Citation: WANG Xin, ZHANG Yu-Jin, WANG Chuan-Kui. Optical Properties and Responsive Mechanism of Carbazole-Based Two-Photon Fluorescent Probes for the Detection of Hypochlorite[J]. Acta Physico-Chimica Sinica, ;2016, 32(12): 2913-2920. doi: 10.3866/PKU.WHXB201609301 shu

Optical Properties and Responsive Mechanism of Carbazole-Based Two-Photon Fluorescent Probes for the Detection of Hypochlorite

School of Physics and Electronics, Shandong Normal University, Jinan 250014, P. R. China

Received Date: 6 June 2016
Revised Date: 30 September 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (11404193), Natural Science Foundation of Shandong Province, China (ZR2014AM026), and Taishan Scholar Project of Shandong Province, China.

The one- and two-photon absorption and emission properties of the two newly synthesized watersoluble two-photon fluorescent probes (HCH and HCM) for the detection of ClO^- were investigated using timedependent density functional theory in combination with response theory. Dramatic changes in the photophysical properties of the molecules following reaction with ClO^- were predicted. The photoabsorption and photoemission peaks for both compounds were clearly blue shifted, while the emission intensities were enhanced. Both probes were also found to have large two-photon cross sections. Importantly, in the presence of ClO^- the two-photon cross section of the molecules increased significantly, which indicated that both HCH and HCM should be good two-photon fluorescent probes for sensing ClO^-. The responsive mechanism of the probes was explored by analyzing the molecular Mulliken charge population, which was attributed to C=N isomerization.
- Fluorescent probe,
- Two-photon absorption,
- ClO^-,
- C=N isomerization
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