Citation: ZHAN Xuan, ZHAO Fang, ZHANG Lei, LÜ Biao-Biao PENG Su-Hong, YING Xiao, WANG Hui, LIU Hai-Yang, . Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 771-779. doi: 10.3866/PKU.WHXB201601043 shu

Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect

ZHAN Xuan ¹ ,
ZHAO Fang ² ,
ZHANG Lei ^2,, ,
LÜ Biao-Biao PENG Su-Hong ³ ,
YING Xiao ¹ ,
WANG Hui ³ ,
LIU Hai-Yang ^2,, ,
^1,2,,

1.
1 Department of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China;
2.
2 State Key Laboratory of Optoelectronics Materials and Technologies, Sun-Yat Sen University, Guangzhou 510275, P. R. China;
3.
3 Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China

Corresponding author: ZHANG Lei, LIU Hai-Yang, ,
Received Date: 3 November 2015
Available Online: 31 December 2015
Fund Project: 国家自然科学基金(21171057,21371059) (21171057,21371059)国家重点基础研究发展规划项目(973)(2013CB922403) (973)(2013CB922403)中山大学光电材料与技术国家重点实验室开放基金(OEMT-2015-KF-05)资助项目 (OEMT-2015-KF-05)

The photophysical properties of pentafluorophenyl-substituted gallium corroles in halogenated benzenes were investigated using ultraviolet-visible (UV-Vis), steady-state, time-resolved fluorescence, and femtosecond transient absorption spectroscopies. The results showed that the absorption maximum wavelength of the gallium corroles was mainly related to the dispersion force of the halogenated benzene solvents. The external heavy atom effect of halogenated benzenes may markedly lower the fluorescence quantum yield of gallium corrole complexes. Photoinduced electron transfer between the gallium corroles and halogenated benzene solvents was detected by femtosecond transient absorption spectroscopy. The experimental evidence showed that the heavy atom effect of the solvent might lower the charge recombination rate of charge-separated gallium corrole-solvent complexes.
- Corrole,
- Gallium,
- Halogenated benzene solvent,
- External heavy atom effect,
- Photophysical property
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