Citation: PEI Tong, PENG Kai, CAI Xin-Yi, YUAN Liang-Jie, XIA Jiang-Bin. Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization[J]. Acta Physico-Chimica Sinica, ;2017, 33(12): 2550-2558. doi: 10.3866/PKU.WHXB201706071 shu

Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization

College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, P. R. China

Received Date: 8 May 2017
Revised Date: 6 June 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (21371138), the Funds for Creative Research Groups of Hubei Province, China (2014CFA007) and the Fundamental Research Funds for the Central Universities, China (2042015kf0180).

New poly(bis-3,4-ethylenedioxythiophene methine)s derivatives with typical electro-optical moieties of thiophene, carbazole and fluorene as the side chains are obtained by facile solid state polymerization (SSP) or melt state polymerization (MSP). Detail characterizations of these polymers are carried out and some key monomers' crystals are obtained for structures analysis. It is found that existence of alkyl chains decrease monomers onset temperatures for SSP (T_onset) due to the weakening of the intermolecular interaction in crystals.
- Poly (bis-3,4-ethylenedioxythiophene methine) s derivatives,
- Solid and melt state polymerization,
- Alkyl chain effect
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