Citation:
LIU Qing-Shan, LIU Hui, MOU Lin. Properties of 1-(Cyanopropyl)-3-methylimidazolium Bis[(trifluoromethyl)sulfonyl]imide[J]. Acta Physico-Chimica Sinica,
;2016, 32(3): 617-623.
doi:
10.3866/PKU.WHXB201512171
-
The functional ionic liquid (FIL) 1-(cyanopropyl)-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide [PCNMIM][NTf2] was synthesized using an ion-exchange method. Density, dynamic viscosity, electrical conductivity, and refractive index were determined in the temperature range 283.15-353.15 K. The effect of methylene group introduction is discussed for the FILs and imidazolium ionic liquids (ILs). The thermal expansion coefficient, molecular volume, standard molar entropy, and lattice energy were determined by the empirical equations from the measurement values. The temperature dependence on electrical conductivity and dynamic viscosity of the FILs were fitted by the Vogel-Fulcher-Tammann (VFT) equation. The adaptability of the Arrhenius equation was also discussed for the electrical conductivity and dynamic viscosity. The study of the thermodynamic properties of the FIL is important for synthesis of new ILs and their application.
-
-
-
[1]
(1) Welton, T. Chem. Rev. 1999, 99, 2071. doi: 10.1021/cr980032t
-
[2]
(2) Rantwijk, F. V.; Sheldon, R. A. Chem. Rev. 2007, 107, 2757. doi: 10.1021/cr050946x
-
[3]
(3) Greaves, T. L.; Drummond, C. J. Chem. Rev. 2008, 108, 206. doi: 10.1021/cr068040u
-
[4]
(4) Hapiot, P.; Lagrost, C. Chem. Rev. 2008, 108, 2238. doi: 10.1021/cr0680686
-
[5]
(5) Jessop, P. G.; Subramaniam, B. Chem. Rev. 2007, 107, 2666. doi: 10.1021/cr040199o
-
[6]
(6) Egashira, M.; Okada, S; Yamaki, S. J. I.; Dri, D. A.; Bonadies, F.; Scrodati, B. J. Power Sources 2004, 138, 240. doi: 10.1016/j.jpowsour.2004.06.022
-
[7]
(7) Egashira, M.; Todo, H.; Yoshimoto, N; Morita, N. M.; Yamaki, J. I. J. Power Sources 2007, 174, 560. doi: 10.1016/j.jpowsour.2007.06.123
-
[8]
(8) Egashira, M.; Nakagawa, M.; Watanabe, I.; Okada, S.; Yamaki, J. I. J. Power Sources 2005, 146, 685. doi: 10.1016/j.jpowsour.2005.03.069
-
[9]
(9) Hardacre, C.; Holbrey, J. D.; Mullan, C. L.; Nieuwenhuyzen, M.; Reichert, W. M.; Seddon, K. R.; Teat, S. J. New J. Chem.2008, 32, 1953. doi: 10.1039/b805063e
-
[10]
(10) Hardacre, C.; Holbrey, J. D.; Mullan, C. L.; Nieuwenhuyzen, M.; Youngs, T. G. A.; Bowron, D. T.; Teat, S. J. Phys. Chem. Chem. Phys. 2010, 12, 1842. doi: 10.1039/b921160h
-
[11]
(11) Zhang, J.; Zhang, Q.; Qiao, B.; Deng, Y. J. Chem. Eng. Data2007, 52, 2277. doi: 10.1021/je700297c
-
[12]
(12) Liu, Q. S.; Liu, J.; Liu, X. X.; Zhang, S. T. J. Chem. Thermodyn. 2015, 90, 39. doi: 10.1016/j.jct.2015.06.010
-
[13]
(13) Bates, E. D.; Mayton, R. D.; Ntai, I.; Davis, J. H., Jr. J. Am. Chem. Soc. 2002, 124, 926. doi: 10.1021/ja017593d
-
[14]
(14) Cai, Y.; Peng, Y.; Song, G. Catal. Lett. 2006, 109, 61. doi: 10.1007/s10562-006-0057-3
-
[15]
(15) Hu, S.; Jiang, T.; Zhang, Z.; Zhu, A.; Han, B.; Song, J.; Xie, Y.; Li, W. Tetrahedron Lett. 2007, 48, 5613. doi: 10.1016/j.tetlet.2007.06.051
-
[16]
(16) Jacquemin, J.; Husson, P.; Padua, A. A. H.; Majer, V. Green Chem. 2006, 8, 172. doi: 10.1039/B513231B
-
[17]
(17) Chen, Y.; Zhuo, K.; Chen, J.; Bai, G. J. Chem. Thermodyn.2015, 86, 13. doi: 10.1016/j.jct.2015.02.017
-
[18]
(18) Chen, Y.; Zhang, H.; Li, A.; Zhuo, K. Fluid Phase Equilibr.2015, 388, 78. doi: 10.1016/j.fluid.2014.12.038
-
[19]
(19) Wei, J.; Chang, C.; Zhang, Y. Y.; Hou, S. Y.; Fang, D.W.; Guan, W. J. Chem. Thermodyn. 2015, 90, 310. doi: 10.1016/j.jct.2015.04.029
-
[20]
(20) Ma, X. X.; Wei, J.; Guan, W.; Pan, Y.; Zheng, L.; Wu, Y.; Yang, J. Z. J. Chem. Thermodyn. 2015, 89, 51. doi: 10.1016/j.jct.2015.02.025
-
[21]
(21) Tong, J.; Hong, M.; Chen, Y.; Wang, H.; Guan, W.; Yang, J. Z.J. Chem. Thermodyn. 2012, 54, 352. doi: 10.1016/j.jct.2012.05.012
-
[22]
(22) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001-2002.
-
[23]
(23) Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Chen, J.; Liu, X. X. J. Chem. Thermodyn. 2013, 66, 88. doi: 10.1016/j.jct.2013.06.008
-
[24]
(24) Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.; Welz-Biermann, U. J. Chem. Eng. Data 2010, 55, 4928. doi: 10.1021/je100507n
-
[25]
(25) Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Liu, X. X.; Chen, J. J. Chem. Eng. Data 2012, 57, 2999. doi: 10.1021/je3004645
-
[26]
(26) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山, 颜佩芳, 杨淼, 谭志诚, 李长平, Welz-Biermann U. 物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762
-
[27]
(27) Zhang, Q. G.; Wei, Y.; Sun, S. S.; Wang, C.; Yang, M.; Liu, Q.S.; Gao, Y. A. J. Chem. Eng. Data 2012, 57, 2185. doi: 10.1021/je300153f
-
[28]
(28) Cheng, Z.; Lee, J. M. J. Phys. Chem. B 2014, 118, 2712. doi: 10.1021/jp411904w
-
[29]
(29) Glasser, L. Thermochim. Acta 2004, 421, 87. doi: 10.1016/j.tca.2004.03.015
-
[30]
(30) Liu, Q. S.; Yang, M.; Li, P. P.; Sun, S. S.; Welz-Biermann, U.; Tan, Z. C.; Zhang, Q. G. J. Chem. Eng. Data 2011, 56, 4094. doi: 10.1021/je200534b
-
[31]
(31) Fang, D.W.; Tong, J.; Guan, W.; Wang, H.; Yang, J. Z. J. Phys. Chem. B 2010, 114, 13808. doi: 10.1021/jp107452q
-
[32]
(32) Fang, D.W.; Guan, W.; Tong, J.; Wang, Z.W.; Yang, J. Z. J. Phys. Chem. B 2008, 112 7499. doi: 10.1021/jp801269u
-
[33]
(33) Tong, J.; Song, B.; Wang, C. X.; Li, L.; Guan, W.; Fang, D.W.; Yang, J. Z. Ind. Eng. Chem. Res. 2011, 50, 2418. doi: 10.1021/ie101903t
-
[34]
(34) Xu, W. G.; Ma, X. X.; Li, L.; Tong, J.; Guan, W. Ind. Eng. Chem. Res. 2012, 51, 4105. doi: 10.1021/ie201530b
-
[35]
(35) Vila, J.; Ginés, P.; Pico, J. M.; Franjo, C.; Jiménez, E.; Varela, L. M.; Cabeza, O. Fluid Phase Equilibr. 2006, 242, 141. doi: 10.1016/j.fluid.2006.01.022
-
[36]
(36) Schreiner, C.; Zugmann, S.; Hartl, R.; Gores, H. J. J. Chem. Eng. Data 2010, 55, 1784. doi: 10.1021/je900878j
-
[37]
(37) Belieres, J. P.; Angell, C. A. J. Phys. Chem. B 2007, 111, 4926. doi: 10.1021/jp067589u
-
[1]
-
-
-
[1]
Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
-
[2]
Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
-
[3]
Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
-
[4]
Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041
-
[5]
Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
-
[6]
Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, 2025, 40(3): 148-152. doi: 10.12461/PKU.DXHX202405166
-
[7]
Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
-
[8]
Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
-
[9]
Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
-
[10]
Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
-
[11]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[12]
Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N4 site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
-
[13]
Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
-
[14]
Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
-
[15]
Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
-
[16]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[17]
Xin Lv , Hongxing Zhang , Kaibo Duan , Wenhui Dai , Zhihui Wen , Wei Guo , Junsheng Hao . Lighting the Way Against Cancer: Photodynamic Therapy. University Chemistry, 2024, 39(5): 70-79. doi: 10.3866/PKU.DXHX202309090
-
[18]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[19]
Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
-
[20]
Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(359)
- HTML views(7)