Citation: HAN Chuan-Hong, GENG Pei-Pei, GUO Yan, CHEN Xiao-Xiao, GUO Xiao-Dong, ZHANG Jun-Hong, LIU Jie, WEI Xi-Lian. Thermoresponsive Properties of a Mixed Aqueous Solution of Cationic Surfactant and Organic Acid[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 863-871. doi: 10.3866/PKU.WHXB201601051 shu

Thermoresponsive Properties of a Mixed Aqueous Solution of Cationic Surfactant and Organic Acid

1.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, Shandong Province, P. R. China

Corresponding author: WEI Xi-Lian,
Received Date: 21 October 2015
Available Online: 4 January 2016
Fund Project: 国家自然科学基金(21473084, 21073081, 21373106, ZR2012BQ013) (21473084, 21073081, 21373106, ZR2012BQ013) 聊城大学科研课题(LDSY2014008) (LDSY2014008)实验技术(314011402)资助项目 (314011402)

Rheological properties of aqueous mixtures of the traditional cationic surfactant cetyltrimethylammonium bromide (CTAB) and organic acid 3-methylsalicylic acid (3MS) were studied as a function of concentration and temperature using steady-state and frequency sweep-rheological measurements. Upon being heated, the solutions exhibited three different types of response. Among them, the most interesting response was that light blue dilute solutions formed over the 3MS concentration range of 80 to 100 mmol·kg^-1. These samples changed from dilute pale blue solutions to transparent viscoelastic ones as their aggregation state transitioned from vesicles to long worm-like micelles with increasing temperature. Moreover, the threshold temperature of the transition increased with 3MS concentration. The results of rheological temperature scanning and conductivity measurements verified this trend. A qualitative explanation for this transformation is that bound 3MS molecules dissociate from the vesicles and join the bulk aqueous phase at high temperature.
- Surfactant,
- Micelle,
- Vesicle,
- Thermoresponsive,
- Rheological property
1. [1]
  (1) Trickett, K.; Eastoe, J. Adv. Colloid Interface 2008, 144, 66. doi: 10.1016/j.cis.2008.08.009
2. [2]
  (2) Chu, Z. L.; Dreiss, C. A.; Feng, Y. J. Chem. Soc. Rev. 2013, 42, 7174. doi: 10.1039/c3cs35490c
3. [3]
  (3) Davies, T. S.; Ketner, A. M.; Raghavan, S. R. J. Am. Chem. Soc. 2006, 128, 6669. doi: 10.1021/ja060021e
4. [4]
  (4) Lee, H. Y.; Diehn, K. K.; Sun, K. S.; Chen, T. H.; Raghavan, S. R. J. Am. Chem. Soc. 2011, 133, 8461. doi: 10.1021/ja202412z
5. [5]
  (5) Zhao, L.;Wang, K.; Xu, L. M.; Liu, Y.; Zhang, S.; Li, Z. B.; Yan, Y.; Huang, J. B. Soft Matter 2012, 8, 9079. doi: 10.1039/C2SM25334H
6. [6]
  (6) Zhang, Y. M.; Feng, Y. J.;Wang, J. Y.; He, S.; Guo, Z. R.; Chu, Z. L.; Dreiss, C. A. Chem. Commun. 2013, 49, 4902. doi: 10.1039/c3cc41059e
7. [7]
  (7) Tsuchiya, K.; Orihara, Y.; Kondo, Y.; Yoshino, N.; Ohkubo, T.; Sakai, H.; Abe, M. J. Am. Chem. Soc. 2004, 126, 12282.
8. [8]
  (8) Liu, C. C.; Hao, J. C. J. Phys. Chem. B. 2011, 115, 980. doi: 10.1021/jp107946n
9. [9]
  (9) Jiang, L. X.;Wang, K.; Ke, F. Y.; Liang, D. H.; Huang, J. B. Soft Matter 2009, 5, 599. doi: 10.1039/B813498G
10. [10]
  (10) Singh, M.; Ford, C.; Agarwal, V.; Fritz, G.; Bose, A.; John, V. T.; McPherson, G. L. Langmuir 2004, 20, 9931. doi: 10.1021/la048967u
11. [11]
  (11) Zhai, L. M.; Herzog, B.; Drechsler, M.; Hoffmann, H. J. Phys. Chem. B 2006, 110, 17697. doi: 10.1021/jp0680591
12. [12]
  (12) Buwalda, R. T.; Stuart, M. C. A.; Engberts, J. B. F. N. Langmuir 2000, 16, 6780. doi: 10.1021/la000164t
13. [13]
  (13) Grabner, D.; Zhai, L.; Talmon, Y.; Schmidt, J.; Freiberger, N.; Glatter, O.; Herzog, B.; Hoffmann, H. J. Phys. Chem. B 2008, 112, 2901. doi: 10.1021/jp0749423
14. [14]
  (14) Horbaschek, K.; Hoffmann, H.; Thunig, C. J. Colloid Interface Sci. 1998, 206, 439. doi: 10.1006/jcis.1998.5690
15. [15]
  (15) Ghosh, R.; Dey, J. Langmuir 2014, 30, 13516. doi: 10.1021/la5022214
16. [16]
  (16) Cates, M. E.; Candau, S. J. J. Phys. Condens. Matter 1990, 2, 6869. doi: 10.1088/0953-8984/2/33/001
17. [17]
  (17) Magid, L. J. J. Phys. Chem. B 1998, 102, 4064. doi: 10.1021/ jp9730961
18. [18]
  (18) Olsson, U.; Soderman, O.; Guering, P. J. Phys. Chem. 1986, 90, 5223. doi: 10.1021/j100412a066
19. [19]
  (19) Rao, U. R. K.; Manohar, C.; Valaulikar, B. S.; Iyer, R. M. J. Phys. Chem. 1987, 91, 3286. doi: 10.1021/j100296a036
20. [20]
  (20) Lin, Z.; Cai, J. J.; Scriven, L. E.; Davis, H. T. J. Phys. Chem. 1994, 98, 5984. doi: 10.1021/j100074a027
21. [21]
  (21) Zheng, Y.; Lin, Z.; Zakin, J. L.; Talmon, Y.; Davis, H. T.; Scriven, L. E. J. Phys. Chem. B 2000, 104, 5263. doi: 10.1021/jp0002998
22. [22]
  (22) Acharya, D. P.; Kunieda, H. J. Phys. Chem. B 2003, 107, 10168. doi: 10.1021/jp0353237
23. [23]
  (23) Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. J. Colloid Interface Sci. 2007, 311, 276. doi: 10.1016/j.jcis.2007.02.050
24. [24]
  (24) Wei, X. L.; Ping, A. L.; Du, P. P.; Liu, J.; Sun, D. Z.; Zhang, Q. F.; Hao, H. G.; Yu, H. J. Soft Matter 2013, 9, 8454. doi: 10.1039/c3sm51017d
25. [25]
  (25) Thurn, H.; Lobl, M.; Hoffmann, H. J. Phys. Chem. 1985, 89, 517. doi: 10.1021/j100249a030
26. [26]
  (26) Lin, Y. Y.; Qiao, Y.; Tang, P. F.; Li, Z. B.; Huang, J. B. Soft Matter 2011, 7, 2762. doi: 10.1039/c0sm01050b
27. [27]
  (27) Shikata, T.; Hirata, H.; Kotaka, T. Langmuir 1989, 5, 398. doi: 10.1021/la00086a020
28. [28]
  (28) Hoffmann, H. Structure and Flow in Surfactant Solutions; Herb, C. A., Prud' homme., R. K. Eds.; American Chemical Society:Washington, DC, 1994; pp 2-31.
29. [29]
  (29) Lin, Z. Langmuir 1996, 12, 1729. doi: 10.1021/la950570q
30. [30]
  (30) Regev, O.; Guillemet, F. Langmuir 1999, 15, 4357. doi: 10.1021/la980935h
31. [31]
  (31) Li, X.; Dong, S. L.; Hao, J. C. Soft Matter 2009, 5, 990. doi: 10.1039/b815640a
32. [32]
  (32) Jiang, L. X.; Deng, M. L.;Wang, Y. L.; Liang, D. H.; Yan, Y.; Huang, J. B. J. Phys. Chem. B 2009, 113, 7498.
33. [33]
  (33) Nagarajan, R. Langmuir 2002, 18, 31. doi: 10.1021/la010831y
34. [34]
  (34) Raghavan, S. R.; Kaler, E.W. Langmuir 2001, 17, 300. doi: 10.1021/la0007933
35. [35]
  (35) Makhloufi, R.; Cressely, R. Colloid Polym. Sci. 1992, 270, 1035. doi: 10.1007/BF00655973
36. [36]
  (36) Ponton, A.; Schott, C.; Quemada, D. Colloids Surf. A 1998, 145, 37. doi: 10.1016/S0927-7757(98)00681-5
37. [37]
  (37) Kalur, G. C.; Frounfelker, B. D.; Cipriano, B. H.; Norman, A. I.; Raghavan, S. R. Langmuir 2005, 21, 10998. doi: 10.1021/la052069w
38. [38]
  (38) Hassan, P. A.; Valaulikar, B. S.; Manohar, C.; Kern, F.; Bourdieu, L.; Candau, S. J. Langmuir 1996, 12, 4350. doi: 10.1021/la960269p
39. [39]
  (39) Menon, S. V. G.; Manohar, C.; Lequeux, F. Chem. Phys. Lett. 1996, 263, 727. doi: 10.1016/S0009-2614(96)01279-1
40. [40]
  (40) Narayanan, J.; Mendes, E.; Manohar, C. Int. J. Mod. Phys. B 2002, 16, 375. doi: 10.1142/S0217979202009895
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
4. [4]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
5. [5]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
8. [8]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
9. [9]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
10. [10]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
11. [11]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
12. [12]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
13. [13]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
14. [14]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
15. [15]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
16. [16]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
17. [17]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
18. [18]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
19. [19]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
20. [20]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(289)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142