Citation: ZHAN Xuan, ZHAO Fang, ZHANG Lei, LÜ Biao-Biao PENG Su-Hong, YING Xiao, WANG Hui, LIU Hai-Yang, . Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 771-779. doi: 10.3866/PKU.WHXB201601043 shu

Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect

ZHAN Xuan ¹ ,
ZHAO Fang ² ,
ZHANG Lei ^2,, ,
LÜ Biao-Biao PENG Su-Hong ³ ,
YING Xiao ¹ ,
WANG Hui ³ ,
LIU Hai-Yang ^2,, ,
^1,2,,

1.
1 Department of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China;
2.
2 State Key Laboratory of Optoelectronics Materials and Technologies, Sun-Yat Sen University, Guangzhou 510275, P. R. China;
3.
3 Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China

Corresponding author: ZHANG Lei, LIU Hai-Yang, ,
Received Date: 3 November 2015
Available Online: 31 December 2015
Fund Project: 国家自然科学基金(21171057,21371059) (21171057,21371059)国家重点基础研究发展规划项目(973)(2013CB922403) (973)(2013CB922403)中山大学光电材料与技术国家重点实验室开放基金(OEMT-2015-KF-05)资助项目 (OEMT-2015-KF-05)

The photophysical properties of pentafluorophenyl-substituted gallium corroles in halogenated benzenes were investigated using ultraviolet-visible (UV-Vis), steady-state, time-resolved fluorescence, and femtosecond transient absorption spectroscopies. The results showed that the absorption maximum wavelength of the gallium corroles was mainly related to the dispersion force of the halogenated benzene solvents. The external heavy atom effect of halogenated benzenes may markedly lower the fluorescence quantum yield of gallium corrole complexes. Photoinduced electron transfer between the gallium corroles and halogenated benzene solvents was detected by femtosecond transient absorption spectroscopy. The experimental evidence showed that the heavy atom effect of the solvent might lower the charge recombination rate of charge-separated gallium corrole-solvent complexes.
- Corrole,
- Gallium,
- Halogenated benzene solvent,
- External heavy atom effect,
- Photophysical property
1. [1]
  (1) Zdilla, M. J.; Abu, O. M. Inorg. Chem. 2008, 47 (22), 10718. doi: 10.1021/ic801182q
2. [2]
  (2) Flamigni, L.; GryKo, D. T. Chem. Soc. Rev. 2009, 38, 1635. doi: 10.1039/b805230c
3. [3]
  (3) Gross, Z.; Galili, N.; Saltsman, I. Angew. Chem. Int. Edit.1999, 38, 1427. doi: 1433-7851/99/3810-1428
4. [4]
  (4) Paolesse, R.; Jaquinod, L.; Nurco, D.; Mini, S.; Sagone, F.; Boschi, T.; Smith, K. M. Chem. Commun. 1999, 1307. doi: 10.1039/A903247I
5. [5]
  (5) Bose, S.; Pariyar, A.; Biswas, A. N.; Bandyopadhyay, P. Catal. Commum. 2011, 12, 1193. doi: 10.1016/j.catcom.2011.04.026
6. [6]
  (6) Liu, H. Y.; Mahmood, M. H. R.; Qiu, S. X.; Chang, C. K.Coord. Chem. Rev. 2013, 25, 1306. doi: 10.1016/j.ccr.2012.12.017
7. [7]
  (7) Chang, C. K.; Kong, P.W.; Liu, H. Y.; Yeung, L. L.; Koon, H.K.; Mak, N. K. Proc. SPIE-Int. Soc. Opt. Eng. 2006, 6139, 613911. doi: 10.1117/12.646328
8. [8]
  (8) Zhang, Y.; Chen, H.; Wen, J. Y.; Wang, X. L.; Wang, H.; Ji, L.N.; Liu, H. Y. Chem. J. Chin. Univ. 2013, 34, 2462. [张阳, 陈欢, 闻金燕, 王湘利, 王惠, 计亮年, 刘海洋. 高等化学学报, 2013, 34, 2462.] doi: 10.7503/cjcu20130610
9. [9]
  (9) Robert, C.; Ohkawara, T. Chem. Eur. J. 2014, 20 (16), 4789. doi: 10.1002/chem.v20.16
10. [10]
  (10) Zou, H. B.; Yang, H.; Liu, Z. Y.; Liu, H. Y. Organomeallic2015, 34 (12), 2791. doi: 10.1021/acs.organomet.5b00069
11. [11]
  (11) Barata, J. F. B.; Zamarron, A.; Neves, M.; Graca, P. M. S. Eur. J. Med. Chem. 2015, 92, 135. doi: 10.1016/j.ejmech.2014.12.025
12. [12]
  (12) Chun, Z.; Jin, X. J. Power Sources 2015, 283, 343. doi: 10.1016/j.jpowsour.2015.02.136
13. [13]
  (13) Basumatary, B.; Sekhar, A. Inorg. Chem. 2015, 54 (9), 4257. doi: 10.1021/ic502919s
14. [14]
  (14) Santtos, C. I. M.; Oliveria, E. Inorg. Chim. Acta 2014, 417, 148. doi: 10.1016/j.ica.2013.09.049
15. [15]
  (15) Agadjannian, H.; Ma, J.; Rentsendorj, A.; Valluripalli, V.; Hwang, J. Y.; Mahammed, A.; Farkas, D. L.; Gray, H. B.; Gross, Z.; Medina-Kauwe, L. K. Proc. Natl. Acad. Sci. U. S. A.2009, 106 (15), 6105. doi: 10.1073/pnas.0901531106
16. [16]
  (16) Wang, J. Y.; Lubow, I.; Chu, D.; Hwang, J. Y.; Lubow, J.; Chu, D.; Ma, J.; Agadjanian, H.; Sims, J.; Gray, H. B.; Gross, Z.; Farkas, D. L.; Lali, K.; Medina-Kauwe, L. K. Mol. Pharm.2011, 8, 2233. doi: 10.1021/mp200094w
17. [17]
  (17) Lim, P.; Mahammed, A.; OKun, Z.; Saltsman, I.; Gross, Z.; Gray, H. B.; Termini, J. Chem. Res. Toxicol. 2012, 25, 400. doi: 10.1021/tx200452w
18. [18]
  (18) Peng, K. M.; Shao, W. L.; Wang, H. H.; Ying, X.; Wang, H.; Ji, L. N.; Liu, H. Y. Acta Phys. -Chim. Sin. 2011, 27 (1), 199. [彭开美, 邵文莉, 汪华华, 应晓, 王惠, 计亮年, 刘海洋.物理化学学报, 2011, 27 (1), 199.] doi: 10.3866/PKU.WHXB20110129
19. [19]
  (19) Zhang, L.; Liu, Z. Y.; Zhan, X.; Liu, H. Y. Photochem. Photobiol. Sci. 2015, 14, 953. doi: 10.1039/c5pp00060b
20. [20]
  (20) Liu, H. Y.; Lai, T. S.; Yeung, L. L. Org. Lett. 2003, 5, 617. doi: 10.1021/ol027111i
21. [21]
  (21) Jozefowicz, M.; Bajorek, M.; Heldt, J. J. Lumin. 2014, 153, 152. doi: 10.1016/j.jlumin.2014.03.019
22. [22]
  (22) Strat, G.; Strat, M. Spectros. Lett. 1994, 27, 177. doi: 10.1080/00387019408000836
23. [23]
  (23) Liu, X.; Mahammed, A.; Tripathy, U.; Gross, Z.; Steer, R. P.Chem. Phys. Lett. 2008, 459, 113. doi: 10.1016/j.cplett.2008.05.038
24. [24]
  (24) Shao, W. L. Photophysical Study on Ultrafast ElectronTransfer in Biomolecular Systems. Sun-Yat Sen University: Guangzhou, 2012; pp 15-30. [邵文莉. 新型光敏剂Corrole的激发态动力学及单线态氧产生过程研究[D]. 广州: 中山大学, 2012: 15-30.]
25. [25]
  (25) Yang, X.; Pan, Z. T.; Ma, Y. J. Analytical. Sci. 2003, 19 (6), 588. doi: 10.3969/j.issn.1006-6144.2003.06.028
26. [26]
  (26) Paul, G. S.; Martin, G. J. Mol. Spectrosc. 1969, 3, 1. doi: 10.1016/0022-2852(69)90335-X
27. [27]
  (27) You, L. L.; Shen, H.; Shi, L.; Zhang, G. L.; Liu, H. Y.; Wang, H.; Ji, L. N. Scientia Sinica chimica 2010, 40, 224. [游丽莉, 沈涵, 史蕾, 张国良, 刘海洋, 王惠, 计亮年. 中国科学, 2010, 40, 224.]
28. [28]
  (28) Chen, P.; Ge, F. Y. Chemistry Online 2014, 77, 243. [陈鹏, 葛凤燕. 化学通报, 2014, 77, 243.] doi: 10.14159/j.cnki.0441-3776.2014.03.008
29. [29]
  (29) Guo, C.; Feng, M. B. Chin. J. Lumin. 1987, 8 (2), 92. [郭础, 冯梅波. 发光学报, 1987, 8 (2), 92.]
30. [30]
  (30) Shi, L.; Liu, H, Y.; Shen, H. J. Porphyr. Phthalocya. 2009, 13, 1221. doi: 10.1142/S1088424609001546
31. [31]
  (31) Ghosh, M.; Mora, A. K.; Sukhendu, N, P.; Kumar, P. H.; Bangal, P. R.; Sinha, S. J. Photochem. Photobiol. A 2015, 306, 55. doi: 10.1016/j.jphotochem.2015.03.019
32. [32]
  (32) Hayes, R, T.; Walsh, C, J.; Wasielewski, M, R. J. Phys. Chem. A 2004, 108, 2375. doi: 10.1021/jp037176i
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