Citation: LIU Qing-Shan, LIU Hui, MOU Lin. Properties of 1-(Cyanopropyl)-3-methylimidazolium Bis[(trifluoromethyl)sulfonyl]imide[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 617-623. doi: 10.3866/PKU.WHXB201512171 shu

Properties of 1-(Cyanopropyl)-3-methylimidazolium Bis[(trifluoromethyl)sulfonyl]imide

LIU Qing-Shan ^1,, ,
LIU Hui ^2,3 ,
MOU Lin ^1,,

1.
1 School of Science, Shenyang Agricultural University, Shenyang 110866, P. R. China;
2.
2 Shanghai Environmental Sanitation Engineering Design Institute Co., Ltd., Shanghai 200232, P. R. China;
3.
3 Shanghai Engineering Research Center of Contaminated Sites Remediation, Shanghai 200232, P. R. China

Corresponding author: LIU Qing-Shan, MOU Lin,
Received Date: 3 August 2015
Available Online: 17 December 2015
Fund Project: 国家自然科学基金(21203193) (21203193)辽宁省高等学校优秀人才支持计划(LJQ2015099)资助 (LJQ2015099)

The functional ionic liquid (FIL) 1-(cyanopropyl)-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide [PCNMIM][NTf₂] was synthesized using an ion-exchange method. Density, dynamic viscosity, electrical conductivity, and refractive index were determined in the temperature range 283.15-353.15 K. The effect of methylene group introduction is discussed for the FILs and imidazolium ionic liquids (ILs). The thermal expansion coefficient, molecular volume, standard molar entropy, and lattice energy were determined by the empirical equations from the measurement values. The temperature dependence on electrical conductivity and dynamic viscosity of the FILs were fitted by the Vogel-Fulcher-Tammann (VFT) equation. The adaptability of the Arrhenius equation was also discussed for the electrical conductivity and dynamic viscosity. The study of the thermodynamic properties of the FIL is important for synthesis of new ILs and their application.
- Functional ionic liquid,
- Density,
- Dynamic viscosity,
- Electrical conductivity,
- Refractive index
1. [1]
  (1) Welton, T. Chem. Rev. 1999, 99, 2071. doi: 10.1021/cr980032t
2. [2]
  (2) Rantwijk, F. V.; Sheldon, R. A. Chem. Rev. 2007, 107, 2757. doi: 10.1021/cr050946x
3. [3]
  (3) Greaves, T. L.; Drummond, C. J. Chem. Rev. 2008, 108, 206. doi: 10.1021/cr068040u
4. [4]
  (4) Hapiot, P.; Lagrost, C. Chem. Rev. 2008, 108, 2238. doi: 10.1021/cr0680686
5. [5]
  (5) Jessop, P. G.; Subramaniam, B. Chem. Rev. 2007, 107, 2666. doi: 10.1021/cr040199o
6. [6]
  (6) Egashira, M.; Okada, S; Yamaki, S. J. I.; Dri, D. A.; Bonadies, F.; Scrodati, B. J. Power Sources 2004, 138, 240. doi: 10.1016/j.jpowsour.2004.06.022
7. [7]
  (7) Egashira, M.; Todo, H.; Yoshimoto, N; Morita, N. M.; Yamaki, J. I. J. Power Sources 2007, 174, 560. doi: 10.1016/j.jpowsour.2007.06.123
8. [8]
  (8) Egashira, M.; Nakagawa, M.; Watanabe, I.; Okada, S.; Yamaki, J. I. J. Power Sources 2005, 146, 685. doi: 10.1016/j.jpowsour.2005.03.069
9. [9]
  (9) Hardacre, C.; Holbrey, J. D.; Mullan, C. L.; Nieuwenhuyzen, M.; Reichert, W. M.; Seddon, K. R.; Teat, S. J. New J. Chem.2008, 32, 1953. doi: 10.1039/b805063e
10. [10]
  (10) Hardacre, C.; Holbrey, J. D.; Mullan, C. L.; Nieuwenhuyzen, M.; Youngs, T. G. A.; Bowron, D. T.; Teat, S. J. Phys. Chem. Chem. Phys. 2010, 12, 1842. doi: 10.1039/b921160h
11. [11]
  (11) Zhang, J.; Zhang, Q.; Qiao, B.; Deng, Y. J. Chem. Eng. Data2007, 52, 2277. doi: 10.1021/je700297c
12. [12]
  (12) Liu, Q. S.; Liu, J.; Liu, X. X.; Zhang, S. T. J. Chem. Thermodyn. 2015, 90, 39. doi: 10.1016/j.jct.2015.06.010
13. [13]
  (13) Bates, E. D.; Mayton, R. D.; Ntai, I.; Davis, J. H., Jr. J. Am. Chem. Soc. 2002, 124, 926. doi: 10.1021/ja017593d
14. [14]
  (14) Cai, Y.; Peng, Y.; Song, G. Catal. Lett. 2006, 109, 61. doi: 10.1007/s10562-006-0057-3
15. [15]
  (15) Hu, S.; Jiang, T.; Zhang, Z.; Zhu, A.; Han, B.; Song, J.; Xie, Y.; Li, W. Tetrahedron Lett. 2007, 48, 5613. doi: 10.1016/j.tetlet.2007.06.051
16. [16]
  (16) Jacquemin, J.; Husson, P.; Padua, A. A. H.; Majer, V. Green Chem. 2006, 8, 172. doi: 10.1039/B513231B
17. [17]
  (17) Chen, Y.; Zhuo, K.; Chen, J.; Bai, G. J. Chem. Thermodyn.2015, 86, 13. doi: 10.1016/j.jct.2015.02.017
18. [18]
  (18) Chen, Y.; Zhang, H.; Li, A.; Zhuo, K. Fluid Phase Equilibr.2015, 388, 78. doi: 10.1016/j.fluid.2014.12.038
19. [19]
  (19) Wei, J.; Chang, C.; Zhang, Y. Y.; Hou, S. Y.; Fang, D.W.; Guan, W. J. Chem. Thermodyn. 2015, 90, 310. doi: 10.1016/j.jct.2015.04.029
20. [20]
  (20) Ma, X. X.; Wei, J.; Guan, W.; Pan, Y.; Zheng, L.; Wu, Y.; Yang, J. Z. J. Chem. Thermodyn. 2015, 89, 51. doi: 10.1016/j.jct.2015.02.025
21. [21]
  (21) Tong, J.; Hong, M.; Chen, Y.; Wang, H.; Guan, W.; Yang, J. Z.J. Chem. Thermodyn. 2012, 54, 352. doi: 10.1016/j.jct.2012.05.012
22. [22]
  (22) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001-2002.
23. [23]
  (23) Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Chen, J.; Liu, X. X. J. Chem. Thermodyn. 2013, 66, 88. doi: 10.1016/j.jct.2013.06.008
24. [24]
  (24) Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.; Welz-Biermann, U. J. Chem. Eng. Data 2010, 55, 4928. doi: 10.1021/je100507n
25. [25]
  (25) Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Liu, X. X.; Chen, J. J. Chem. Eng. Data 2012, 57, 2999. doi: 10.1021/je3004645
26. [26]
  (26) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山, 颜佩芳, 杨淼, 谭志诚, 李长平, Welz-Biermann U. 物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762
27. [27]
  (27) Zhang, Q. G.; Wei, Y.; Sun, S. S.; Wang, C.; Yang, M.; Liu, Q.S.; Gao, Y. A. J. Chem. Eng. Data 2012, 57, 2185. doi: 10.1021/je300153f
28. [28]
  (28) Cheng, Z.; Lee, J. M. J. Phys. Chem. B 2014, 118, 2712. doi: 10.1021/jp411904w
29. [29]
  (29) Glasser, L. Thermochim. Acta 2004, 421, 87. doi: 10.1016/j.tca.2004.03.015
30. [30]
  (30) Liu, Q. S.; Yang, M.; Li, P. P.; Sun, S. S.; Welz-Biermann, U.; Tan, Z. C.; Zhang, Q. G. J. Chem. Eng. Data 2011, 56, 4094. doi: 10.1021/je200534b
31. [31]
  (31) Fang, D.W.; Tong, J.; Guan, W.; Wang, H.; Yang, J. Z. J. Phys. Chem. B 2010, 114, 13808. doi: 10.1021/jp107452q
32. [32]
  (32) Fang, D.W.; Guan, W.; Tong, J.; Wang, Z.W.; Yang, J. Z. J. Phys. Chem. B 2008, 112 7499. doi: 10.1021/jp801269u
33. [33]
  (33) Tong, J.; Song, B.; Wang, C. X.; Li, L.; Guan, W.; Fang, D.W.; Yang, J. Z. Ind. Eng. Chem. Res. 2011, 50, 2418. doi: 10.1021/ie101903t
34. [34]
  (34) Xu, W. G.; Ma, X. X.; Li, L.; Tong, J.; Guan, W. Ind. Eng. Chem. Res. 2012, 51, 4105. doi: 10.1021/ie201530b
35. [35]
  (35) Vila, J.; Ginés, P.; Pico, J. M.; Franjo, C.; Jiménez, E.; Varela, L. M.; Cabeza, O. Fluid Phase Equilibr. 2006, 242, 141. doi: 10.1016/j.fluid.2006.01.022
36. [36]
  (36) Schreiner, C.; Zugmann, S.; Hartl, R.; Gores, H. J. J. Chem. Eng. Data 2010, 55, 1784. doi: 10.1021/je900878j
37. [37]
  (37) Belieres, J. P.; Angell, C. A. J. Phys. Chem. B 2007, 111, 4926. doi: 10.1021/jp067589u
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