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Citation: ZHAO Li-Yun, ZHANG Yu-Jin, MA Hong, LENG Jian-Cai. Influence of Terminal Group on Nonlinear Optical Properties of Fluorene Derivatives[J]. Acta Physico-Chimica Sinica, ;2016, 32(6): 1543-1548. doi: 10.3866/PKU.WHXB201603142 shu

Influence of Terminal Group on Nonlinear Optical Properties of Fluorene Derivatives

1.
chool of Science, Qilu University of Technology, Jinan 250353, P. R. China;
2.
School of Physics and Electronics, Shandong Normal University, Jinan 250014, P. R. China

Received Date: 14 December 2015
Revised Date: 11 March 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (11247307, 11304172, 11304186), Shandong Province Key Research Development Program, China (2015GGX101017), Qilu University of Technology Subject Construction Funds, China, Excellent Young Scholars Research Fund of Shandong Normal University, China, and International Cooperation Training Program for Young and Middle School Teachers in Shandong Province, China.

The nanosecond-scale propagations and optical-limiting properties of two fluorene derivatives-2, 7-bis(4'-(dimethylamino)-distyryl)-9H-fluorene (F1) and 2,7-bis(4'-(nitro)-distyryl)-9H-fluorene (F2) with different terminal groups are investigated by solving the coupled rate equations and field intensity equation using an iterative predictor-corrector finite-difference time-domain technique. The influence of the propagation distance (z), particle number density (N), and pulse width (τ) on the optical-limiting properties and two-photon absorption (TPA) of these molecules is analyzed. The calculations show that both F1 and F2 possess large two-photon absorption cross sections and pronounced optical-limiting properties. In addition, the nonlinear optical properties depend crucially on the terminal groups. F2, with terminal groups of ―NO₂, has much larger dipole moments, an enhanced two-photon absorption cross section, and superior optical-limiting ability compared with F1, which have terminal groups of ―N(CH₃)₂.
- Optical limiting,
- Two-photon absorption,
- Rate equation-field intensity equation,
- Fluorene derivative molecule
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