Citation: LIU Guo, LU Yuan-Yuan, ZHANG Jing, LI Zhi, FENG Zhao-Chi, LI Can. Phase Transformation and Photocatalytic Properties of Bi₂O₃ Prepared Using a Precipitation Method[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1247-1256. doi: 10.3866/PKU.WHXB201602231 shu

Phase Transformation and Photocatalytic Properties of Bi₂O₃ Prepared Using a Precipitation Method

LIU Guo ¹ ,
LU Yuan-Yuan ¹ ,
ZHANG Jing ^1,, ,
LI Zhi ^2,, ,
FENG Zhao-Chi ³ ,
LI Can ³

1.
1 School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China;
2.
2 Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3.
3 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Corresponding author: ZHANG Jing, LI Zhi,
Received Date: 19 November 2015
Available Online: 22 February 2016
Fund Project: 国家自然科学基金(21573101) (21573101)教育部留学回国科研启动基金(教外司留[2013]1792号) (教外司留[2013]1792号)辽宁省自然科学基金(2014020107) (2014020107)辽宁省高等学校优秀人才支持计划项目(LJQ2014041) (LJQ2014041)

A Bi(OH)₃ precursor was prepared using a precipitation method using bismuth nitrate as a starting material and ammonia as the precipitation agent. Bi(OH)₃ was then calcined at different temperatures and different time. X-ray diffraction (XRD), Raman spectroscopy, thermogravimetry (TG), scanning electronic microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-Vis diffuse reflectance spectroscopy (UVVis DRS) were used to investigate the phase transformation from Bi(OH)₃ to Bi₂O₃ and the particle size, morphology, and optical properties of Bi₂O₃ during the phase transformation. It was found that Bi(OH)₃ after calcination undergoes the following process: Bi(OH)₃ → Bi₅O₇NO₃ → β-Bi₂O₃/Bi₅O₇NO₃ → β-Bi₂O₃/Bi₅O₇NO₃/α-Bi₂O₃ → α-Bi₂O₃. It was observed that the above phase transformation from Bi(OH)₃ to Bi₂O₃ and the growth of the particle size are interrelated. It was also found that the phase transition from β-Bi₂O₃ to α-Bi₂O₃ was faster compared with the phase transition from Bi₅O₇NO₃ to β-Bi₂O₃. Also, the degradation of Rhodamine B (RhB) was studied to investigate and compare the photocatalytic performance of Bi₂O₃ with different crystalline phases. The result indicates that Bi₅O₇NO₃ and β-Bi₂O₃ exhibit excellent photocatalytic performance, while α-Bi₂O₃ has a low photocatalytic activity.
- Bi₅O₇NO₃,
- β-Bi₂O₃,
- α-Bi₂O₃,
- Bismuth oxide,
- Precipitation method,
- Phase transformation
1. [1]
  (1) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
2. [2]
  (2) Karunakaran, C.; Dhanalakshmi, R. Sol. Energy Mater. Sol. Cells 2008, 92 (5), 588. doi: 10.1016/j.solmat.2007.12.009
3. [3]
  (3) Zhu, J. F.; Zäch, M. Curr. Opin. Colloid Interface Sci. 2009, 14 (4), 260. doi: 10.1016/j.cocis.2009.05.003
4. [4]
  (4) Kumar, B.; Llorente, M.; Froehlich, J.; Dang, T.; Sathrum, A.; Kubiak, C. P. Annu. Rev. Phys. Chem. 2012, 63, 541. doi: 10.1146/annurev-physchem-032511-143759
5. [5]
  (5) Cheng, H. F.; Huang, B. B.; Lu, J. B.; Wang, Z. Y.; Xu, B.; Qin, X. Y.; Zhang, X. Y.; Dai, Y. Phys. Chem. Chem. Phys. 2010, 12 (48), 15468. doi: 10.1039/c0cp01189d
6. [6]
  (6) Wang, C. H.; Shao, C. L.; Liu, U. C.; Zhang, L. N. Scripta Mater. 2008, 59 (3), 332. doi: 10.1016/j.scriptamat.2008.03.038
7. [7]
  (7) Wang, C.; Shao, C.; Wang, L.; Zhang, L.; Li, X.; Liu, Y. J. Colloid Interface Sci. 2009, 333 (1), 242. doi: 10.1016/j.jcis.2008.12.077
8. [8]
  (8) Brezesinski, K.; Ostermann, R.; Hartmann, P.; Perlich, J.; Brezesinski, T. Chem. Mater. 2010, 22 (10), 3079. doi: 10.1021/cm903780m
9. [9]
  (9) Hou, J. G.; Yang, C.; Wang, Z.; Zhou,W. L.; Jiao, S. Q.; Zhu, H. M. Appl. Catal. B: Environ. 2013, 142-143, 504.
10. [10]
  (10) Xiao, X.; Hua, R. P.; Liu, C.; Xing, C. L.; Qian, C.; Zuo, X. X.; Nan, J. M.; Wang, L. S. Appl. Catal. B: Environ. 2013, 140-141, 433.
11. [11]
  (11) Huang, Q. Q.; Zhang, S. N.; Cai, C. X.; Zhou, B. Mater. Lett. 2011, 65 (6), 988. doi: 10.1016/j.matlet.2010.12.055
12. [12]
  (12) Qiu, Y. F.; Yang, M. L.; Fan, H. B.; Zuo, Y. Z.; Shao, Y. Y.; Xu, Y. J.; Yang, X. X.; Yang, S. H. CrystEngComm 2011, 13 (6), 1843. doi: 10.1039/C0CE00508H
13. [13]
  (13) Schlesinger, M.; Schulze, S.; Hietschold, M.; Mehring, M. Dalton Trans. 2013, 42 (4), 1047. doi: 10.1039/C2DT32119J
14. [14]
  (14) Lu, Y.; Zhao, Y.; Zhao, J. Z.; Song, Y. H.; Huang, Z. F.; Gao, F. F.; Li, N.; Li, Y.W. Ceram. Int. 2014, 40 (9), 15057. doi: 10.1016/j.ceramint.2014.06.113
15. [15]
  (15) Zhu, G. Q.; Lian, J.; Hojamberdiev, M.; Que,W. X. J. Clust. Sci. 2013, 24 (3), 829. doi: 10.1007/s10876-013-0576-1
16. [16]
  (16) Cai, G. Y.; Xu, L. L.; Wei, B.; Che, J. X.; Gao, H.; Sun,W. J. Mater. Lett. 2014, 120, 1. doi: 10.1016/j.matlet.2014.01.027
17. [17]
  (17) Hu, R. P.; Xiao, X.; Tu, S. H.; Zuo, X. X.; Nan, J. M. Appl. Catal. B: Environ. 2015, 163, 510. doi: 10.1016/j.apcatb.2014.08.025
18. [18]
  (18) Sun, Y. Y.; Wang,W. Z.; Zhang, L.; Zhang, Z. J. Chem. Eng. J. 2012, 211-212 (15), 161.
19. [19]
  (19) Li, R.; Zhen, Q.; Guo, S. Q.; Shi, G.; Vannier, R. N.; Drache, M. J. Funct. Mater. 2006, 37 (11), 1828. [李榕, 甄强, 郭曙强, 石刚, Rose-Noelle Vannier, Michel Drache. 功能材料, 2006, 37 (11), 1828.]
20. [20]
  (20) Cheng, L. J.; Kang, Y. J. Alloy. Compd. 2014, 585, 85. doi: 10.1016/j.jallcom.2013.08.010
21. [21]
  (21) Tseng, T. K.; Choi, J.; Jung, D.W.; Davidson, M.; Holloway, P. H. ACS. Appl. Mater. Interfaces 2010, 2, 943. doi: 10.1021/am900812a
22. [22]
  (22) Zhang, J.; Xu, Q.; Li, M. J.; Feng, Z. C.; Li, C. J. Phys. Chem. C 2009, 113 (5), 1698. doi: 10.1021/jp808013k
23. [23]
  (23) Li, M. J.; Feng, Z. C.; Xiong, G.; Ying, P. L.; Xin, Q.; Li, C. J. Phys. Chem. B 2001, 105, 8107. doi: 10.1021/jp010526l
24. [24]
  (24) Wu, S. H.; Liu, J.; Lan, Y. Z. Hydrometallurgy of China 2005, 24 (3), 121. [吴绍华, 刘进, 兰尧中. 湿法冶金, 2005, 24 (3), 121.]
25. [25]
  (25) Abdullah, A. H.; Abdullah, E. A.; Zainal, Z.; Hussein, M. Z.; Ban, T. K. Water Sci. Technol. 2012, 65 (9), 1632. doi: 10.2166/wst.2012.057
26. [26]
  (26) Abdullah, E. A.; Abdullah, A. H.; Zainal, Z.; Hussein, M. Z.; Ban, T. K. E-J. Chem. 2012, 9 (4), 2429. doi: 10.1155/2012/707853
27. [27]
  (27) Yu, S. J.; Zhang, G. K.; Gao, Y. Y.; Huang, B. B. J. Colloid Interface Sci. 2011, 354, 322. doi: 10.1016/j.jcis.2010.10.012
28. [28]
  (28) Lu, Y. G.; Yang, Y. C.; Ye, Z. X.; Liu, S. Y. J. Inorg. Mater. 2012, 27 (6), 643. [卢远刚, 杨迎春, 叶芝祥, 刘盛余. 无机材料学报, 2012, 27 (6), 643.] doi: 10.3724/SP.J.1077.2012.00643
29. [29]
  (29) Kodama, H. J. Solid State Chem. 1994, 112, 27. doi: 10.1006/jssc.1994.1259
30. [30]
  (30) Hao,W. C.; Gao, Y.; Jing, X.; Zou,W.; Chen, Y.; Wang, T. M. J. Mater. Sci. Technol. 2014, 30 (2), 192. doi: 10.1016/j.jmst.2013.09.023
31. [31]
  (31) Kumar, K. P. Scripta Metall. Mater. 1995, 32 (6), 873. doi: 10.1016/0956-716X(95)93217-R
32. [32]
  (32) Hague, D. C.; Mayo, M. J. Nanostruct. Mater. 1993, 3 (1-6), 61. doi: 10.1016/0965-9773(93)90063-H
33. [33]
  (33) Banfield, J. F.; Bischoff, B. L.; Anderson, M. A. Chem. Geol. 1993, 110 (1-3), 211. doi: 10.1016/0009-2541(93)90255-H
34. [34]
  (34) Kumar, K. N. P.; Keizer, K. A.; Burggraaf, J.; Okubo, T.; Nagamoto, H.; Morooka, S. Nature 1992, 358 (6381), 48. doi: 10.1038/358048a0
35. [35]
  (35) Wu, Y. C.; Chaing, Y. C.; Huang, C. Y.; Wang, S. F.; Yang, H. Y. Dyes Pigments 2013, 98, 25. doi: 10.1016/j.dyepig.2013.02.006
36. [36]
  (36) Li, X. Y.; Wang, D. S.; Cheng, G. X.; Luo, Q. Z.; An, J.; Wang, Y. H. Appl. Catal. B: Environ. 2008, 81, 267. doi: 10.1016/j.apcatb.2007.12.022
1. [1]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
2. [2]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
3. [3]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
4. [4]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
5. [5]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
6. [6]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
7. [7]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
8. [8]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
9. [9]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
10. [10]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
11. [11]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
14. [14]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
15. [15]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
16. [16]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
17. [17]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
18. [18]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
19. [19]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
20. [20]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(788)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Phase Transformation and Photocatalytic Properties of Bi2O3 Prepared Using a Precipitation Method

Metrics

通讯作者: 陈斌, bchen63@163.com

Phase Transformation and Photocatalytic Properties of Bi₂O₃ Prepared Using a Precipitation Method