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Citation: WANG Ya-Li, LI Qi, WENG Wei-Zheng, XIAWen-Sheng, WAN Hui-Lin. Catalytic Behaviors and Stability of Y₂O₃-Modified Ni/SiO₂ for Partial Oxidation of Methane into Synthesis Gas[J]. Acta Physico-Chimica Sinica, ;2016, 32(11): 2776-2784. doi: 10.3866/PKU.WHXB201608302 shu

Catalytic Behaviors and Stability of Y₂O₃-Modified Ni/SiO₂ for Partial Oxidation of Methane into Synthesis Gas

Fujian Province Key Laboratory of Theoretical and Computational Chemistry, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, State Key Laboratory of Physical Chemistry of Solid State Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 13 June 2016
Revised Date: 29 August 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (21373169), and PCSIRT (IRT1036).

Aseries of Y₂O₃-modified Ni/SiO₂ catalysts were synthesized by a conventional impregnation method. Catalytic performances for the partial oxidation of methane (POM) to synthesis gas were investigated. The addition of Y₂O₃ promotes a decrease in size of Ni particles supported on silica, increased the dispersion of Ni particles, and enhanced the interaction between Ni and silica. These properties gave the catalysts increased anti-sintering and resistance to carbon deposits. The catalytic behaviors of the Ni-based catalysts for POM were significantly improved when Y₂O₃ was introduced.
- Partial oxidation of methane,
- Ni,
- SiO₂,
- Y₂O₃,
- Stability
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Catalytic Behaviors and Stability of Y2O3-Modified Ni/SiO2 for Partial Oxidation of Methane into Synthesis Gas

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通讯作者: 陈斌, bchen63@163.com

Catalytic Behaviors and Stability of Y₂O₃-Modified Ni/SiO₂ for Partial Oxidation of Methane into Synthesis Gas