Citation: SUN Li-Yuan, ZHANG Ya-Fei, GONG Yan-Jun. Structural Features and Application of Micro-Microporous Composite Zeolites[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1105-1122. doi: 10.3866/PKU.WHXB201603015 shu

Structural Features and Application of Micro-Microporous Composite Zeolites

1.
State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis of China National Petroleum Corporation, China University of Petroleum, Beijing 102249, P. R. China

Corresponding author: GONG Yan-Jun,
Received Date: 22 December 2015
Available Online: 29 February 2016
Fund Project: 国家重点基础研究发展计划(2012CB215002) (2012CB215002)国家自然科学基金(21176255,21276278) (21176255,21276278)中国石油股份公司项目(2014A-2111)资助 (2014A-2111)

Micro-microporous composite zeolites with binary (or more) structures not only possess the advantages of the two kinds of molecular sieves, but also tailor the pore structure and acid property of the composite samples. These changes induce the formation of special properties of the composites and further present special catalytic performance, which drives many research studies. Based on synthetic methods and micro-structural features, micro-microporous composites can mainly be divided into two types: intergrowth or co-existence composite zeolites. The former has a structural rearrangement that is produced by the stacking of distinct layers and leads to the generation of a new crystal structure. The latter is formed by staggered growth and has a compound interface when two or more zeolites appeared in the same gel system. Compared with the intergrowth zeolites, the co-existence zeolites do not possess the new and perfect crystal structure. This review summarizes the development of micro-microporous composites, focusing on their synthesis and structural characteristics as well as the application of intergrowth and co-existence composite zeolites in the field of catalytic reactions.
- Zeolite,
- Micro-microporous composite zeolite,
- Intergrowth zeolite,
- Co-existence zeolite,
- Catalytic application
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