Citation: ZHU Shou-Pu, WU Tian, SU Hai-Ming, QU Shan-Shan, XIE Yong-Juan, CHEN Ming, DIAO Guo-Wang. Hydrothermal Synthesis of Fe₃O₄/rGO Nanocomposites as Anode Materials for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2016, 32(11): 2737-2744. doi: 10.3866/PKU.WHXB201609072 shu

Hydrothermal Synthesis of Fe₃O₄/rGO Nanocomposites as Anode Materials for Lithium Ion Batteries

ZHU Shou-Pu ^1,2, ,
WU Tian ^1,2 ,
SU Hai-Ming ^1,2 ,
QU Shan-Shan ^1,2 ,
XIE Yong-Juan ^1,2 ,
CHEN Ming ^1,2 ,
DIAO Guo-Wang ^1,2

1.
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu Province, P. R. China;
2.
Key Laboratory of Environmental Materials & Environmental Engineering of Jiangsu Province, Yangzhou 225002, Jiangsu Province, P. R. China

Received Date: 27 June 2016
Revised Date: 6 September 2016

Fe₃O₄/rGO nanocomposites were prepared by hydrothermal method using Fe(OH)3 as precursor of magnetite nanoparticles, graphene oxide (GO) as precursor of reduced graphene oxide (rGO), hydrazine and trisodium citrate as mixed reducing agent. The morphologies, structures and compositions of the products were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). The electrochemical characteristics of assembled coin-type cells versus metallic lithium were evaluated by cyclic voltammetry and galvanostatic charge-discharge. The uniform morphology, high reductive level of rGO and the role of rGO buffering the volume changes of Fe₃O₄ nanoparticles in the charging-discharging process can be responsible for the good electrochemical performance of Fe₃O₄/rGO nanocomposites.
- Lithium ion battery,
- Nanocomposite,
- Magnetite,
- Graphene,
- Anode material
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis of Fe₃O₄/rGO Nanocomposites as Anode Materials for Lithium Ion Batteries