Citation: CHEN Hao, YANG Tao, LI Jie-Wei, ZHANG Xin-Wen, QIAN Yan, XIE Ling-Hai, HUANG Wei. Synthesis and Optoelectronic Properties of a Solution- Processable Anthraquinone/Fluorene Hybrid Bipolar Fluorescent Material[J]. Acta Physico-Chimica Sinica, ;2016, 32(9): 2346-2354. doi: 10.3866/PKU.WHXB201605163 shu

Synthesis and Optoelectronic Properties of a Solution- Processable Anthraquinone/Fluorene Hybrid Bipolar Fluorescent Material

CHEN Hao ^1, ,
YANG Tao ¹ ,
LI Jie-Wei ² ,
ZHANG Xin-Wen ¹ ,
QIAN Yan ¹ ,
XIE Ling-Hai ¹ ,
HUANG Wei ^1,2

1.
Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210023, P. R. China;
2.
Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, P. R. China

Received Date: 21 March 2016
Revised Date: 16 May 2016

Fund Project: The project was supported by the National Key Basic Research Program of China (973) (2012CB723402), Jiangsu National Synergistic Innovation Center (2011) for Advanced Materials (SICAM), China, Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), China (YX03001), Synergistic Innovation Center for Organic Electronics and Information Displays, China, National Natural Science Foundation of China (21373114, 21573111), and Qing Lan Project and NUPT 1311 Project, China.

The solution-processable, anthraquinone-based, fluorene bipolar fluorescent material 2-(9,9'-bis (2-ethylhexyl)-9H-fluoren-2-yl)anthracene-9,10- dione (FAA) was synthesized via a Suzuki reaction. The photophysical properties of FAAwere subsequently investigated by acquiring absorption and photoluminescence spectra, and its optical properties were studied using computational density functional theory methods. Data obtained from single-carrier devices incorporating FAA demonstrated its well-matched bipolar charge-transport characteristics. The electroluminescence performance of this material was also examined by doping FAA into a 1,3-di(9H-carbazol-9-yl)benzene (mCP) matrix as the light-emitting layer via spin coating to produce an organic light-emitting diode (OLED) with an indiumtin oxide (ITO)/poly(3,4-ethylenedioxythiophene:poly(styrenesulfonate) (PEDOT:PSS)/mCP:FAA/3,3'-(5'-(3-(pyridin-3-yl)phenyl)-[1,1':3',1"-terphen-yl]-3,3"-diyl)dipyridine (TmPyPb)/ LiF/Al structure. This device exhibited a maximum luminance of 1719 cd·m^-2 with a turn-on voltage of 7.4 V, along with maximum current and power efficiencies of 1.66 cd·A^-1 and 0.56 lm·W^-1, respectively. The electroluminescence mechanism of the OLED is discussed based on the energy level diagrams of the functional layers.
- Organic light-emitting diode,
- Solution processing,
- Fluorescent material,
- Bipolar characteristics,
- Anthraquinone
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