Citation: CAO Meng-Xiong, LIU Hao, WANG Hai-Ou, ZHANG Yun, TAN Wei-Shi, SHI Yang-Guang. Effects of B-and In-Doping on Microstructures, Magnetostriction and Magnetic Properties of Melt-Spun Fe81Ga19 Ribbons[J]. Acta Physico-Chimica Sinica, ;2016, 32(7): 1829-1838. doi: 10.3866/PKU.WHXB201605191
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Two series of (Fe0.81Ga0.19)100-xBx (Fe-Ga-B) and (Fe0.81Ga0.19)100-xInx (Fe-Ga-In) ribbons were successfully prepared with melt spinning method. Thermal treatments were afterwards conducted out on these Fe-Ga-B ribbons. The sample microstructures of the alloys were examined by high resolution X-ray diffraction (HRXRD) and extended X-ray absorption fine structure (EXAFS). The magnetic properties were measured by a vibrating sample magnetometer (VSM) at room temperature. The magnetostriction constant, measured by resistance strain gauge method, of the melt-spun (Fe0.81Ga0.19)98B2 ribbon decreased sharply due to the L12 phase. Both the Fe2B and modified-DO3 phases played a positive role in increasing the magnetostriction constant of the Fe-Ga alloys. The Fe2B phase presented a lower saturation magnetization and a larger saturation field. As the B composition increased, the saturation magnetization of the ribbons decreased and the coercivity intensified. For the Fe-Ga-In ribbons, the non-magnetic In-rich phase was formed, leading to their lattices distortion and, hence, the magnetoelastic effect was weakened. The non-magnetic In-rich phase could suppress the movements of the magnetic domain and domain wall. Therefore, In-doping decreased the saturation magnetostriction and saturation magnetization of the Fe-Ga alloy. In-doping could also increase the coercivity of the Fe-Ga alloy. The addition of B and In changed the microstructures of the Fe-Ga alloys and accordingly their magnetic properties and magnetostriction.
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Keywords:
- Fe-Ga alloy,
- Magnetostriction,
- Fe2B phase,
- In-rich phase,
- EXAFS
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