Citation: ZHOU Ping-Ping, XI Xi, SONG Bing-Lei, PEI Xiao-Mei, CUI Zheng-Gang. Rheological Behavior of Trimeric Anionic Surfactant/Cationic Additive Mixed Systems[J]. Acta Physico-Chimica Sinica, ;2016, 32(9): 2309-2317. doi: 10.3866/PKU.WHXB201605125 shu

Rheological Behavior of Trimeric Anionic Surfactant/Cationic Additive Mixed Systems

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 18 March 2016
Revised Date: 12 May 2016

Fund Project: The project was supported by the Fundamental Research Funds for the Central Universities, China (JUSRP51507, JUSRP51405A) and National Natural Science Foundation of China (31300486).

Surfactant structure is known to have a significant effect on the formation and properties of wormlike micelles. In the present study, a new trimeric anionic surfactant (sodium 2,2',2"-(benzene-1,3,5-triyltris(oxy)) tritetradecanoate, abbreviated as Ph-TrisC₁₄Na) was synthesized from myristic acid and m-trihydroxybenzene. The viscoelastic properties of single component Ph-TrisC₁₄Na and Ph-TrisC₁₄Na/cationic additive systems were subsequently investigated by steady state and dynamic rheological measurements, using butyltrimethyl ammonium bromide (C₄TAB), hexyltrimethyl ammonium bromide (C₆TAB), and octyltrimethyl ammonium bromide (C₈TAB) as the additives. The results show that the unique molecular structure of Ph-TrisC₁₄Na enables the formation of wormlike micelles when this compound is the sole component of the solution, and generates solutions with significant viscoelasticity. The addition of cationic species further optimizes the molecular geometry of the Ph-TrisC₁₄Na and promotes the rapid growth of wormlike micelles. Additives with longer hydrophobic chains have a marked effect on the viscoelasticity and the microstructure of the mixed solution systems. A 50 mmol·L^-1 Ph-TrisC₁₄Na solution exhibits a zero shear viscosity of 1535 Pa·s together with micelle lengths in the range of 4.0 to 7.5 μm at a C₈TAB to Ph-TrisC₁₄Na molar ratio of 0.5. The present system shows the advantage of using an oligomeric surfactant in viscoelastic surfactant solutions. The information obtained from this work should be beneficial with regard to expanding the scope of highly viscoelastic anionic wormlike micellar systems.
- Trimeric anionic surfactant,
- Wormlike micelle,
- Organic additive,
- Molecular geometry,
- Viscoelasticity
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