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Citation: TONG Jing, CHEN Teng-Fei, ZHANG Duo, WANG Lin-Fu, TONG Jian, YANG Jia-Zhen. Molar Surface Gibbs Free Energy of the Aqueous Solution of the Ionic Liquid [C2mim][OAc][J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1161-1167. doi: 10.3866/PKU.WHXB201602232 shu

Molar Surface Gibbs Free Energy of the Aqueous Solution of the Ionic Liquid [C2mim][OAc]

  • 1.

    College of Chemistry, Liaoning University, Shenyang 110036, P. R. China

  • Corresponding author: TONG Jing, 
  • Received Date: 27 November 2015
    Available Online: 22 February 2016

    Fund Project: 国家自然科学基金(21273003) (21273003)辽宁省教育厅项目(LJQ2013001) (LJQ2013001)辽宁省百千万人才项目(2013921029)资助 (2013921029)

  • The values of the density and surface tension for an aqueous solution of the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate [C2mim][OAc] with various molalities were measured from 288.15 to 318.15 K with intervals of 5 K. Based on the thermodynamic model of the surface tension of a solution proposed by LI Yi-Gui et al., a new concept of the molar surface Gibbs free energy was proposed and a linear empirical equation between the molar surface Gibbs free energy and the concentration of the solution was established. Using this empirical equation, the molar surface Gibbs free energy of aqueous [C2mim][OAc] was estimated. Using the estimated molar surface Gibbs free energy, the surface tension of the solution was predicted. The predicted values and corresponding experimental values are in agreement. Thus, the molar surface Gibbs free energy may become a semi-empirical method to predict the properties of ILs and their solution parachor. From the molar Gibbs free energy, a new Eötvös equation was obtained and each parameter of the new equation has a clear physical meaning.
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    1. [1]

      (1) Zhang, S.; Wang, J.; Lu, X.; Zhou, Q. Structures and Interactions of Ionic Liquids; Springer-Verlag: Berlin Heidelberg, 2014.

    2. [2]

      (2) Armand, M.; Endres, F.; MacFarlane, D. R.; Ohno, H.; Scrosati, B. Nat. Mater. 2009, 8, 621. doi: 10.1038/nmat2448

    3. [3]

      (3) Hallett, J. P.; Welton, T. Chem. Rev. 2011, 111, 3508. doi: 10.1021/cr1003248

    4. [4]

      (4) Chen, Z. J.; Lee, J. M. J. Phys. Chem. B 2014, 118, 2712. doi: 10.1021/jp411904w

    5. [5]

      (5) Rocha, M. A. A.; Lima, C. F. R. A. C.; Gomes, L. R.; Schröder, B.; Coutinho, J. A. P.; Marrucho, I. M.; Esperança, J. M. S. S.; Rebelo, L. P. N.; Shimizu, K.; Lopes, J. N. C.; Santos, L. M. N. B. F. J. Phys. Chem. B 2011, 115, 10919. doi: 10.1021/jp2049316

    6. [6]

      (6) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan. Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山, 颜佩芳, 杨淼, 谭志诚, 李长平, Welz-Biermann, U. 物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762

    7. [7]

      (7) Geppert-Rybczynska, M.; Lehmann, J. K.; Heintz, A. J. Chem. Thermodynamics 2014, 71, 171. doi: 10.1016/j.jct.2013.12.009

    8. [8]

      (8) Tong, J.; Hong, M.; Chen, Y.; Wang, H.; Yang, J. Z. J. Chem. Eng. Data 2012, 57 (8), 2265. doi: 10.1021/je300161h

    9. [9]

      (9) Li, Y. G.; Lu, J. F. The Theory of Electrolyte Solution; Press of Qinghua University: Beijing, 2005; pp 330-333. [李以圭, 陆九芳. 电解质溶液理论. 北京: 清华大学出版社, 2005: 330-333.]

    10. [10]

      (10) Li, Y. G. Ind. Eng. Chem. Res. 1999, 38, 4137. doi: 10.1021/ie991069m

    11. [11]

      (11) Li, Z. B.; Li, Y. G.; Lu, J. F. Ind. Eng. Chem. Res. 1999, 38, 1133. doi: 10.1021/ie980465m

    12. [12]

      (12) Tong, J.; Kong, Y. X.; Wang, P. P.; Dai, L. L.; Yang, J. Z. Sci. China Chem. 2012, 42, 776. [佟静, 孔玉霞, 王盼盼, 代丽丽, 杨家振. 中国科学: 化学, 2012, 42, 776.] doi: 10.1360/032011-369

    13. [13]

      (13) Xu, W. G.; Li, C.; Liu, R. J.; Yang, H. X.; Tong, J.; Yang, J. Z. Ind. Eng. Chem. Res. 2014, 53, 9959. doi: 10.1021/ie501240t

    14. [14]

      (14) Tong, J.; Chen, T. F.; Wang, L. F.; Zhang, D.; Yang, Q.; Yang, J. Z. J. Solut. Chem. 2016, doi: 10.1007/s10953-015-0423-0)

    15. [15]

      (15) Tong, J.; Li, J. B.; Zhang, Q. G.; Yang, J. Z. Acta Chim. Sin. 2007, 65, 315. [佟静, 李景斌, 张庆国, 杨家振. 化学学报, 2007, 65, 315.]

    16. [16]

      (16) Yang, J. Z.; Li, J. B.; Tong, J.; Hong, M. Acta Chim. Sin. 2007, 65, 655. [杨家振, 李景斌, 佟静, 洪梅. 化学学报, 2007, 65, 655.]

    17. [17]

      (17) Guan, W.; Ma, X. X.; Li, L.; Tong, J.; Fang, D.W.; Yang, J. Z. J. Phys. Chem. B 2011, 115, 12915. doi: 10.1021/jp207882t

    18. [18]

      (18) Li, C.; Yang, H. X.; Liu, R. J.; Yang, Q.; Tong, J.; Yang, J. Z. Acta Phys. -Chim. Sin. 2015, 31 (1), 11. [李驰, 杨宏旭, 刘入境, 杨奇, 佟静, 杨家振. 物理化学学报, 2015, 31 (1), 11.] doi: 10.3866/PKU.WHXB201411063

    19. [19]

      (19) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; Boca Raton: CRC Press, 2001-2002.

    20. [20]

      (20) Krossing, I.; Slattery, J. M. Z. Phys. Chem. 2006, 220, 1343. doi: 10.1524/zpch.2006.220.10.1343

    21. [21]

      (21) Deetlefs, M.; Seddon, K. R.; Shara, M. Phys. Chem. Chem. Phys. 2006, 8, 642. doi: 10.1039/B513453F

    22. [22]

      (22) Tong, J.; Yang, H. X.; Liu, R. J.; Li, C.; Xia, L. X.; Yang, J. Z. J. Phys. Chem. B 2014, 118, 12972. doi: 10.1021/jp509240w

    23. [23]

      (23) Adamson, A.W. Physical Chemistry of Surfaces, 3rd ed.; Science Press: Beijing, 1986; translated by Gu, T. R. [Adamson, A.W. 表面的物理化学. 顾惕人, 译. 北京: 科学出版社, 1986.]

    24. [24]

      (24) Tong, J.; Zhang, Q. G.; Hong, M.; Yang, J. Z. Acta Phys. -Chim. Sin. 2006, 22 (1), 71. [佟静, 张庆国, 洪梅, 杨家振. 物理化学学报, 2006, 22 (1), 71.] doi: 10.3866/PKU.WHXB20060114

    25. [25]

      (25) Mountain, B.W.; Seward, T. M. Geochimica et Cosmochimica Acta 2003, 67, 3005. doi: 10.1016/S0016-7037(03)00303-X

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