Citation:
ZHOU Li, ZHU Jun, XU Ya-Feng, SHAO Zhi-Peng, ZHANG Xu-Hui, YE Jia-Jiu, HUANG Yang, ZHANG Chang-Neng, DAI Song-Yuan. Influence of Insulating Oxide Coatings on the Performance of Perovskite Solar Cells and the Interface Charge Recombination Dynamics[J]. Acta Physico-Chimica Sinica,
;2016, 32(5): 1207-1213.
doi:
10.3866/PKU.WHXB201602241
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Insulating oxides of SiO2, ZrO2, and Al2O3 were coated using a dipping method on the surface of mesoporous TiO2 nanoparticles for perovskite solar cells. The effects of the insulating oxide coatings on the performance of the perovskite solar cells and the interface charge recombination dynamics were investigated in detail. The efficiency of devices after SiO2 coating improved by 13.7% due to their FF (fill factor) increasing from 67.6% to 72.3%. However, the devices with ZrO2 and Al2O3 coatings exhibited an increase in Voc of up to 50 mV and a decrease in Jsc and FF. Transient absorption spectroscopy on a timescale from nanoseconds to milliseconds was performed to study the interface recombination lifetime between electrons and holes and the changes of the device performances are discussed.
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[1]
(1) Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. J. Am. Chem. Soc. 2009, 131, 6050. doi: 10.1021/ja809598r
-
[2]
(2) Yang, W. S.; Noh, J. H.; Jeon, N. J.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Science 2015, 348 (6240), 1234. doi: 10.1126/science.aaa9272
-
[3]
(3) Prashant, V. K. J. Am. Chem. Soc. 2014, 136, 3713. doi: 10.1021/ja501108n
-
[4]
(4) Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; Snaith, H. J. Science 2013, 342, 341. doi: 10.1126/science.1243982
-
[5]
(5) Xing, G.; Mathews, N.; Sun, S. S.; Lam, Y. M.; Grätzel, M.; Mhaisalkar, S.; Sum, T. C. Science 2013, 342, 344. doi: 10.1126/science.1243167
-
[6]
(6) Wehrenfennig, C.; Eperon, G. E.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. Adv. Mater. 2014, 26, 1584. doi: 10.1002/adma.201305172
-
[7]
(7) Marchioro, A.; Teuscher, J.; Friedrich, D.; Kunst, M.; van de Krol, R.; Moehl, T.; Grätzel, M.; Moser, J. E. Nat. Photon. 2014, 8(3), 250.
-
[8]
(8) Ponseca, C. S.; Savenije, T. J.; Abdellah, M.; Zheng, K.; Yartsev, A.; Pascher, T.; Harlang, T.; Chabera, P.; Pullerits, T.; Stepanov, A.; Wolf, J. P.; Sundström, V. J. Am. Chem. Soc. 2014, 136, 5189. doi: 10.1038photon.2013.374
-
[9]
(9) Shen, Q.; Ogomi, Y.; Chang, J.; Tsukamoto, S.; Kukihara, K.; Oshima, T.; Osada, N.; Yoshino, K.; Katayama, K.; Toyoda, T.; Hayase, S. Phys. Chem. Chem. Phys. 2014, 16 (37), 19984. doi: 10.1039/C4CP03073G
-
[10]
(10) Dualeh, A.; Moehl, T.; Tétreault, N.; Teuscher, J.; Gao, P.; Nazeeruddin, M. K.; Grätzel, M. ACS Nano 2014, 8, 362.
-
[11]
(11) Leijtens, T.; Lauber, B.; Eperon, G. E.; Stranks, S. D.; Snaith, H. J. J. Phys. Chem. Lett. 2014, 5, 1096. doi: 10.1021/jz500209g
-
[12]
(12) Marin-Beloqui, J. M.; Hernandez, J. P.; Palomares, E. Chem. Commun. 2014, 50, 14566. doi: 10.1039/C4CC06338D
-
[13]
(13) Kay, A.; Grätzel, M. Chem. Mater. 2002, 14, 2930. doi: 10.1021/cm0115968
-
[14]
(14) Palomares, E.; Clifford, J. N.; Haque, S. A.; Lutz, T.; Durrant, J. R. Chem. Commun. 2002, (14), 1464.
-
[15]
(15) Ogomi, Y.; Kukihara, K.; Shen, Q.; Toyoda, T.; Yoshino, K.; Pandey, S.; Momose, H.; Hayase, S. ChemPhysChem 2014, 15, 1062. doi: 10.1002/cphc.201301153
-
[16]
(16) Baikie, T.; Fang, Y.; Kadro, J. M.; Wei, F.; Mhaisalkar, S. G.; Grätzel, M.; White, T. J. J. Mater. Chem. A 2013, 1, 5628.
-
[17]
(17) Jeon, N. J.; Lee, J.; Noh, J. H.; Nazeeruddin, M. K.; Grätzel, M.; Seok, S. I. J. Am. Chem. Soc. 2013, 135, 19087. doi: 10.1021/ja410659k
-
[18]
(18) Shao, Z. P.; Pan, X.; Zhang, X. H.; Ye, J. J.; Zhu, L. Z.; Li, Y.; Ma, Y. M.; Huang, Y.; Zhu, J.; Hu, L.; Kong, F. T.; Dai, S. Y. Acta Chim. Sin. 2015, 73, 267. [邵志鹏, 潘旭, 张旭辉, 叶加久, 朱梁正, 李毅, 马艳梅, 黄阳, 朱俊, 胡林华, 孔凡太, 戴松元. 化学学报, 2015, 73, 367.] doi: 10.6023/A14100721
-
[19]
(19) Dai, S. Y.; Li, Z. Q.; Tao, L.; Hu, L. H. Journal of Anhui Normal University (Natural Science) 2015, (4), 001. [戴松元, 李兆乾, 桃李, 胡林华. 安徽师范大学学报(自然科学版), 2015, (4), 001.]
-
[20]
(20) Liang, J.; Zhang, G.; Sun.W. RSC Adv. 2014, 4, 6746. doi: 10.1039/c3ra46188b
-
[21]
(21) Li, W. X.; Hu, L. H.; Dai, S. Y. Acta Phys. -Chim. Sin. 2011, 27 (10), 2367. [李文欣, 胡林华, 戴松元. 物理化学学报, 2011, 27 (10), 2367.] doi: 10.3866/PKU.WHXB20111011
-
[22]
(22) Stranks, S. D.; Burlakov, V. M.; Leijtens, T.; Ball, J. M.; Goriely, A.; Snaith, H. J. Phys. Rev. Appl. 2014, 2, 034007.
-
[23]
(23) Abate, A.; Saliba, M.; Hollman, D. J.; Stranks, S. D.; Wojciechowski, K.; Avolio, R.; Grancini, G.; Petrozza, A.; Snaith, H. J. Nano Lett. 2014, 14 (6), 3247. doi: 10.1021l500627x
-
[24]
(24) Olson, C.; Veldman, D.; Bakker, K.; Lenzmann, F. Int. J. Photoenergy 2011, 513089.
-
[25]
(25) Matas Adams, A.; Marin-Beloqui, J. M.; Stoica, G.; Palomares, E. J. Mater. Chem. A 2015, 3, 22154. doi: 10.1039/C5TA06041A
-
[26]
(26) Marin-Beloqui, J. M.; Hernandez, J. P.; Palomares, E. Chem. Commun. 2014, 50, 14566. doi: 10.1039/C4CC06338D
-
[27]
(27) Ogomi, Y.; Kukihara, K.; Qing, S.; Toyoda, T.; Yoshino, K.; Pandey, S.; Momose, H.; Hayase, S. ChemPhysChem 2014, 15 (6), 1062. doi: 10.1002/cphc.201301153
-
[28]
(28) Palomares, E.; Clifford, J. N.; Haque, S. A.; Lutz, T.; Durrant, J. R. J. Am. Chem. Soc. 2003, 125 (2), 475. doi: 10.1021/ja027945w
-
[29]
(29) Zhao, K.; Pan, Z.; Mora-Seró, I.; Cánovas, E.; Wang, H.; Song, Y.; Gong, X.; Wang, J.; Bonn, M.; Bisquert, J.; Zhong, X. J. Am. Chem. Soc. 2015, 137, 5602. doi: 10.1021/jacs.5b01946
-
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