Citation: HUO Jian-Xia, SONG Su-Wei, JIN Cheng-Wei, REN Ning, GENG Li-Na, ZHANG Jian-Jun. Synthesis, Characterization, Thermal Decomposition Mechanism and Properties of the [Eu(4-MOBA)₃(terpy)(H₂O)]₂ Complex[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 901-906. doi: 10.3866/PKU.WHXB201602173 shu

Synthesis, Characterization, Thermal Decomposition Mechanism and Properties of the [Eu(4-MOBA)₃(terpy)(H₂O)]₂ Complex

HUO Jian-Xia ^1,2 ,
SONG Su-Wei ⁴ ,
JIN Cheng-Wei ^1,2 ,
REN Ning ^3,, ,
GENG Li-Na ² ,
ZHANG Jian-Jun ^1,2,,

1.
1. Testing and Analysis Center, Hebei Normal University, Shijiazhuang 050024, P. R. China;
2.
2. College of Chemistry&Material Science, Hebei Normal University, Shijiazhuang 050024, P. R. China;
3.
3. College of Chemical Engineering&Material, Handan University, Handan 056005, Hebei Province, P. R. China;
4.
4. Petro China Jingtang LNG Co., Ltd., Tangshan 063210, Hebei Province, P. R. China

Corresponding author: REN Ning, ZHANG Jian-Jun,
Received Date: 29 December 2015
Available Online: 15 February 2016
Fund Project: 国家自然科学基金(31201305, 21473049) (31201305, 21473049)河北省自然科学基金(B2016205207)资助项目 (B2016205207)

A new complex [Eu(4-MOBA)₃(terpy)(H₂O)]₂ (4-MOBA: 4-methoxybenzoate, terpy: 2,2' :6',2"-terpyridine) was synthesized. The complex was characterized using Fourier transform infrared (FTIR) spectroscopy, elemental analysis, and powder X-ray diffraction (XRD). The structure of the complex was determined using single-crystal XRD. In the complex, each Eu³⁺ ion is nine coordinated to one terpy molecule, one water molecule and three carboxylate groups. The carboxylate groups are bonded to the Eu³⁺ ion in three modes: bidentate, bridging bidentate, and monodentate. Based on thermogravimetry-differential scanning calorimetry/Fourier transform infrared (TG-DSC/FTIR) measurements, we determined the thermal decomposition mechanism. The emission spectra of the complex exhibited characteristic luminescence, suggesting that terpy and 4-methoxybenzoic acid can act as sensitizing chromophores in this system. Also, bacteriostatic activities for the complex to Candida albicans and Escherichia coli are discussed.
- Lanthanide complex,
- Crystal structure,
- Thermal decomposition mechanism,
- Luminescence,
- 2,2':6',2"-Terpyridine,
- Antimicrobial activity
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Synthesis, Characterization, Thermal Decomposition Mechanism and Properties of the [Eu(4-MOBA)3(terpy)(H2O)]2 Complex

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Synthesis, Characterization, Thermal Decomposition Mechanism and Properties of the [Eu(4-MOBA)₃(terpy)(H₂O)]₂ Complex