Citation: ZHOU Li, ZHU Jun, XU Ya-Feng, SHAO Zhi-Peng, ZHANG Xu-Hui, YE Jia-Jiu, HUANG Yang, ZHANG Chang-Neng, DAI Song-Yuan. Influence of Insulating Oxide Coatings on the Performance of Perovskite Solar Cells and the Interface Charge Recombination Dynamics[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1207-1213. doi: 10.3866/PKU.WHXB201602241 shu

Influence of Insulating Oxide Coatings on the Performance of Perovskite Solar Cells and the Interface Charge Recombination Dynamics

  • Corresponding author: ZHU Jun,  DAI Song-Yuan, 
  • Received Date: 11 December 2015
    Available Online: 22 February 2016

    Fund Project: 国家高技术研究发展计划(863)(2015AA050602) (863)(2015AA050602)国家自然科学基金(21403247)资助项目 (21403247)

  • Insulating oxides of SiO2, ZrO2, and Al2O3 were coated using a dipping method on the surface of mesoporous TiO2 nanoparticles for perovskite solar cells. The effects of the insulating oxide coatings on the performance of the perovskite solar cells and the interface charge recombination dynamics were investigated in detail. The efficiency of devices after SiO2 coating improved by 13.7% due to their FF (fill factor) increasing from 67.6% to 72.3%. However, the devices with ZrO2 and Al2O3 coatings exhibited an increase in Voc of up to 50 mV and a decrease in Jsc and FF. Transient absorption spectroscopy on a timescale from nanoseconds to milliseconds was performed to study the interface recombination lifetime between electrons and holes and the changes of the device performances are discussed.
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    1. [1]

      (1) Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. J. Am. Chem. Soc. 2009, 131, 6050. doi: 10.1021/ja809598r

    2. [2]

      (2) Yang, W. S.; Noh, J. H.; Jeon, N. J.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Science 2015, 348 (6240), 1234. doi: 10.1126/science.aaa9272

    3. [3]

      (3) Prashant, V. K. J. Am. Chem. Soc. 2014, 136, 3713. doi: 10.1021/ja501108n

    4. [4]

      (4) Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; Snaith, H. J. Science 2013, 342, 341. doi: 10.1126/science.1243982

    5. [5]

      (5) Xing, G.; Mathews, N.; Sun, S. S.; Lam, Y. M.; Grätzel, M.; Mhaisalkar, S.; Sum, T. C. Science 2013, 342, 344. doi: 10.1126/science.1243167

    6. [6]

      (6) Wehrenfennig, C.; Eperon, G. E.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. Adv. Mater. 2014, 26, 1584. doi: 10.1002/adma.201305172

    7. [7]

      (7) Marchioro, A.; Teuscher, J.; Friedrich, D.; Kunst, M.; van de Krol, R.; Moehl, T.; Grätzel, M.; Moser, J. E. Nat. Photon. 2014, 8(3), 250.

    8. [8]

      (8) Ponseca, C. S.; Savenije, T. J.; Abdellah, M.; Zheng, K.; Yartsev, A.; Pascher, T.; Harlang, T.; Chabera, P.; Pullerits, T.; Stepanov, A.; Wolf, J. P.; Sundström, V. J. Am. Chem. Soc. 2014, 136, 5189. doi: 10.1038photon.2013.374

    9. [9]

      (9) Shen, Q.; Ogomi, Y.; Chang, J.; Tsukamoto, S.; Kukihara, K.; Oshima, T.; Osada, N.; Yoshino, K.; Katayama, K.; Toyoda, T.; Hayase, S. Phys. Chem. Chem. Phys. 2014, 16 (37), 19984. doi: 10.1039/C4CP03073G

    10. [10]

      (10) Dualeh, A.; Moehl, T.; Tétreault, N.; Teuscher, J.; Gao, P.; Nazeeruddin, M. K.; Grätzel, M. ACS Nano 2014, 8, 362.

    11. [11]

      (11) Leijtens, T.; Lauber, B.; Eperon, G. E.; Stranks, S. D.; Snaith, H. J. J. Phys. Chem. Lett. 2014, 5, 1096. doi: 10.1021/jz500209g

    12. [12]

      (12) Marin-Beloqui, J. M.; Hernandez, J. P.; Palomares, E. Chem. Commun. 2014, 50, 14566. doi: 10.1039/C4CC06338D

    13. [13]

      (13) Kay, A.; Grätzel, M. Chem. Mater. 2002, 14, 2930. doi: 10.1021/cm0115968

    14. [14]

      (14) Palomares, E.; Clifford, J. N.; Haque, S. A.; Lutz, T.; Durrant, J. R. Chem. Commun. 2002, (14), 1464.

    15. [15]

      (15) Ogomi, Y.; Kukihara, K.; Shen, Q.; Toyoda, T.; Yoshino, K.; Pandey, S.; Momose, H.; Hayase, S. ChemPhysChem 2014, 15, 1062. doi: 10.1002/cphc.201301153

    16. [16]

      (16) Baikie, T.; Fang, Y.; Kadro, J. M.; Wei, F.; Mhaisalkar, S. G.; Grätzel, M.; White, T. J. J. Mater. Chem. A 2013, 1, 5628.

    17. [17]

      (17) Jeon, N. J.; Lee, J.; Noh, J. H.; Nazeeruddin, M. K.; Grätzel, M.; Seok, S. I. J. Am. Chem. Soc. 2013, 135, 19087. doi: 10.1021/ja410659k

    18. [18]

      (18) Shao, Z. P.; Pan, X.; Zhang, X. H.; Ye, J. J.; Zhu, L. Z.; Li, Y.; Ma, Y. M.; Huang, Y.; Zhu, J.; Hu, L.; Kong, F. T.; Dai, S. Y. Acta Chim. Sin. 2015, 73, 267. [邵志鹏, 潘旭, 张旭辉, 叶加久, 朱梁正, 李毅, 马艳梅, 黄阳, 朱俊, 胡林华, 孔凡太, 戴松元. 化学学报, 2015, 73, 367.] doi: 10.6023/A14100721

    19. [19]

      (19) Dai, S. Y.; Li, Z. Q.; Tao, L.; Hu, L. H. Journal of Anhui Normal University (Natural Science) 2015, (4), 001. [戴松元, 李兆乾, 桃李, 胡林华. 安徽师范大学学报(自然科学版), 2015, (4), 001.]

    20. [20]

      (20) Liang, J.; Zhang, G.; Sun.W. RSC Adv. 2014, 4, 6746. doi: 10.1039/c3ra46188b

    21. [21]

      (21) Li, W. X.; Hu, L. H.; Dai, S. Y. Acta Phys. -Chim. Sin. 2011, 27 (10), 2367. [李文欣, 胡林华, 戴松元. 物理化学学报, 2011, 27 (10), 2367.] doi: 10.3866/PKU.WHXB20111011

    22. [22]

      (22) Stranks, S. D.; Burlakov, V. M.; Leijtens, T.; Ball, J. M.; Goriely, A.; Snaith, H. J. Phys. Rev. Appl. 2014, 2, 034007.

    23. [23]

      (23) Abate, A.; Saliba, M.; Hollman, D. J.; Stranks, S. D.; Wojciechowski, K.; Avolio, R.; Grancini, G.; Petrozza, A.; Snaith, H. J. Nano Lett. 2014, 14 (6), 3247. doi: 10.1021l500627x

    24. [24]

      (24) Olson, C.; Veldman, D.; Bakker, K.; Lenzmann, F. Int. J. Photoenergy 2011, 513089.

    25. [25]

      (25) Matas Adams, A.; Marin-Beloqui, J. M.; Stoica, G.; Palomares, E. J. Mater. Chem. A 2015, 3, 22154. doi: 10.1039/C5TA06041A

    26. [26]

      (26) Marin-Beloqui, J. M.; Hernandez, J. P.; Palomares, E. Chem. Commun. 2014, 50, 14566. doi: 10.1039/C4CC06338D

    27. [27]

      (27) Ogomi, Y.; Kukihara, K.; Qing, S.; Toyoda, T.; Yoshino, K.; Pandey, S.; Momose, H.; Hayase, S. ChemPhysChem 2014, 15 (6), 1062. doi: 10.1002/cphc.201301153

    28. [28]

      (28) Palomares, E.; Clifford, J. N.; Haque, S. A.; Lutz, T.; Durrant, J. R. J. Am. Chem. Soc. 2003, 125 (2), 475. doi: 10.1021/ja027945w

    29. [29]

      (29) Zhao, K.; Pan, Z.; Mora-Seró, I.; Cánovas, E.; Wang, H.; Song, Y.; Gong, X.; Wang, J.; Bonn, M.; Bisquert, J.; Zhong, X. J. Am. Chem. Soc. 2015, 137, 5602. doi: 10.1021/jacs.5b01946

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