Citation: ZHOU Li, ZHU Jun, XU Ya-Feng, SHAO Zhi-Peng, ZHANG Xu-Hui, YE Jia-Jiu, HUANG Yang, ZHANG Chang-Neng, DAI Song-Yuan. Influence of Insulating Oxide Coatings on the Performance of Perovskite Solar Cells and the Interface Charge Recombination Dynamics[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1207-1213. doi: 10.3866/PKU.WHXB201602241 shu

Influence of Insulating Oxide Coatings on the Performance of Perovskite Solar Cells and the Interface Charge Recombination Dynamics

1.
1 School of Physics and Materials Science, Anhui University, Hefei 230601, P. R. China;
2.
2 Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Science, Hefei 230031, P. R. China;

Corresponding author: ZHU Jun, DAI Song-Yuan,
Received Date: 11 December 2015
Available Online: 22 February 2016
Fund Project: 国家高技术研究发展计划(863)(2015AA050602) (863)(2015AA050602)国家自然科学基金(21403247)资助项目 (21403247)

Insulating oxides of SiO₂, ZrO₂, and Al₂O₃ were coated using a dipping method on the surface of mesoporous TiO₂ nanoparticles for perovskite solar cells. The effects of the insulating oxide coatings on the performance of the perovskite solar cells and the interface charge recombination dynamics were investigated in detail. The efficiency of devices after SiO₂ coating improved by 13.7% due to their FF (fill factor) increasing from 67.6% to 72.3%. However, the devices with ZrO₂ and Al₂O₃ coatings exhibited an increase in V_oc of up to 50 mV and a decrease in J_sc and FF. Transient absorption spectroscopy on a timescale from nanoseconds to milliseconds was performed to study the interface recombination lifetime between electrons and holes and the changes of the device performances are discussed.
- Perovskite solar cell,
- Recombination lifetime,
- Transient absorption,
- Surface coating,
- Metal oxide
1. [1]
  (1) Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. J. Am. Chem. Soc. 2009, 131, 6050. doi: 10.1021/ja809598r
2. [2]
  (2) Yang, W. S.; Noh, J. H.; Jeon, N. J.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Science 2015, 348 (6240), 1234. doi: 10.1126/science.aaa9272
3. [3]
  (3) Prashant, V. K. J. Am. Chem. Soc. 2014, 136, 3713. doi: 10.1021/ja501108n
4. [4]
  (4) Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; Snaith, H. J. Science 2013, 342, 341. doi: 10.1126/science.1243982
5. [5]
  (5) Xing, G.; Mathews, N.; Sun, S. S.; Lam, Y. M.; Grätzel, M.; Mhaisalkar, S.; Sum, T. C. Science 2013, 342, 344. doi: 10.1126/science.1243167
6. [6]
  (6) Wehrenfennig, C.; Eperon, G. E.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. Adv. Mater. 2014, 26, 1584. doi: 10.1002/adma.201305172
7. [7]
  (7) Marchioro, A.; Teuscher, J.; Friedrich, D.; Kunst, M.; van de Krol, R.; Moehl, T.; Grätzel, M.; Moser, J. E. Nat. Photon. 2014, 8(3), 250.
8. [8]
  (8) Ponseca, C. S.; Savenije, T. J.; Abdellah, M.; Zheng, K.; Yartsev, A.; Pascher, T.; Harlang, T.; Chabera, P.; Pullerits, T.; Stepanov, A.; Wolf, J. P.; Sundström, V. J. Am. Chem. Soc. 2014, 136, 5189. doi: 10.1038photon.2013.374
9. [9]
  (9) Shen, Q.; Ogomi, Y.; Chang, J.; Tsukamoto, S.; Kukihara, K.; Oshima, T.; Osada, N.; Yoshino, K.; Katayama, K.; Toyoda, T.; Hayase, S. Phys. Chem. Chem. Phys. 2014, 16 (37), 19984. doi: 10.1039/C4CP03073G
10. [10]
  (10) Dualeh, A.; Moehl, T.; Tétreault, N.; Teuscher, J.; Gao, P.; Nazeeruddin, M. K.; Grätzel, M. ACS Nano 2014, 8, 362.
11. [11]
  (11) Leijtens, T.; Lauber, B.; Eperon, G. E.; Stranks, S. D.; Snaith, H. J. J. Phys. Chem. Lett. 2014, 5, 1096. doi: 10.1021/jz500209g
12. [12]
  (12) Marin-Beloqui, J. M.; Hernandez, J. P.; Palomares, E. Chem. Commun. 2014, 50, 14566. doi: 10.1039/C4CC06338D
13. [13]
  (13) Kay, A.; Grätzel, M. Chem. Mater. 2002, 14, 2930. doi: 10.1021/cm0115968
14. [14]
  (14) Palomares, E.; Clifford, J. N.; Haque, S. A.; Lutz, T.; Durrant, J. R. Chem. Commun. 2002, (14), 1464.
15. [15]
  (15) Ogomi, Y.; Kukihara, K.; Shen, Q.; Toyoda, T.; Yoshino, K.; Pandey, S.; Momose, H.; Hayase, S. ChemPhysChem 2014, 15, 1062. doi: 10.1002/cphc.201301153
16. [16]
  (16) Baikie, T.; Fang, Y.; Kadro, J. M.; Wei, F.; Mhaisalkar, S. G.; Grätzel, M.; White, T. J. J. Mater. Chem. A 2013, 1, 5628.
17. [17]
  (17) Jeon, N. J.; Lee, J.; Noh, J. H.; Nazeeruddin, M. K.; Grätzel, M.; Seok, S. I. J. Am. Chem. Soc. 2013, 135, 19087. doi: 10.1021/ja410659k
18. [18]
  (18) Shao, Z. P.; Pan, X.; Zhang, X. H.; Ye, J. J.; Zhu, L. Z.; Li, Y.; Ma, Y. M.; Huang, Y.; Zhu, J.; Hu, L.; Kong, F. T.; Dai, S. Y. Acta Chim. Sin. 2015, 73, 267. [邵志鹏, 潘旭, 张旭辉, 叶加久, 朱梁正, 李毅, 马艳梅, 黄阳, 朱俊, 胡林华, 孔凡太, 戴松元. 化学学报, 2015, 73, 367.] doi: 10.6023/A14100721
19. [19]
  (19) Dai, S. Y.; Li, Z. Q.; Tao, L.; Hu, L. H. Journal of Anhui Normal University (Natural Science) 2015, (4), 001. [戴松元, 李兆乾, 桃李, 胡林华. 安徽师范大学学报(自然科学版), 2015, (4), 001.]
20. [20]
  (20) Liang, J.; Zhang, G.; Sun.W. RSC Adv. 2014, 4, 6746. doi: 10.1039/c3ra46188b
21. [21]
  (21) Li, W. X.; Hu, L. H.; Dai, S. Y. Acta Phys. -Chim. Sin. 2011, 27 (10), 2367. [李文欣, 胡林华, 戴松元. 物理化学学报, 2011, 27 (10), 2367.] doi: 10.3866/PKU.WHXB20111011
22. [22]
  (22) Stranks, S. D.; Burlakov, V. M.; Leijtens, T.; Ball, J. M.; Goriely, A.; Snaith, H. J. Phys. Rev. Appl. 2014, 2, 034007.
23. [23]
  (23) Abate, A.; Saliba, M.; Hollman, D. J.; Stranks, S. D.; Wojciechowski, K.; Avolio, R.; Grancini, G.; Petrozza, A.; Snaith, H. J. Nano Lett. 2014, 14 (6), 3247. doi: 10.1021l500627x
24. [24]
  (24) Olson, C.; Veldman, D.; Bakker, K.; Lenzmann, F. Int. J. Photoenergy 2011, 513089.
25. [25]
  (25) Matas Adams, A.; Marin-Beloqui, J. M.; Stoica, G.; Palomares, E. J. Mater. Chem. A 2015, 3, 22154. doi: 10.1039/C5TA06041A
26. [26]
  (26) Marin-Beloqui, J. M.; Hernandez, J. P.; Palomares, E. Chem. Commun. 2014, 50, 14566. doi: 10.1039/C4CC06338D
27. [27]
  (27) Ogomi, Y.; Kukihara, K.; Qing, S.; Toyoda, T.; Yoshino, K.; Pandey, S.; Momose, H.; Hayase, S. ChemPhysChem 2014, 15 (6), 1062. doi: 10.1002/cphc.201301153
28. [28]
  (28) Palomares, E.; Clifford, J. N.; Haque, S. A.; Lutz, T.; Durrant, J. R. J. Am. Chem. Soc. 2003, 125 (2), 475. doi: 10.1021/ja027945w
29. [29]
  (29) Zhao, K.; Pan, Z.; Mora-Seró, I.; Cánovas, E.; Wang, H.; Song, Y.; Gong, X.; Wang, J.; Bonn, M.; Bisquert, J.; Zhong, X. J. Am. Chem. Soc. 2015, 137, 5602. doi: 10.1021/jacs.5b01946
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