Citation: CHEN Feng-Feng, DONG Yan, SANG Xiao-Yan, ZHOU Yan, TAO Duan-Jian. Physicochemical Properties and CO₂ Solubility of Tetrabutylphosphonium Carboxylate Ionic Liquids[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 605-610. doi: 10.3866/PKU.WHXB201512241 shu

Physicochemical Properties and CO₂ Solubility of Tetrabutylphosphonium Carboxylate Ionic Liquids

1.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China

Corresponding author: ZHOU Yan, TAO Duan-Jian,
Received Date: 11 September 2015
Available Online: 23 December 2015
Fund Project: 国家自然科学基金(21206063,21566011,31570560) (21206063,21566011,31570560)江西省自然科学基金(20151BAB213016) (20151BAB213016)

Four tetrabutylphosphonium carboxylate ionic liquids ([P₄₄₄₄][CA]) were prepared, and their densities, viscosities, refractive indices, and conductivities were measured and correlated with thermodynamic and empirical equations in the temperature range of 298.15-348.15 K. The influence of temperature on these four properties of [P₄₄₄₄][CA] was discussed, and their thermal expansion coefficient values were calculated. The CO₂ absorption capacity of [P₄₄₄₄][CA] was studied at 313.15 K and 100 kPa. The results indicated that [P₄₄₄₄][Buty] had the highest CO₂ capture capacity among these ionic liquids, with an absorption capacity of 0.4 mol·mol^-1 and balance time of less than 5 min.
- Ionic liquid,
- Tetrabutylphosphonium carboxylate,
- Physicochemical property,
- CO₂ capture
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Physicochemical Properties and CO2 Solubility of Tetrabutylphosphonium Carboxylate Ionic Liquids

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通讯作者: 陈斌, bchen63@163.com

Physicochemical Properties and CO₂ Solubility of Tetrabutylphosphonium Carboxylate Ionic Liquids