Citation: ZHAN Xuan, ZHAO Fang, ZHANG Lei, LÜ Biao-Biao PENG Su-Hong, YING Xiao, WANG Hui, LIU Hai-Yang, . Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 771-779. doi: 10.3866/PKU.WHXB201601043 shu

Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect

ZHAN Xuan ¹ ,
ZHAO Fang ² ,
ZHANG Lei ^2,, ,
LÜ Biao-Biao PENG Su-Hong ³ ,
YING Xiao ¹ ,
WANG Hui ³ ,
LIU Hai-Yang ^2,, ,
^1,2,,

1.
1 Department of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China;
2.
2 State Key Laboratory of Optoelectronics Materials and Technologies, Sun-Yat Sen University, Guangzhou 510275, P. R. China;
3.
3 Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China

Corresponding author: ZHANG Lei, LIU Hai-Yang, ,
Received Date: 3 November 2015
Available Online: 31 December 2015
Fund Project: 国家自然科学基金(21171057,21371059) (21171057,21371059)国家重点基础研究发展规划项目(973)(2013CB922403) (973)(2013CB922403)中山大学光电材料与技术国家重点实验室开放基金(OEMT-2015-KF-05)资助项目 (OEMT-2015-KF-05)

The photophysical properties of pentafluorophenyl-substituted gallium corroles in halogenated benzenes were investigated using ultraviolet-visible (UV-Vis), steady-state, time-resolved fluorescence, and femtosecond transient absorption spectroscopies. The results showed that the absorption maximum wavelength of the gallium corroles was mainly related to the dispersion force of the halogenated benzene solvents. The external heavy atom effect of halogenated benzenes may markedly lower the fluorescence quantum yield of gallium corrole complexes. Photoinduced electron transfer between the gallium corroles and halogenated benzene solvents was detected by femtosecond transient absorption spectroscopy. The experimental evidence showed that the heavy atom effect of the solvent might lower the charge recombination rate of charge-separated gallium corrole-solvent complexes.
- Corrole,
- Gallium,
- Halogenated benzene solvent,
- External heavy atom effect,
- Photophysical property
1. [1]
  (1) Zdilla, M. J.; Abu, O. M. Inorg. Chem. 2008, 47 (22), 10718. doi: 10.1021/ic801182q
2. [2]
  (2) Flamigni, L.; GryKo, D. T. Chem. Soc. Rev. 2009, 38, 1635. doi: 10.1039/b805230c
3. [3]
  (3) Gross, Z.; Galili, N.; Saltsman, I. Angew. Chem. Int. Edit.1999, 38, 1427. doi: 1433-7851/99/3810-1428
4. [4]
  (4) Paolesse, R.; Jaquinod, L.; Nurco, D.; Mini, S.; Sagone, F.; Boschi, T.; Smith, K. M. Chem. Commun. 1999, 1307. doi: 10.1039/A903247I
5. [5]
  (5) Bose, S.; Pariyar, A.; Biswas, A. N.; Bandyopadhyay, P. Catal. Commum. 2011, 12, 1193. doi: 10.1016/j.catcom.2011.04.026
6. [6]
  (6) Liu, H. Y.; Mahmood, M. H. R.; Qiu, S. X.; Chang, C. K.Coord. Chem. Rev. 2013, 25, 1306. doi: 10.1016/j.ccr.2012.12.017
7. [7]
  (7) Chang, C. K.; Kong, P.W.; Liu, H. Y.; Yeung, L. L.; Koon, H.K.; Mak, N. K. Proc. SPIE-Int. Soc. Opt. Eng. 2006, 6139, 613911. doi: 10.1117/12.646328
8. [8]
  (8) Zhang, Y.; Chen, H.; Wen, J. Y.; Wang, X. L.; Wang, H.; Ji, L.N.; Liu, H. Y. Chem. J. Chin. Univ. 2013, 34, 2462. [张阳, 陈欢, 闻金燕, 王湘利, 王惠, 计亮年, 刘海洋. 高等化学学报, 2013, 34, 2462.] doi: 10.7503/cjcu20130610
9. [9]
  (9) Robert, C.; Ohkawara, T. Chem. Eur. J. 2014, 20 (16), 4789. doi: 10.1002/chem.v20.16
10. [10]
  (10) Zou, H. B.; Yang, H.; Liu, Z. Y.; Liu, H. Y. Organomeallic2015, 34 (12), 2791. doi: 10.1021/acs.organomet.5b00069
11. [11]
  (11) Barata, J. F. B.; Zamarron, A.; Neves, M.; Graca, P. M. S. Eur. J. Med. Chem. 2015, 92, 135. doi: 10.1016/j.ejmech.2014.12.025
12. [12]
  (12) Chun, Z.; Jin, X. J. Power Sources 2015, 283, 343. doi: 10.1016/j.jpowsour.2015.02.136
13. [13]
  (13) Basumatary, B.; Sekhar, A. Inorg. Chem. 2015, 54 (9), 4257. doi: 10.1021/ic502919s
14. [14]
  (14) Santtos, C. I. M.; Oliveria, E. Inorg. Chim. Acta 2014, 417, 148. doi: 10.1016/j.ica.2013.09.049
15. [15]
  (15) Agadjannian, H.; Ma, J.; Rentsendorj, A.; Valluripalli, V.; Hwang, J. Y.; Mahammed, A.; Farkas, D. L.; Gray, H. B.; Gross, Z.; Medina-Kauwe, L. K. Proc. Natl. Acad. Sci. U. S. A.2009, 106 (15), 6105. doi: 10.1073/pnas.0901531106
16. [16]
  (16) Wang, J. Y.; Lubow, I.; Chu, D.; Hwang, J. Y.; Lubow, J.; Chu, D.; Ma, J.; Agadjanian, H.; Sims, J.; Gray, H. B.; Gross, Z.; Farkas, D. L.; Lali, K.; Medina-Kauwe, L. K. Mol. Pharm.2011, 8, 2233. doi: 10.1021/mp200094w
17. [17]
  (17) Lim, P.; Mahammed, A.; OKun, Z.; Saltsman, I.; Gross, Z.; Gray, H. B.; Termini, J. Chem. Res. Toxicol. 2012, 25, 400. doi: 10.1021/tx200452w
18. [18]
  (18) Peng, K. M.; Shao, W. L.; Wang, H. H.; Ying, X.; Wang, H.; Ji, L. N.; Liu, H. Y. Acta Phys. -Chim. Sin. 2011, 27 (1), 199. [彭开美, 邵文莉, 汪华华, 应晓, 王惠, 计亮年, 刘海洋.物理化学学报, 2011, 27 (1), 199.] doi: 10.3866/PKU.WHXB20110129
19. [19]
  (19) Zhang, L.; Liu, Z. Y.; Zhan, X.; Liu, H. Y. Photochem. Photobiol. Sci. 2015, 14, 953. doi: 10.1039/c5pp00060b
20. [20]
  (20) Liu, H. Y.; Lai, T. S.; Yeung, L. L. Org. Lett. 2003, 5, 617. doi: 10.1021/ol027111i
21. [21]
  (21) Jozefowicz, M.; Bajorek, M.; Heldt, J. J. Lumin. 2014, 153, 152. doi: 10.1016/j.jlumin.2014.03.019
22. [22]
  (22) Strat, G.; Strat, M. Spectros. Lett. 1994, 27, 177. doi: 10.1080/00387019408000836
23. [23]
  (23) Liu, X.; Mahammed, A.; Tripathy, U.; Gross, Z.; Steer, R. P.Chem. Phys. Lett. 2008, 459, 113. doi: 10.1016/j.cplett.2008.05.038
24. [24]
  (24) Shao, W. L. Photophysical Study on Ultrafast ElectronTransfer in Biomolecular Systems. Sun-Yat Sen University: Guangzhou, 2012; pp 15-30. [邵文莉. 新型光敏剂Corrole的激发态动力学及单线态氧产生过程研究[D]. 广州: 中山大学, 2012: 15-30.]
25. [25]
  (25) Yang, X.; Pan, Z. T.; Ma, Y. J. Analytical. Sci. 2003, 19 (6), 588. doi: 10.3969/j.issn.1006-6144.2003.06.028
26. [26]
  (26) Paul, G. S.; Martin, G. J. Mol. Spectrosc. 1969, 3, 1. doi: 10.1016/0022-2852(69)90335-X
27. [27]
  (27) You, L. L.; Shen, H.; Shi, L.; Zhang, G. L.; Liu, H. Y.; Wang, H.; Ji, L. N. Scientia Sinica chimica 2010, 40, 224. [游丽莉, 沈涵, 史蕾, 张国良, 刘海洋, 王惠, 计亮年. 中国科学, 2010, 40, 224.]
28. [28]
  (28) Chen, P.; Ge, F. Y. Chemistry Online 2014, 77, 243. [陈鹏, 葛凤燕. 化学通报, 2014, 77, 243.] doi: 10.14159/j.cnki.0441-3776.2014.03.008
29. [29]
  (29) Guo, C.; Feng, M. B. Chin. J. Lumin. 1987, 8 (2), 92. [郭础, 冯梅波. 发光学报, 1987, 8 (2), 92.]
30. [30]
  (30) Shi, L.; Liu, H, Y.; Shen, H. J. Porphyr. Phthalocya. 2009, 13, 1221. doi: 10.1142/S1088424609001546
31. [31]
  (31) Ghosh, M.; Mora, A. K.; Sukhendu, N, P.; Kumar, P. H.; Bangal, P. R.; Sinha, S. J. Photochem. Photobiol. A 2015, 306, 55. doi: 10.1016/j.jphotochem.2015.03.019
32. [32]
  (32) Hayes, R, T.; Walsh, C, J.; Wasielewski, M, R. J. Phys. Chem. A 2004, 108, 2375. doi: 10.1021/jp037176i
1. [1]
  Jialiang XU , Jiabin CUI . Recent biological applications of corroles: From diagnosis to therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2303-2317. doi: 10.11862/CJIC.20240245
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
4. [4]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
5. [5]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
6. [6]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
7. [7]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
8. [8]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
9. [9]
  Daojuan Cheng , Fang Fang . Exploration and Implementation of Science-Education Integration in Organic Chemistry Teaching for Pharmacy Majors: A Case Study on Nucleophilic Substitution Reactions of Alkyl Halides. University Chemistry, 2024, 39(11): 72-78. doi: 10.12461/PKU.DXHX202403105
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Yecang Tang , Shan Ling , Zhen Fang . Exploration of a Hierarchical and Integration-Oriented Talent Training Model in the Demonstration Center for Experimental Chemistry Education. University Chemistry, 2024, 39(7): 188-192. doi: 10.12461/PKU.DXHX202405107
12. [12]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
13. [13]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
14. [14]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
15. [15]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
16. [16]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
17. [17]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
18. [18]
  Yaqin Zheng , Lian Zhuo , Meng Li , Chunying Rong . Enhancing Understanding of the Electronic Effect of Substituents on Benzene Rings Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 193-198. doi: 10.12461/PKU.DXHX202406119
19. [19]
  Guoxian Zhu , Jing Chen , Rongkai Pan . Enhancing the Teaching Quality of Atomic Structure: Insights and Strategies. University Chemistry, 2024, 39(3): 376-383. doi: 10.3866/PKU.DXHX202305027
20. [20]
  Jin Jia , Shangda Jiang . Is the z Axis Special in Atomic Structure?. University Chemistry, 2024, 39(6): 400-404. doi: 10.12461/PKU.DXHX202403091

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(460)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142