Citation: YE Juan, SUN Kai, TAO Min-Long, TU Yu-Bing, XIE Zheng-Bo, WANG Ya-Li, HAO Shao-Jie, XIAO Hua-Fang, WANG Jun-Zhong. Chiral Features of the Achiral Copper Phthalocyanine on a Bi(111) Surface[J]. Acta Physico-Chimica Sinica, ;2016, 32(10): 2593-2598. doi: 10.3866/PKU.WHXB201607071 shu

Chiral Features of the Achiral Copper Phthalocyanine on a Bi(111) Surface

School of Physical Science and Technology, Southwest University, Chongqing 400715, P. R. China

Received Date: 1 June 2016
Revised Date: 7 July 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (10974156, 21173170, 91121013, 11574253).

The adsorption and chiral features of a self-assembled CuPc monolayer on a semi-metallic Bi(111) surface have been evaluated using the low temperature scanning tunneling microscopy (LT-STM). Under low coverage conditions, the individual CuPc molecules rotated around the molecular center at 78 K until they interacted with other molecule to form clusters, because of the relatively weak interfacial interactions between the CuPc molecules and the Bi(111) surface. As the level of molecular coverage increased, the CuPc molecules self-assembled into two-dimensional domains with each molecule exhibiting chiral features. Beyond one monolayer, the CuPc molecules underwent an orientational transition from a flat-lying to a standing-up configuration. The chiral features of the CuPc molecules were attributed to the combined effect of asymmetric charge transfer between the CuPc molecules and the Bi(111) substrate and the formation of asymmetric intermolecular van der Waals interactions.
- CuPc,
- Scanning tunneling microscopy,
- Semi-metallic Bi(111),
- Chiral feature,
- Self-assembly
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