Citation: LIANG Sisi, SHANG Mengmeng, LIN Jun. Single-Component Luminescent Materials Activated with Mixed-Valence Eu(+2, +3): Designed Synthesis, Luminescent Properties and Mechanisms[J]. Acta Physico-Chimica Sinica, ;2018, 34(3): 237-246. doi: 10.3866/PKU.WHXB201708281 shu

Single-Component Luminescent Materials Activated with Mixed-Valence Eu(+2, +3): Designed Synthesis, Luminescent Properties and Mechanisms

LIANG Sisi ¹ ,
SHANG Mengmeng ^1,, ,
LIN Jun ^1,2,,

1.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
2.
School of Applied Physics & Materials, Wuyi University, Jiangmen 529020, Guangdong Province, P. R. China

Corresponding author: SHANG Mengmeng, mmshang@ciac.ac.cn LIN Jun, jlin@ciac.ac.cn
Received Date: 26 June 2017
Revised Date: 21 July 2017
Accepted Date: 1 August 2017
Available Online: 28 March 2017
Fund Project: The project was supported by the National Natural Science Foundation of China (51672265, 91433110)the National Natural Science Foundation of China 91433110the National Natural Science Foundation of China 51672265

White LEDs are considered the next-generation light source as they are environmentally friendly and have high efficiencies. Therefore, researches are being conducted to meet the performance requirements of phosphors, which are the crucial components of white LEDs. Eu²⁺ and Eu³⁺ ions have different electronic structures, which lead to distinct photoluminescence properties. The characteristic emissions of Eu²⁺ and Eu³⁺ originate from the 4f-4f and 4f-5d transitions, respectively. In order to combine their respective features, the research of mixed-valence Eu ions into single-phase phosphors has become a hot research topic in recent years. The mixed-valence Eu ion-doped phosphors have tunable luminescence properties because they possess the respective properties of Eu²⁺ and Eu³⁺. From their respective characters of Eu²⁺ and Eu³⁺, this paper mainly reviews the progress of mixed valence Eu(+2, +3) ion-activated single-component luminescent materials in recent years from three aspects: unbalanced substitution, crystal field regulation, and other systems. In addition, the respective photoluminescence properties of Eu²⁺ and Eu³⁺ and the luminescence performances and mechanisms of the mixed-valence Eu ion-activated phosphors have been summarized. The luminescence performances and mechanisms have been summarized as well. All the research works carried out in this field provide inspiration for the investigation of new phosphors.
- Phosphor,
- Mixed valence,
- Single component,
- Eu,
- Whitelight-emitting diode
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