Citation: HU Bin, WANG Pei, LÜ Xiao-Jing, WANG Ping-Jing, DAI Yu-Yu, OUYANG Mi. Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 961-968. doi: 10.3866/PKU.WHXB201601047 shu

Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers

HU Bin ^1,, ,
WANG Pei ¹ ,
LÜ Xiao-Jing ² ,
WANG Ping-Jing ² ,
DAI Yu-Yu ² ,
OUYANG Mi ^2,,

1.
1. Key Laboratory of Rare Earth Functional Materials and Applications, Zhoukou Normal University, Zhoukou 466001, Henan Province, P. R. China;
2.
2. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Corresponding author: HU Bin, OUYANG Mi,
Received Date: 23 November 2015
Available Online: 28 December 2015
Fund Project: 国家自然科学基金(51203138, 51273179) (51203138, 51273179)河南省重点科技攻关项目(152102210156)资助 (152102210156)

Copolymers were prepared by electropolymerization using different feed ratios of 6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)hexyl ferrocenecarboxylate (BTC-H-Fc) and 3,4-ethoxylenedioxythiophene (EDOT). The structure and performance of copolymers were characterized by electrochemical measurements, Fourier transform infrared (FT-IR) spectroscopy, and spectroelectrochemistry. The results showed that all the copolymers could exhibit desirable electrochemical features. Spectroelectrochemical studies indicated that P(BTC-H-Fc: EDOT)-1 was light green at the neutral state, and changed to green and then purple with increasing applied potential. P(BTC-H-Fc:EDOT)-4 possessed outstanding color-changing ability; its colors included chocolate brown, yellow brown, green, blue, and purple. P(BTC-H-Fc:EDOT)-8 could be chocolate brown, gray black, blue green, and sky blue. All the copolymer films possessed favorable optical contrast, switching time, and coloration efficiency, laying the foundation for their potential applications in electrochromic device.
- Conjugated polymer,
- Electrochromism,
- Ferrocene,
- Electropolymerization,
- Coloration efficiency
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