Citation: LI Yan, CHAI Jin-Ling. Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1227-1235. doi: 10.3866/PKU.WHXB201602223 shu

Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface

LI Yan ,
CHAI Jin-Ling ^,

1.
Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, P. R. China

Corresponding author: CHAI Jin-Ling,
Received Date: 7 December 2015
Available Online: 19 February 2016
Fund Project: 国家自然科学基金(21306092,21476133) (21306092,21476133)山东省高校科技计划(J12LA02)资助项目 (J12LA02)

Two imidazole-based surface active ionic liquids (C_nmimBr) were synthesized, and their aggregation behavior at the air/water interface was studied via an oscillating bubble method. The effects of the C_nmimBr concentration, inorganic salts (NaBr and CaBr₂), and temperature on the aggregation behavior were investigated. The results of the adsorption dynamics showed that the adsorption-controlled process dominated, but the relaxation process was not purely mono-exponential. The addition of inorganic salt or increase in temperature improved the surface activity of the C_nmimBr and lowered the dynamic surface tension. The dilational rheological results revealed that the dilational modulus, elastic modules, and viscous modules increased with increasing oscillating frequencies, and the modulus reached a maximum value with increasing C_nmimBr concentration. Increasing the temperature or adding inorganic salts (NaBr or CaBr₂) decreased the dilational modulus. The elastic modulus was dominant for the C_nmimBr layer, and the elastic modulus of C₁₄mimBr was larger than that of C12mimBr.
- Adsorption dynamics,
- Dilational modulus,
- Air/water interface,
- Imidazole-based surface active ionic liquid
1. [1]
  (1) Zhu, S.; Wu, Y.; Chen, Q.; Yu, Z.; Wang, C.; Jin, S.; Ding, Y.; Wu, G. Green Chem. 2006, 8, 325. doi: 10.1039/B601395C
2. [2]
  (2) Welton, T. Chem. Rev. 1999, 99, 2071. doi: 10.1021/cr980032t
3. [3]
  (3) George, A.; Brandt, A.; Tran, K.; Zahari, S. M. S. N. S.; Klein-Marcushamer, D.; Sun, N.; Sathitsuksanoh, N.; Shi, J.; Stavila, V.; Parthasarathi, R.; Singh, S.; Holmes, B. M.; Welton, T.; Simmons, B. A.; Hallett, J. P. Green Chem. 2015, 17, 1728. doi: 10.1039/C4GC01208A
4. [4]
  (4) Redel, E.; Krämer, J.; Thomann, R.; Janiak, C. J. Organomet. Chem. 2009, 694, 1069. doi: 10.1016/j.jorganchem.2008.09.050
5. [5]
  (5) Vollmer, C.; Redel, E.; Abu-Shandi, K.; Thomann, R.; Manyar, H.; Hardacre, C.; Janiak, C. Chem. -Eur. J. 2010, 16, 3849. doi: 10.1002/chem.200903214
6. [6]
  (6) Ochędzan-Siodłak, W.; Dziubek, K.; Czaja, K. Polym. Bull. 2013, 70, 1. doi: 10.1007/s00289-012-0809-8
7. [7]
  (7) Li, R. X. Green Solvent——Synthesis and Utilization of Ionic Liquids; Chemical Industry Press: Beijing, 2004. [李汝雄. 绿色溶剂——离子液体的合成与应用. 北京: 化学工业出版社, 2004.]
8. [8]
  (8) Prechtl, M. H. G.; Scholten, J. D.; Dupont, J. J. Mol. Catal. AChem. 2009, 313, 74. doi: 10.1016/j.molcata.2009.08.004
9. [9]
  (9) Wang, H. Y.; Li, H. P.; Cui, G. K.; Li, Z. Y.; Wang, J. J. Acta Phys. -Chim Sin. 2016, 32, 249. [王慧勇, 李虹培, 崔国凯, 李志勇, 王键吉. 物理化学学报, 2016, 32, 249.] doi: 10.3866/PKU.WHXB201512042
10. [10]
  (10) dos Santos, M. R.; Diniz, J. R.; Arouca, A. M.; Gomes, A. F.; Gozzo, F. C.; Tamborim, S. M.; Parize, A. L.; Suarez, P. A. Z.; Neto, B. A. D. ChemSusChem 2012, 5, 716. doi: 10.1002/cssc.201100453
11. [11]
  (11) Chatel, G.; Goux-Henry, C.; Mirabaud, A.; Rossi, T.; Kardos, N.; Andrioletti, B.; Draye, M. J. Catal. 2012, 291, 127. doi: 10.1016/j.jcat.2012.04.016
12. [12]
  (12) Shi, L.; Li, N.; Zheng, L. J. Phys. Chem. C 2011, 115, 18295. doi: 10.1021/jp206325d
13. [13]
  (13) Zhang, X. H.; Xu, H. Y.; Ge, L. L.; Guo, R. Acta Phys. -Chim. Sin. 2016, 32, 356. [张晓红, 许红岩, 葛玲玲, 郭荣. 物理化学学报, 2016, 32, 356.] doi: 10.3866/PKU.WHXB201512012
14. [14]
  (14) Li, X.W.; Gao, Y. A.; Liu, J.; Zheng, L. Q.; Chen, B.; Wu, L. Z.; Tung, C. H. J. Colloid Interface Sci. 2010, 343, 94. doi: 10.1016/j.jcis.2009.11.010
15. [15]
  (15) Liu, J.; Zhao, M.; Zhang, Q.; Sun, D.; Wei, X.; Zheng, L. Colloid Polym. Sci. 2011, 289, 1711. doi: 10.1007/s00396-011-2492-y
16. [16]
  (16) Shi, L.; Li, N.; Yan, H.; Gao, Y.; Zheng, L. Langmuir 2011, 27, 1618. doi: 10.1021/la104719v
17. [17]
  (17) Ao, M.; Huang, P.; Xu, G.; Yang, X.; Wang, Y. Colloid Polym. Sci. 2008, 287, 395. doi: 10.1007/s00396-008-1976-x
18. [18]
  (18) Ao, M.; Xu, G.; Zhu, Y.; Bai, Y. J. Colloid Interface Sci. 2008, 326, 490. doi: 10.1016/j.jcis.2008.06.048
19. [19]
  (19) Liu, Y.; Yu, L.; Zhang, S.; Yuan, J.; Shi, L.; Zheng, L. Colloid Surf. A 2010, 359, 66. doi: 10.1016/j.colsurfa.2010.01.065
20. [20]
  (20) Qin, C.; Chai, J.; Chen, J.; Xia, Y.; Yu, X.; Liu, J. Colloid Polym. Sci. 2008, 286, 579. doi: 10.1007/s00396-007-1818-2
21. [21]
  (21) Gochev, G. Curr. Opin. Colloid Interface Sci. 2015, 20, 115. doi: 10.1016/j.cocis.2015.03.003
22. [22]
  (22) Ravera, F.; Loglio, G.; Kovalchuk, V. I. Curr. Opin. Colloid Interface Sci. 2010, 15, 217. doi: 10.1016/j.cocis.2010.04.001
23. [23]
  (23) Ravera, F.; Ferrari, M.; Santini, E.; Liggieri, L. Adv. Colloid Interface Sci. 2005, 117, 75. doi: 10.1016/j.cis.2005.06.002
24. [24]
  (24) Dukhin, S. S.; Kretzhmar, G.; Miller, B. Dynamics of Adsorption at Liquid Interfaces——Theory, Experiment, Application; Elsevier: Amsterdam, 1995.
25. [25]
  (25) Zhai, X. R.; Liu, T.; Xu, G. Y.; Tan, G. R.; Lü, X.; Zhang, J. Acta Phys. -Chim. Sin. 2013, 29, 1253. [翟雪如, 刘腾, 徐桂英, 檀国荣, 吕鑫, 张健. 物理化学学报, 2013, 29, 1253.] doi: 10.3866/PKU.WHXB201303251
26. [26]
  (26) Yuan, Z.W.; Yuan, J.; Lü, X.; Zhang, J.; Xu, G. Y. Acta Phys. -Chim. Sin. 2013, 29, 449. [苑再武, 苑敬, 吕鑫, 张健, 徐桂英. 物理化学学报, 2013, 29, 449.] doi: 10.3866/PKU.WHXB201212283
27. [27]
  (27) Cao, C.; Lei, J.; Zhang, L.; Du, F. P. Langmuir 2014, 30, 13744. doi: 10.1021/la502890w
28. [28]
  (28) Cao, C.; Lei, J.; Huang, T.; Du, F. P. Soft Matter 2014, 10, 8896. doi: 10.1039/C4SM01666A
29. [29]
  (29) Huang, T.; Cao, C.; Liu, Z. L.; Li, Y.; Du, F. P. Soft Matter 2014, 10, 6810. doi: 10.1039/C4SM00950A
30. [30]
  (30) Inoue, T.; Ebina, H.; Dong, B.; Zheng, L. J. Colloid Interface Sci. 2007, 314, 236. doi: 10.1016/j.jcis.2007.05.052
31. [31]
  (31) Deng, Q.; Li, H.; Li, C.; Lv, W.; Li, Y. RSC Adv. 2015, 5, 61868. doi: 10.1039/C5RA09120A
32. [32]
  (32) Dong, B.; Zhao, X.; Zheng, L.; Zhang, J.; Li, N.; Inoue, T. Colloid Surf. A 2008, 317, 666. doi: 10.1016/j.colsurfa.2007.12.001
33. [33]
  (33) Rosen, M. J. Surfactants and Interfacial Phenomena; Wiley: New York, 2004.
34. [34]
  (34) Jaycock, M. J.; Parfitt, G. D. Chemistry of Interfaces; John Wiley and Sons: New York, 1981.
35. [35]
  (35) Polavarapu, P.; Krafft, M. P. J. Fluorine Chem. 2015, 171, 12. doi: 10.1016/j.jfluchem.2014.10.020
36. [36]
  (36) Krafft, M. P.; Fainerman, V. B.; Miller, R. Colloid Polym. Sci. 2015, 293, 3091. doi: 10.1007/s00396-015-3622-8
37. [37]
  (37) Jeribi, M.; Almir-Assad, B.; Langevin, D.; Hénaut, I.; Argillier, J. F. J. Colloid Interface Sci. 2002, 256, 268. doi: 10.1006/jcis.2002.8660
38. [38]
  (38) Li, J. B.; Zhang, Y.; Yan, L. L. Angew. Chem. Int. Edit. 2001, 40, 891. doi: 10.1002/1521-3773(20010302)40:5<891::AIDANIE891>3.0.CO;2-K
39. [39]
  (39) Serrien, G.; Geeraerts, G.; Ghosh, L.; Joos, P. Colloid Surface 1992, 68, 219. doi: 10.1016/0166-6622(92)80208-J
40. [40]
  (40) Miller, R.; Aksenenko, E. V.; Liggieri, L.; Ravera, F.; Ferrari, M.; Fainerman, V. B. Langmuir 1999, 15, 1328. doi: 10.1021/la980956b
41. [41]
  (41) Klitzing, R. V.; Müller, H. J. Curr. Opin. Colloid Interface Sci. 2002, 7, 42. doi: 10.1016/S1359-0294(02)00005-5
42. [42]
  (42) Lv, Q.; Li, Z.; Li, B.; Li, S.; Sun, Q. Ind. Eng. Chem. Res. 2015, 54, 9468. doi: 10.1021/acs.iecr.5b02197
43. [43]
  (43) Li, Y. M.; Xu, G. Y.; Xin, X.; Cao, X. R.; Wu, D. Carbohydr. Polym. 2008, 72, 211. doi: 10.1016/j.carbpol.2007.08.008
44. [44]
  (44) Xin, X.; Xu, G.; Wu, D.; Gong, H.; Zhang, H.; Wang, Y. Colloid. Surf. A 2008, 322, 54. doi: 10.1016/j.colsurfa.2008.02.025
45. [45]
  (45) Zhu, Y.; Xu, G.; Xin, X.; Zhang, H.; Shi, X. J. Chem. Eng. Data 2009, 54, 989. doi: 10.1021/je800788f
46. [46]
  (46) Ivanov, I. B.; Danov, K. D.; Ananthapadmanabhan, K. P.; Lips, A. Adv. Colloid Interface Sci. 2005, 114－115, 61. doi: 10.1016/j.cis.2004.11.001
47. [47]
  (47) Stubenrauch, C.; Fainerman, V. B.; Aksenenko, E. V.; Miller, R. J. Phys. Chem. B 2005, 109, 1505. doi: 10.1021/jp046525l
48. [48]
  (48) Wu, D.; Xu, G.; Feng, Y.; Li, Y. Int. J. Biol. Macromol. 2007, 40, 345. doi: 10.1016/j.ijbiomac.2006.09.004
49. [49]
  (49) He, F.; Xu, G.; Pang, J.; Ao, M.; Han, T.; Gong, H. Langmuir 2011, 27, 538. doi: 10.1021/la103478c
50. [50]
  (50) Stubenrauch, C.; Miller, R. J. Phys. Chem. B 2004, 108, 6412. doi: 10.1021/jp049694e
1. [1]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
4. [4]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
5. [5]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
6. [6]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
7. [7]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
8. [8]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
9. [9]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
10. [10]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
11. [11]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
12. [12]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
13. [13]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
14. [14]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
15. [15]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
16. [16]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
17. [17]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
18. [18]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
19. [19]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
20. [20]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(742)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142