fluorine atoms are expected to play a critical role in the thermal expansion behavior of double-ReO₃ compounds. This study presents a potential method to tune the thermal expansion of NTE (negative thermal expansion) families which have an open framework structure.
- Solid solution,
- Fluorides,
- ReO₃,
- Controllable thermal expansion,
- Zero thermal expansion
1. [1]
  Mary, T. A.; Evans, J. S. O.; Vogt, T.; Sleightet, A. W. Science 1996, 272 (5258), 90. doi: 10.1126/science.272.5258.90 doi: 10.1126/science.272.5258.90
2. [2]
  Greve, B. K.; Martin, K. L.; Lee, P. L.; Chupas, P. J.; Chapman, K. W.; Wilkinson, A. P. J. Am. Chem. Soc. 2010, 132 (44), 15496. doi: 10.1021/ja106711v doi: 10.1021/ja106711v
3. [3]
  Lock, N.; Wu, Y.; Christensen, M.; Cameron, L. J.; Peterson, V. K.; Bridgeman, A. J.; Kepert, C. J.; Iversen, B. B. J. Phys. Chem. C 2010, 114 (39), 16181. doi: 10.1021/jp103212z doi: 10.1021/jp103212z
4. [4]
  Mohn, P. Nature 1999, 400 (6739), 18. doi: 10.1038/21778 doi: 10.1038/21778
5. [5]
  Takenaka, K.; Takagi, H. Appl. Phys. Lett. 2005, 87 (26), 261902. doi: 10.1063/1.2147726 doi: 10.1063/1.2147726
6. [6]
  Deng, S.; Sun, Y.; Wu, H.; Huang, Q.; Yan, J.; Shi, K.; Malik, M. I.; Lu, H.; Wang, L.; Huang, R.; Li, L.; Wang, C. Chem. Mater. 2015, 27 (7), 2495. doi: 10.1021/cm504702m doi: 10.1021/cm504702m
7. [7]
  Chen, J.; Nittala, K.; Forrester, J. S.; Jones, J. L.; Deng, J.; Yu, R.; Xing, X. J. Am. Chem. Soc. 2011, 133 (29), 11114. doi: 10.1021/ja2046292 doi: 10.1021/ja2046292
8. [8]
  Azuma, M.; Chen, W. T.; Seki, H.; Czapski, M.; Olga, S.; Oka, K.; Mizumaki, M.; Watanuki, T.; Ishimatsu, N.; Kawamura, N.; Ishiwata, S.; Tucker, M. G.; Shimakawa, Y.; Attfield, J. P. Nat. Commun. 2011, 2, 347. doi: 10.1038/ncomms1361 doi: 10.1038/ncomms1361
9. [9]
  Hu, L.; Chen, J.; Sanson, A.; Wu, H.; Rodriguez, C. G.; Olivi, L.; Ren, Y.; Fan, L.; Deng, J.; Xing, X. J. Am. Chem. Soc. 2016, 138 (27), 8320. doi: 10.1021/jacs.6b02370 doi: 10.1021/jacs.6b02370
10. [10]
  Dejneka, M. J.; Chapman, C. L.; Misture, S. T. J. Am. Ceram. Soc. 2011, 94 (8), 2249. doi: 10.1111/j.1551-2916.2011.04730.x doi: 10.1111/j.1551-2916.2011.04730.x
11. [11]
  Uchino, K.; Nomura, S.; Cross, L. E.; Newnham, R. E.; Jang, S. J. J. Mater. Sci. 1981, 16 (3), 569. doi: 10.1007/BF02402772 doi: 10.1007/BF02402772
12. [12]
  Atkinson, A.; Barnett, S.; Gorte, R. J.; Irvine, J. T. S.; McEvoy, A. J.; Mogensen, M.; Singhal, S. C.; Vohs, J. Nat. Mater. 2004, 3 (1), 17. doi: 10.1038/nmat1040 doi: 10.1038/nmat1040
13. [13]
  Chen, J.; Hu, L.; Deng, J.; Xing, X. Chem. Soc. Rev. 2015, 44 (11), 3522. doi: 10.1039/C4CS00461B doi: 10.1039/C4CS00461B
14. [14]
  Adam, J. L. Chem. Rev. 2002, 102 (6), 2461. doi: 10.1021/cr010305b doi: 10.1021/cr010305b
15. [15]
  Greve, B. K.; Martin, K. L.; Lee, P. L.; Chupas, P. J.; Chapman, K. W.; Wilkinson, A. P. J. Am. Chem. Soc.2010, 132 (44), 15496. doi: 10.1021/ja106711v doi: 10.1021/ja106711v
16. [16]
  Hu, L.; Chen, J.; Fan, L.; Ren, Y.; Rong, Y.; Pan, Z.; Deng, J.; Yu, R.; Xing, X. J. Am. Chem. Soc. 2014, 136 (39), 13566. doi: 10.1021/ja5077487 doi: 10.1021/ja5077487
17. [17]
  Hu, L.; Chen, J.; Fan, L.; Ren, Y.; Huang, Q.; Sanson, A.; Jiang, Z.; Zhou, M.; Rong, Y.; Wang, Y.; Deng, J.; Xing, X. Adv. Mater. 2015, 27 (31), 4592. doi: 10.1002/adma.201500868 doi: 10.1002/adma.201500868
18. [18]
  Hancock, J. C.; Chapman, K. W.; Halder, G. J.; Morelock, C. R.; Kaplan, B. S.; Gallington, L. C.; Bongiorno, A.; Han, C.; Zhou, S.; Wilkinson, A. P. Chem. Mater. 2015, 27 (11), 3912. doi: 10.1021/acs.chemmater.5b00662 doi: 10.1021/acs.chemmater.5b00662
19. [19]
  Hu, L.; Chen, J.; Xu, J.; Wang, N.; Han, F.; Ren, Y.; Pan, Z.; Rong, Y.; Huang, R.; Deng, J.; Li, L.; Xing, X. J. Am. Chem. Soc. 2016, 138 (44), 14530. doi: 10.1021/jacs.6b08746 doi: 10.1021/jacs.6b08746
20. [20]
  Sleight, A. Nature 2003, 425 (6959), 674. doi: 10.1038/425674a doi: 10.1038/425674a
21. [21]
  Margadonna, S.; Prassides, K.; Fitch, A. N. J. Am. Chem. Soc. 2004, 126 (47), 15390. doi: 10.1021/ja044959o doi: 10.1021/ja044959o
22. [22]
  Song, X.; Sun, Z.; Huang, Q.; Rettenmayr, M.; Liu, X.; Seyring, M.; Li, G.; Rao, G.; Yin, F. Adv. Mater.2011, 23 (40), 4690. doi: 10.1002/adma.201102552 doi: 10.1002/adma.201102552
23. [23]
  Phillips, A. E.; Halder, G. J.; Chapman, K. W.; Goodwin, A. L.; Kepert, C. J. J. Am. Chem. Soc. 2009, 132 (1), 10. doi: 10.1021/ja906895 doi: 10.1021/ja906895
1. [1]
  Lixing ZHANG , Yaowen WANG , Xu HAN , Junhong ZHOU , Jinghui WANG , Liping LI , Guangshe LI . Research progress in the synthesis of fluorine-containing perovskites and their derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1689-1701. doi: 10.11862/CJIC.20250007
2. [2]
  Huoshuai Huang , Zhidong Wei , Jiawei Yan , Jiasheng Chi , Qianxiang Su , Mingxia Chen , Zhi Jiang , Yangzhou Sun , Wenfeng Shangguan . Unveiling the mechanism of direct-to-indirect bandgap transition in the photocatalytic hydrogen evolution of Zn_xCd_1−xS solid solution. Acta Physico-Chimica Sinica, 2026, 42(1): 100141-0. doi: 10.1016/j.actphy.2025.100141
3. [3]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
4. [4]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
5. [5]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
6. [6]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-0. doi: 10.3866/PKU.WHXB202406012
7. [7]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
8. [8]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
9. [9]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
10. [10]
  Yuhang Zhang , Yi Li , Yuehan Cao , Yingjie Shuai , Yu Zhou , Ying Zhou . Regulating the formation type by Ir of intermediates to suppress product overoxidation in photocatalytic methane conversion. Acta Physico-Chimica Sinica, 2026, 42(2): 100173-0. doi: 10.1016/j.actphy.2025.100173
11. [11]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
12. [12]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
13. [13]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
14. [14]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 100021-0. doi: 10.3866/PKU.WHXB202311005
15. [15]
  Rongzhan LOU , Qiaoling KANG , Zhenchao BAI , Dongyun LI , Yang XU , Rui WANG , Qingyi LU . Research progress of sodium ion high entropy layered oxide cathode. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2411-2428. doi: 10.11862/CJIC.20250142
16. [16]
  Anqun LAI , Qiaoyu WU , Qingqing LIANG , Qiyong LI , Guowen DONG , Yongjie DING , Jia′nan CHEN , Qing YAN , Zhonghua PAN , Wangchuan XIAO . Electrocatalytic water oxidation properties of Nd-Co polynuclear complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2527-2535. doi: 10.11862/CJIC.20250151
17. [17]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
18. [18]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
19. [19]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
20. [20]
  Ruyan Liu , Zhenrui Ni , Olim Ruzimuradov , Khayit Turayev , Tao Liu , Luo Yu , Panyong Kuang . Ni-induced modulation of Pt 5d-H 1s antibonding orbitals for enhanced hydrogen evolution and urea oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100159-0. doi: 10.1016/j.actphy.2025.100159

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(634)
HTML views(74)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Controllable Thermal Expansion and Crystal Structure of (Fe1-xNix)ZrF6 Solid Solutions

Metrics

通讯作者: 陈斌, bchen63@163.com

Controllable Thermal Expansion and Crystal Structure of (Fe_1-xNi_x)ZrF₆ Solid Solutions