Citation: BIAN Shao-Wei, XU Ling-Li, GUO Mei-Xia, SHAO Fu, LIU Si. Fabrication of Graphene/Cotton and MnO₂/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1199-1206. doi: 10.3866/PKU.WHXB201602222 shu

Fabrication of Graphene/Cotton and MnO₂/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors

1.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, P. R. China

Corresponding author: BIAN Shao-Wei,
Received Date: 16 November 2015
Available Online: 15 February 2016
Fund Project: 国家自然科学基金(51402048) (51402048)

Graphene/cotton composite fabrics for use as flexible electrodes were prepared using a thermal reduction method. The reducing condition significantly influenced the conductivity of the graphene/cotton fabrics. The conductive graphene/cotton fabrics with hierarchical structures used as flexible electrode substrates facilitate the loading of pseudocapacitor materials, enhancing electron transport and electrolyte ion diffusion. The electrode structure was characterized in detail using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and the standard four-point probe method. After further electrochemical deposition of MnO₂ sheets on the composite fabrics, the resulting MnO₂/graphene/cotton composite fabrics for use as electrode materials had excellent electrochemical performance and great flexibility. The specific capacitance reached 536 F·g^-1 at a scan rate of 5 mV·s^-1. The electrochemical test results indicate that it can be further used for flexible energy storage materials.
- Graphene,
- Cotton,
- Electrochemical capacitor,
- Flexible electrode,
- Textile
1. [1]
  (1) Xue, J. L.; Zhao, Y.; Cheng, H. H.; Hu, C. G.; Hu, Y.; Meng, Y. N.; Shao, H. B.; Zhang, Z. P.; Qu, L. T. Phys. Chem. Chem. Phys. 2013, 15, 8042. doi: 10.1039/c3cp51571k
2. [2]
  (2) Bian, S.W.; Zhu, L. RSC Adv. 2013, 3, 4212. doi: 10.1039/c3ra40333e
3. [3]
  (3) Xu, L. L.; Bian, S.W.; Song, K. L. J. Mater. Sci. 2014, 49, 6217. doi: 10.1007/s10853-014-8346-5
4. [4]
  (4) Jiang, H.; Lee, P. S.; Li, C. Z. Energy Environ. Sci. 2013, 6, 41. doi: 10.1039/c2ee23284g
5. [5]
  (5) Chen, J.; Sheng, K. X.; Luo, P. H.; Li, C.; Shi, G. Q. Adv. Mater. 2012, 24, 4569. doi: 10.1002/adma.201201978
6. [6]
  (6) Meng, C. Z.; Liu, C. H.; Chen, L. Z.; Hu, C. H.; Fan, S. S. Nano Lett. 2010, 10, 4025. doi: 10.1021/nl1019672
7. [7]
  (7) Pech, D.; Brunet, M.; Durou, H.; Huang, P. H.; Mochalin, V.; Gogotsi, Y.; Taberna, P. L.; Simon, P. Nature Nanotech. 2010, 5, 651. doi: 10.1038/nnano.2010.162
8. [8]
  (8) Lin, J.; Zhang, C. G.; Yan, Z.; Zhu, Y.; Peng, Z.W.; Hauge, R. H.; Natelson, D.; Tour, J. M. Nano Lett. 2013, 13, 72. doi: 10.1021/nl3034976
9. [9]
  (9) Bian, S.W.; Zhao, Y. P.; Xian, C. Y. Mater. Lett. 2013, 111, 75. doi: 10.1016/j.matlet.2013.08.028
10. [10]
  (10) Xu, L. L.; Guo, M. X.; Liu, S.; Bian, S.W. RSC Adv. 2015, 5, 25244. doi: 10.1039/c4ra16063k
11. [11]
  (11) Simon, P.; Gogotsi, Y.; Dunn, B. Science 2014, 343, 1210. doi: 10.1126/science.1249625
12. [12]
  (12) Simon, P.; Gogotsi, Y. Nature Mater. 2008, 7, 845. doi: 10.1038/nmat2297
13. [13]
  (13) Wang, Y. F.; Zuo, S. L. Acta Phys. -Chim. Sin. 2016, 32, 481. [王永芳, 左宋林. 物理化学学报, 2016, 32, 481.] doi: 10.3866/PKU.WHXB201511041
14. [14]
  (14) Su, P.; Guo, H. L.; Peng, S.; Ning, S. K. Acta Phys. -Chim. Sin. 2012, 28, 2745. [苏鹏, 郭慧林, 彭三, 宁生科. 物理化学学报, 2012, 28, 2745.] doi: 10.3866/PKU.WHXB201208221
15. [15]
  (15) Liang, G.; Zhu, L.; Xu, J.; Fang, D.; Bai, Z.; Xu, W. Electrochim. Acta 2013, 103, 9. doi: 10.1016/j.electacta.2013.04.065
16. [16]
  (16) Xin, C.; Ming, P.; Xiao, Y.; Yongping, F.; Dechun, Z. J. Mater. Chem. C 2013, 2, 1184. doi: 10.1039/c3tc31706d
17. [17]
  (17) Zhao, Y.; Hu, C. G.; Hu, Y.; Cheng, H. H.; Shi, G. Q.; Qu, L. T. Angew. Chem. Int. Edit. 2012, 51, 11371. doi: 10.1002/anie.201206554
18. [18]
  (18) Jost, K.; Perez, C. R.; McDonough, J. K.; Presser, V.; Heon, M.; Dion, G.; Gogotsi, Y. Energy Environ. Sci. 2011, 4, 5060. doi: 10.1039/c1ee02421c
19. [19]
  (19) Hu, L. B.; Chen, W.; Xie, X.; Liu, N. A.; Yang, Y.; Wu, H.; Yao, Y.; Pasta, M.; Alshareef, H. N.; Cui, Y. ACS Nano 2011, 5, 8904. doi: 10.1021/nn203085j
20. [20]
  (20) Lu, Z.; Mao, C.; Zhang, H. J. Mater. Chem. C 2015, 3, 4265. doi: 10.1039/c5tc00917k
21. [21]
  (21) Shateri-Khalilabad, M.; Yazdanshenas, M. Cellulose 2013, 20, 963. doi: 10.1007/s10570-013-9873-y
22. [22]
  (22) Sun, X.; Wang, H.; Lei, Z.; Liu, Z.; Wei, L. RSC Adv. 2014, 4, 30233. doi: 10.1039/c4ra03983a
23. [23]
  (23) Hassan, S.; Suzuki, M.; Mori, S.; El-Moneim, A. A. RSC Adv. 2014, 4, 20479. doi: 10.1039/c4ra01132e
24. [24]
  (24) Chen, W.; Rakhi, R. B.; Hu, L. B.; Xie, X.; Cui, Y.; Alshareef, H. N. Nano Lett. 2011, 11, 5165. doi: 10.1021/nl2023433
25. [25]
  (25) Li, C. C.; Yu, H.; Yan, Q.; Hng, H. H. J. Power Sources 2015, 274, 310. doi: 10.1016/j.jpowsour.2014.10.056
26. [26]
  (26) Hongtao, L.; Lei, Z.; Yunlong, G.; Cheng, C.; Lianjiang, Y.; Lang, J.; Gui, Y.; Wenping, H.; Yungi, L.; Daoben, Z. J. Mater. Chem. C 2013, 1, 3104. doi: 10.1039/c3tc00067b
27. [27]
  (27) Pei, S. F.; Zhao, J. P.; Du, J. H.; Ren, W. C.; Cheng, H. M. Carbon 2010, 48, 4466. doi: 10.1016/j.carbon.2010.08.006
28. [28]
  (28) Szabo, T.; Berkesi, O.; Forgo, P.; Josepovits, K.; Sanakis, Y.; Petridis, D.; Dekany, I. Chem. Mater. 2006, 18, 2740. doi: 10.1021/cm060258
29. [29]
  (29) Shin, H. J.; Kim, K. K.; Benayad, A.; Yoon, S. M.; Park, H. K.; Jung, I. S.; Jin, M. H.; Jeong, H. K.; Kim, J. M.; Choi, J. Y.; Lee, Y. H. Adv. Funct. Mater. 2009, 19, 1987. doi: 10.1002/adfm.200900167
30. [30]
  (30) Zhu, J.; Tang, S.; Xie, H.; Dai, Y.; Meng, X. ACS Appl. Mater. Interfaces 2014, 6, 17637. doi: 10.1021/am505622c
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
3. [3]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
4. [4]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
5. [5]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
8. [8]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
9. [9]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
10. [10]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
13. [13]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
14. [14]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
15. [15]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
16. [16]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
17. [17]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
18. [18]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
19. [19]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
20. [20]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(801)
HTML views(68)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Graphene/Cotton and MnO2/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors

Metrics

通讯作者: 陈斌, bchen63@163.com

Fabrication of Graphene/Cotton and MnO₂/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors