Citation:
YUAN Jun-Sheng, LIU Zi-Yu, LI Fei, LI Shen-Yu. Study of the Hydrated Structure of KCl and NaCl Mixed Solutions Using X-ray Diffraction and Raman Spectroscopy[J]. Acta Physico-Chimica Sinica,
;2016, 32(5): 1143-1150.
doi:
10.3866/PKU.WHXB201602184
-
Research on the hydrated structure of KCl and NaCl mixed solutions with a concentration range between 0 and 26% was conducted using X-ray diffraction and Raman spectroscopy at 25 ℃. Their reduced structure functions, F(Q), and reduced pair distribution functions, G(r), obtained from X-ray diffraction indicate that compared with Na+, the hydration numbers and shell radii of the hydrated K+ ions are larger. This explains why the solubility of NaCl is higher than that of KCl at 25 ℃. According to the Raman spectroscopy, the tetrahedral hydrogen bonds of water molecules will be destroyed with the increase in KCl concentration and the decrease in NaCl concentration. The extent of the bond destruction has systematic variations; for example, increasing at first and then decreasing. These results show that the destruction of the hydrogen bond structure resulting from Na+ is more serious than from K+. Also, with the appropriate K+ content in the NaCl solution, Na+ will behave as a structure breaker instead of a structure maker, which enhances the destructiveness of the solution structure.
-
-
-
[1]
(1) Smirnova, P. R.; Grechinb, O. V.; Trostina, V. N. Russ. J. Phys. Chem. A 2014, 88, 250. doi: 10.1134/S0036024414020253
-
[2]
(2) Brady, G.W.; Krause, J. T. J. Phys. Chem. 1957, 27, 304. doi: 10.1063/1.1743691
-
[3]
(3) Terekhova, D. S.; Ryss, A. I.; Radchenko, I. V. J. Struct. Chem. 1969, 10, 807. doi: 10.1007/BF00743973
-
[4]
(4) Fishkis, M. Y.; Soboleva, T. E. J. Struct. Chem. 1974, 15, 175. doi: 10.1007/BF00746552
-
[5]
(5) Neilson, G.W.; Skipper, N. Chem. Phys. Lett. 1985, 114, 35. doi: 10.1016/0009-2614(85)85050-8
-
[6]
(6) Tongraar, A.; Liedl, K. R.; Rode, B. M. J. Phys. Chem. A 1998, 102, 10340. doi: 10.1021/jp982270y
-
[7]
(7) Azam, S. S.; Hofer, T. S.; Randolf, B. R.; Rode, B. M. J. Phys. Chem. A 2009, 113, 1827. doi: 10.1021/jp8093462
-
[8]
(8) Ramaniah, L. M.; Bernasconi, M.; Parrinello, M. J. Chem. Phys. 1999, 111, 1587. doi: 10.1063/1.479418
-
[9]
(9) Liu, Y.; Lu, H. G.; Wu, Y. B.; Hu, T. P.; Li, Q. L. J. Chem. Phys. 2010, 132, 124503. doi: 10.1063/1.3369624
-
[10]
(10) Harsányi, I.; Bopp, P. A.; Vrhovšek, A.; Pusztai, L. J. Mol. Liq. 2011, 158, 61. doi: 10.1016/j.molliq.2010.10.010
-
[11]
(11) Gereben, O.; Pusztai, L. J. Non-Cryst. Solids 2015, 407, 213. doi: 10.1016/j.jnoncrysol.2014.08.047
-
[12]
(12) Mile, V.; Gereben, O.; Kohara, S.; Pusztai, L. J. Phys. Chem. B 2012, 116, 9758. doi: 10.1021/jp301595m
-
[13]
(13) Mile, V.; Pusztai, L.; Dominguez, H.; Pizi, O. J. Phys. Chem. B 2009, 113, 10760. doi: 10.1021/jp900092g
-
[14]
(14) Palinkas, G.; Radnai, T.; Hajdu, F. Zeitschrift Für Naturforschung A 1980, 35, 107. doi: 10.1515/zna-1980-0121
-
[15]
(15) Ohtaki, H.; Fukushima, N. J. Solution Chem. 1992, 21, 23. doi: 10.1007/BF00648978
-
[16]
(16) Nikologorskaya, E. L.; Kuznetsov, V. V.; Grechin, O. V.; Trostin, V. N. Russ. J. Inorg. Chem. 2000, 45, 1759. doi: 10.1134/S1070363207120043
-
[17]
(17) Li, F.; Han, Z.; Li, D. C.; Li, S. Y.; Yuan, J. S. Chin. J. Anal. Lab. 2014, 33, 1072. [李非, 韩镇, 李栋婵, 李申予, 袁俊生. 分析试验室, 2014, 33, 1072.] doi: 10.13595/j.cnki.issn1000-0720.2014.0253
-
[18]
(18) Li, F.; Yuan, J. S.; Li, D. C.; Li, S. Y.; Han, Z. J. Mol. Struct. 2015, 1081, 38. doi: 10.1016/j.molstruc.2014.09.062
-
[19]
(19) Juha′s, P.; Davis, T.; Farrow, C. L.; Billinge, S. J. L. J. Appl. Cryst. 2013, 43, 560. doi: 10.1107/S0021889813005190
-
[20]
(20) Li, Q. Z.; Wu, G. S.; Yu, Z.W. J. Am. Chem. Soc. 2006, 128, 1438. doi: 10.1021/ja0569149
-
[21]
(21) Feng, W. S.; Fang, Y.; Xu, J. X.; Fang, C. H.; Jia, Q. J.; Wang, H. H.; Jiang, X. M. Acta Phys. -Chim. Sin. 2008, 24 (3), 497. [冯望生, 房艳, 徐继香, 房春晖, 贾全杰, 王焕华, 姜晓明. 物理化学学报, 2008, 24 (3), 497.] doi: 10.3866/PKU.WHXB20080326
-
[22]
(22) Fu, L. X-ray Study of the Structure of LiquidWater. Ph. D. Dissertation, Stanford University, American, 2009.
-
[23]
(23) Zhou, Y. Q. Structure and Properties of Aqueous Sodium Borate Solutions. Ph. D. Dissertation, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, 2010. [周永全. 硼酸钠水溶液结构及性质[D]. 西宁: 中国科学院青海盐湖研究所, 2010.]
-
[24]
(24) Megyes, T.; Bálint, S.; Grósz, T.; Radnai, T.; Bakó, I. J. Chem. Phys. 2008, 128, 044501 doi: 10.1063/1.2821956
-
[25]
(25) Ohtomo, N.; Arakawa, K. Bull. Chem. Soc. Jpn. 1980, 53, 1789. doi: 10.1246/bcsj.53.1789
-
[26]
(26) Mancinelli, R.; Botti, A.; Bruni, F.; Ricci, M. A. J. Phys. Chem. B 2007, 111, 13570. doi: 10.1021/jp075913v
-
[27]
(27) Li, F. Study on the Structure of Potassium Salt Aqueous Solutions. Ph. D. Dissertation, Hebei University of Technology, Tianjin, 2015. [李非. 钾盐水溶液结构研究[D]. 天津: 河北工业大学, 2015.]
-
[28]
(28) Wang, C. C.; Lin, K.; Hu, N. Y.; Zhou, X. G.; Liu, S. L. Acta Phys. -Chim. Sin. 2012, 28, 1823. [王陈琛, 林珂, 胡乃银, 周晓国, 刘世林. 物理化学学报, 2012, 28, 1823.] doi: 10.3866/PKU.WHXB201205154
-
[29]
(29) Impey, R.W.; Madden, P. A.; McDonald, I. R. J. Phys. Chem. 1983, 87, 5071. doi: 10.1021/j150643a008
-
[1]
-
-
-
[1]
Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, 2025, 40(3): 62-67. doi: 10.12461/PKU.DXHX202404045
-
[2]
Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
-
[3]
Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
-
[4]
Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
-
[5]
Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
-
[6]
Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
-
[7]
Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
-
[8]
Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
-
[9]
Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
-
[10]
Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
-
[11]
Hongwei Ma , Fang Zhang , Hui Ai , Niu Zhang , Shaochun Peng , Hui Li . Integrated Crystallographic Teaching with X-ray,TEM and STM. University Chemistry, 2024, 39(3): 5-17. doi: 10.3866/PKU.DXHX202308107
-
[12]
Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
-
[13]
Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
-
[14]
Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
-
[15]
Cheng Rong , Jiang Jiang , Xinyu Zheng . Constructivism and Deconstructivism in General Chemistry Teaching: Taking the Teaching of Colloidal Solutions as an Example. University Chemistry, 2024, 39(2): 292-297. doi: 10.3866/PKU.DXHX202308035
-
[16]
Yinuo Wu , Jiantao Ye , Xie Zhou , Yu Qian , Lei Guo . Teaching Design of Basic Chemistry Based on PBL Methodology for Medical Undergraduates: A Case Study on “Osmotic Pressure of Solution”. University Chemistry, 2024, 39(3): 149-157. doi: 10.3866/PKU.DXHX202309077
-
[17]
Xinxue Li . The Application of Reverse Thinking in Teaching of Boiling Point Elevation and Freezing Point Depression of Dilute Solutions in General Chemistry. University Chemistry, 2024, 39(11): 359-364. doi: 10.3866/PKU.DXHX202401075
-
[18]
Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co9S8/Ni3S2 heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
-
[19]
Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb2+ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
-
[20]
Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(1036)
- HTML views(45)