Citation: ZHANG Xue, HAN Yang, CHAI Shuang-Zhi, HU Nan-Tao, YANG Zhi, GENG Hui-Juan, WEI Hao. Advances in Cu₂ZnSn(S,Se)₄ Thin Film Solar Cells[J]. Acta Physico-Chimica Sinica, ;2016, 32(6): 1330-1346. doi: 10.3866/PKU.WHXB201603073 shu

Advances in Cu₂ZnSn(S,Se)₄ Thin Film Solar Cells

1.
School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2.
College of Physics and Electronic Engineering, Anyang Normal University, Anyang 455000, Henan Province, P. R. China

Received Date: 18 January 2016
Revised Date: 7 March 2016

CdTe and Cu(In,Ga)(S,Se)₂ (CIGSSe) light absorber materials have dominated the research field of compound semiconductor solar cells. Despite the high power conversion efficiencies and technological advances of CdTe and CIGS photovoltaic technologies, certain issues, like rare earth constituent elements or toxic elements, limit their future upscaled applications. In recent years, Cu₂ZnSn(S,Se)₄ (CZTSSe) thin film solar cells have become research hotspots, drawing increased interest. With earth-abundant and environmentallybenign constituent elements, CZTSSe light absorber materials are widely regarded as the next-generation photovoltaic technology that can replace CdTe and CIGS as a promising candidate for terawatt-level power output. In this review, the synthesis, structure, and properties of CZTSSe materials will be discussed. This review will primarily demonstrate the developments and recent advances of different fabrication techniques and deposition methods, such as vacuum-based and solution-based deposition methods, covering their advantages and disadvantages. Recent developments in CZTSSe fabrication methods and CZTSSe nanocrystal preparation approaches will also be reviewed. Finally, some limitations on CZTSSe photovoltaic technology will be analyzed, and directions for improvement will be suggested, helping scientists to make future developments in this field.
- Cu₂ZnSn(S,Se)₄,
- Thin film,
- Solar cell,
- Preparation method,
- Research progress
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Advances in Cu₂ZnSn(S,Se)₄ Thin Film Solar Cells