Citation: YANG Jing-He, YANG Duo, TANG Pei, MA Ding. Liquid-Phase Heterogeneous Catalytic Reactions by Metal-Free Graphene-Based Catalysts[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 75-84. doi: 10.3866/PKU.WHXB201512153
-
Metal-free carbon catalysts have been receiving increasing attention in the fields of nanomaterials and catalysis. Compared with conventional metal catalysts, there are many advantages for metal-free carbon catalysts, such as simple synthesis, stable structure, large surface area, and diverse applications. Graphene is one layer of carbon atoms and has a periodic structure of aromatic carbon atoms. Graphene oxide is a highly oxidized form of graphene. As a new carbon material, its application in catalysis has emerged over the past 5 years. Graphene-based materials can efficiently catalyze hydrocarbon conversion, organic synthesis, energy conversion, and other heterogeneous catalytic processes. This review highlights the recent progress in the development of metal-free graphene-based catalysts (graphene oxide and graphene) and associated catalytic reactions.
-
Keywords:
- Graphitic oxide,
- Graphene,
- Catalysis,
- Metal-free,
- Carbon
-
-
[1]
(1) Blaser, H. U.; Malan, C.; Pugin, B.; Spindler, F.; Steiner, H.; Studer, M. Adv. Syn. Catal. 2003, 345, 103. doi: 10.1002/adsc.200390000
-
[2]
(2) Astruc, D.; Lu, F.; Aranzaes, J. R. Angew. Chem. Int. Edit. 2005, 44, 7852.
-
[3]
(3) Balasubramanian, K.; Burghard, M. Small 2005, 1, 180.
-
[4]
(4) Banerjee, S.; Hemraj-Benny, T.; Wong, S. S. Adv. Mater. 2005, 17, 17.
-
[5]
(5) Baleizao, C.; Garcia, H. Chem. Rev. 2006, 106, 3987. doi: 10.1021/cr050973n
-
[6]
(6) Busca, G. Chem. Rev. 2007, 107, 5366. doi: 10.1021/cr068042e
-
[7]
(7) Navalon, S.; Dhakshinamoorthy, A.; Alvaro, M.; Garcia, H. Chem. Rev. 2014, 114, 6179.
-
[8]
(8) Dhakshinamoorthy, A.; Navalon, S.; Alvaro, M.; Garcia, H. ChemSusChem 2012, 5, 46. doi: 10.1002/cssc.201100517
-
[9]
(9) Dhakshinamoorthy, A.; Primo, A.; Concepcion, P.; Alvaro, M.; Garcia, H. Chem. -Eur. J. 2013, 19, 7547. doi: 10.1002/chem.201300653
-
[10]
(10) Zhang, Y.; Zhang, L.; Zhou, C. Accounts Chem. Res. 2013, 46, 2329. doi: 10.1021/ar300203n
-
[11]
(11) Wei, D.; Wu, B.; Guo, Y.; Yu, G.; Liu, Y. Accounts Chem. Res. 2013, 46, 106. doi: 10.1021/ar300103f
-
[12]
(12) Quintana, M.; Vazquez, E.; Prato, M. Accounts Chem. Res. 2013, 46, 138. doi: 10.1021/ar300138e
-
[13]
(13) Park, J.; Yan, M. Accounts Chem. Res. 2013, 46, 181. doi: 10.1021/ar300172h
-
[14]
(14) Malig, J.; Jux, N.; Guldi, D. M. Accounts Chem. Res. 2013, 46, 53. doi: 10.1021/ar300124z
-
[15]
(15) Koehler, F. M.; Stark, W. J. Accounts Chem. Res. 2013, 46, 2297. doi: 10.1021/ar300125w
-
[16]
(16) James, D. K.; Tour, J. M. Accounts Chem. Res. 2013, 46, 2307. doi: 10.1021/ar300127r
-
[17]
(17) Dreyer, D. R.; Park, S.; Bielawski, C. W.; Ruoff, R. S. Chem. Soc. Rev. 2010, 39, 228. doi: 10.1039/B917103G
-
[18]
(18) Pumera, M. Chem. Soc. Rev. 2010, 39, 4146. doi: 10.1039/c002690p
-
[19]
(19) Chua, C. K.; Pumera, M. Chem. Soc. Rev. 2014, 43, 291. doi: 10.1039/C3CS60303B
-
[20]
(20) Zhang, X.; Ji, X.; Su, R. F.; Weeks, B. L.; Zhang, Z.; Deng, S. L. ChemPlusChem 2013, 78, 703. doi: 10.1002/cplu.v78.7
-
[21]
(21) Long, J.; Xie, X.; Xu, J.; Gu, Q.; Chen, L.; Wang, X. ACS Catal. 2012, 2, 622. doi: 10.1021/cs3000396
-
[22]
(22) Yamaguchi, K.; Mizuno, N. Chem. -Eur. J. 2003, 9, 4353. doi: 10.1002/chem.200304916
-
[23]
(23) Yang, J. H.; Sun, G.; Gao, Y.; Zhao, H.; Tang, P.; Tan, J.; Lu, A. H.; Ma, D. Energy Environ. Sci. 2013, 6, 793. doi: 10.1039/c3ee23623d
-
[24]
(24) Gao, Y.; Hu, G.; Zhong, J.; Shi, Z.; Zhu, Y.; Su, D. S.; Wang, J.; Bao, X.; Ma, D. Angew. Chem. Int. Edit. 2013, 52, 2109. doi: 10.1002/anie.v52.7
-
[25]
(25) Li, W.; Gao, Y.; Chen, W.; Tang, P.; Li, W.; Shi, Z.; Su, D.; Wang, J.; Ma, D. ACS Catal. 2014, 4, 1261.
-
[26]
(26) Cao, Y. H.; Luo, X. Y.; Yu, H.; Peng, F.; Wang, H. J.; Ning, G. Q. Catal. Sci. Technol. 2013, 3, 2654. doi: 10.1039/c3cy00256j
-
[27]
(27) Dreyer, D. R.; Jia, H. P.; Bielawski, C. W. Angew. Chem. Int. Edit. 2010, 49, 6813.
-
[28]
(28) Boukhvalov, D. W.; Dreyer, D. R.; Bielawski, C. W.; Son, Y. W. ChemCatChem 2012, 4, 1844. doi: 10.1002/cctc.v4.11
-
[29]
(29) Su, C. L.; Acik, M.; Takai, K.; Lu, J.; Hao, S. J.; Zheng, Y.; Wu, P. P.; Bao, Q. L.; Enoki, T.; Chabal, Y. J.; Loh, K. P. Nat. Commun. 2012, 3, 1298. doi: 10.1038/ncomms2315
-
[30]
(30) Gao, Y. J.; Ma, D.; Wang, C. L.; Guan, J.; Bao, X. H. Chem. Commun. 2011, 47, 2432 doi: 10.1039/C0CC04420B
-
[31]
(31) Kong, X. K.; Sun, Z. K.; Chen, M.; Chen, C. L.; Chen, Q. W. Energy Environ. Sci. 2013, 6, 3260 doi: 10.1039/c3ee40918j
-
[32]
(32) Kong, X. K.; Chen, Q. W.; Lun, Z. Y. J. Mater. Chem. A 2014, 2, 610. doi: 10.1039/C3TA13946H
-
[33]
(33) Chauhan, S. M. S.; Mishra, S. Molecules 2011, 16, 7256. doi: 10.3390/molecules16097256
-
[34]
(34) Kim, Y.; Some, S.; Lee, H. Chem. Commun. 2013, 49, 5702. doi: 10.1039/c3cc42787k
-
[35]
(35) Verma, S.; Mungse, H. P.; Kumar, N.; Choudhary, S.; Jain, S. L.; Sain, B.; Khatri, O. P. Chem. Commun. 2011, 47, 12673. doi: 10.1039/c1cc15230k
-
[36]
(36) Yu, H.; Wang, X.; Zhu, Y.; Zhuang, G.; Zhong, X.; Wang, J. G. Chem. Phys. Lett. 2013, 583, 146. doi: 10.1016/j.cplett.2013.08.011
-
[37]
(37) Hu, F.; Patel, M.; Luo, F.; Flach, C.; Mendelsohn, R.; Garfunkel, E.; He, H.; Szostak, M. J. Am. Chem. Soc. 2015, 137, 14473. doi: 10.1021/jacs.5b09636
-
[38]
(38) Medina, J.; Aviles, F.; Tapia, A. Mol. Phys. 2015, 113, 1297. doi: 10.1080/00268976.2014.986241
-
[39]
(39) Wang, W.; Sun, T.; Zhang, Y.; Wang, Y. B. Comput. Theor. Chem. 2014, 1046, 64. doi: 10.1016/j.comptc.2014.07.017
-
[1]
-
-
[1]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[2]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
-
[3]
Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
-
[4]
Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
-
[5]
Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
-
[6]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[7]
Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
-
[8]
Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
-
[9]
Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
-
[10]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[11]
Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
-
[12]
Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu2O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
-
[13]
Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
-
[14]
Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
-
[15]
Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
-
[16]
Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
-
[17]
Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
-
[18]
Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO2-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
-
[19]
Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
-
[20]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(470)
- HTML views(47)