Citation: LI Yan, CHAI Jin-Ling. Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1227-1235. doi: 10.3866/PKU.WHXB201602223 shu

Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface

LI Yan ,
CHAI Jin-Ling ^,

1.
Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, P. R. China

Corresponding author: CHAI Jin-Ling,
Received Date: 7 December 2015
Available Online: 19 February 2016
Fund Project: 国家自然科学基金(21306092,21476133) (21306092,21476133)山东省高校科技计划(J12LA02)资助项目 (J12LA02)

Two imidazole-based surface active ionic liquids (C_nmimBr) were synthesized, and their aggregation behavior at the air/water interface was studied via an oscillating bubble method. The effects of the C_nmimBr concentration, inorganic salts (NaBr and CaBr₂), and temperature on the aggregation behavior were investigated. The results of the adsorption dynamics showed that the adsorption-controlled process dominated, but the relaxation process was not purely mono-exponential. The addition of inorganic salt or increase in temperature improved the surface activity of the C_nmimBr and lowered the dynamic surface tension. The dilational rheological results revealed that the dilational modulus, elastic modules, and viscous modules increased with increasing oscillating frequencies, and the modulus reached a maximum value with increasing C_nmimBr concentration. Increasing the temperature or adding inorganic salts (NaBr or CaBr₂) decreased the dilational modulus. The elastic modulus was dominant for the C_nmimBr layer, and the elastic modulus of C₁₄mimBr was larger than that of C12mimBr.
- Adsorption dynamics,
- Dilational modulus,
- Air/water interface,
- Imidazole-based surface active ionic liquid
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