Citation:
SHI Ji-Fu, HUANG Qi-Zhang, WAN Qing-Cui, XU Xue-Qing, LI Chun-Sheng, XU Gang. Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica,
;2016, 32(4): 822-827.
doi:
10.3866/PKU.WHXB201602262
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We report the preparation and application of a 1-methyl-3-propylimidazolium sulfide-based ionic liquid electrolyte for quantum-dot-sensitized solar cells. By optimizing the concentrations of S and Na2S, a considerable conductivity of 12.96 mS·cm-1 is achieved at 25℃. Differential scanning calorimetry indicates that the glass transition temperature of the electrolyte is-85℃. The quantum-dot-sensitized solar cell assembled with this ionic liquid electrolyte displays a high energy conversion efficiency (η) of 3.03% at 25℃, which is comparable to the efficiency of quantum-dot-sensitized solar cells using a water-based polysulfide electrolyte (η= 3.34%). Due to the favorable thermal properties of this ionic liquid electrolyte (lower glass transition temperature and nonvolatility at higher temperatures), the quantum-dot-sensitized solar cell maintains satisfactory η even at-20℃ (η= 2.32%) and 80℃ (η= 1.90%), which is superior to the cell using the water-based polysulfide electrolyte.
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