Citation: CAI Li-Li, WEN Yue-Hua, CHENG Jie, CAO Gao-Ping, YANG Yu-Sheng. Synthesis and Electrochemical Performance of a Benzoquinone-Based Polymer Anode for Aqueous Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 969-974. doi: 10.3866/PKU.WHXB201601061 shu

Synthesis and Electrochemical Performance of a Benzoquinone-Based Polymer Anode for Aqueous Lithium-Ion Batteries

1.
1. Faculty of Science, Beijing University of Chemical Technology, Beijing 110159, P. R. China;
2.
2. Research Institute of Chemical Defence, Beijing 100191, P. R. China

Corresponding author: WEN Yue-Hua,
Received Date: 25 September 2015
Available Online: 4 January 2016
Fund Project:

Using the tetrachloro-p-benzoquinone (TCQ) monomer, poly(benzoquinonyl sulfide) (PBQS) was synthesized by a simple polycondensation reaction. The influence of the molar ratio of S to Na₂S on the electrochemical performance of a PBQS anode was assessed by changing the amount of S added. The results showed that the electrochemical performance of PBQS strongly depended on the molar ratio of S to Na₂S. When the molar ratio of S to Na₂S was 0.4, two Cl were replaced by S, and PBQS with a stable structure was obtained. The discharge capacity of PBQS exceeded 140 mAh·g^-1. At the same time, PBQS displayed satisfactory rate capability and excellent cyclability. Conversely, when the molar ratio of S to Na₂S was decreased to 0.25, Cl was not substituted completely and the polymerization degree was low. Upon increasing the molar ratio of S to Na₂S to 0.7, an unstable S-S bond may form in the polymer. The above two factors degraded the electrode performance of these materials.
- Aqueous lithium-ion battery,
- Polycondensation,
- Poly(benzoquinonyl sulfide),
- Mole ratio of S to Na₂S,
- Electrochemical performance
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