Citation: LI Bao-Qing, YUAN Wen-Hui, LI Li. Adsorption of Pb²⁺ and Cd²⁺ on Graphene Nanosheets Prepared Using Thermal Exfoliation[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 997-1004. doi: 10.3866/PKU.WHXB201602182 shu

Adsorption of Pb²⁺ and Cd²⁺ on Graphene Nanosheets Prepared Using Thermal Exfoliation

LI Bao-Qing ¹ ,
YUAN Wen-Hui ^2,, ,
LI Li ³

1.
1. The Key Laboratory of Heavy Metal Pollution Prevention and Soil Remediation, Guangdong Vocational College of Environmental Protection Engineering, Foshan 528216, Guangdong Province, P. R. China;
2.
2. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China;
3.
3. College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Corresponding author: YUAN Wen-Hui,
Received Date: 22 December 2015
Available Online: 17 February 2016
Fund Project: 广东环境保护工程职业学院2013 年院长基金及国家自然科学基金(20976057)资助项目 (20976057)

Graphene nanosheets (GNSs) were prepared using oxidation of graphite powder followed by rapid thermal exfoliation under a nitrogen atmosphere. The as-prepared samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), Raman spectroscopy, and Fourier transform infrared (FT-IR) spectroscopy. The specific surface area was determined using the nitrogen adsorption and desorption method. These analytic techniques revealed that the samples possessed a curled morphology consisting of a thin paper-like structure, which was made of a few graphite layers (approximately four layers) and a large specific surface area (628.5 m²·g^-1). The effects of pH, adsorption time, temperature and initial concentration of Pb²⁺ and Cd²⁺ on adsorption onto the GNSs were investigated. The maximum adsorption capacities of GNSs for Pb²⁺ and Cd²⁺ ions were approximately 460.20 and 72.39 mg·g^-1, respectively. These results indicate that the resulting high-quality GNSs can be used as an attractive adsorptive material for removing Pb²⁺ and Cd²⁺ from water.
- Graphene,
- Thermal exfoliation,
- Characterization,
- Adsorption,
- Heavy metal ion
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Adsorption of Pb2+ and Cd2+ on Graphene Nanosheets Prepared Using Thermal Exfoliation

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Adsorption of Pb²⁺ and Cd²⁺ on Graphene Nanosheets Prepared Using Thermal Exfoliation