Citation: BIAN Shao-Wei, XU Ling-Li, GUO Mei-Xia, SHAO Fu, LIU Si. Fabrication of Graphene/Cotton and MnO₂/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1199-1206. doi: 10.3866/PKU.WHXB201602222 shu

Fabrication of Graphene/Cotton and MnO₂/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors

1.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, P. R. China

Corresponding author: BIAN Shao-Wei,
Received Date: 16 November 2015
Available Online: 15 February 2016
Fund Project: 国家自然科学基金(51402048) (51402048)

Graphene/cotton composite fabrics for use as flexible electrodes were prepared using a thermal reduction method. The reducing condition significantly influenced the conductivity of the graphene/cotton fabrics. The conductive graphene/cotton fabrics with hierarchical structures used as flexible electrode substrates facilitate the loading of pseudocapacitor materials, enhancing electron transport and electrolyte ion diffusion. The electrode structure was characterized in detail using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and the standard four-point probe method. After further electrochemical deposition of MnO₂ sheets on the composite fabrics, the resulting MnO₂/graphene/cotton composite fabrics for use as electrode materials had excellent electrochemical performance and great flexibility. The specific capacitance reached 536 F·g^-1 at a scan rate of 5 mV·s^-1. The electrochemical test results indicate that it can be further used for flexible energy storage materials.
- Graphene,
- Cotton,
- Electrochemical capacitor,
- Flexible electrode,
- Textile
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沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Graphene/Cotton and MnO2/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors

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通讯作者: 陈斌, bchen63@163.com

Fabrication of Graphene/Cotton and MnO₂/Graphene/Cotton Composite Fabrics as Flexible Electrodes for Electrochemical Capacitors