Citation: NING Yan-Xiao, FU Qiang, BAO Xin-He. Applications of PEEM/LEEM in Dynamic Studies of Surface Physics and Chemistry of Two-Dimensional Atomic Crystals[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 171-182. doi: 10.3866/PKU.WHXB201512152 shu

Applications of PEEM/LEEM in Dynamic Studies of Surface Physics and Chemistry of Two-Dimensional Atomic Crystals

1.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Corresponding author: FU Qiang, BAO Xin-He,
Received Date: 25 October 2015
Available Online: 14 December 2015
Fund Project: 国家自然科学基金(21573224,21222305,21373208,21321002) (21573224,21222305,21373208,21321002)国家科技部项目(2013CB933100,2013CB834603)资助 (2013CB933100,2013CB834603)

Photoemission electron microscopy (PEEM)/low energy electron microscopy (LEEM) are surface techniques that can be used to image surface structure, electronic states, and surface chemistry. Important applications of the technique in catalysis, energy, nano science, and material sciences have been seen. In this paper, we briefly introduce the principle of PEEM/LEEM and the recent advances of the technique. Then, some applications of PEEM/LEEM in dynamic studies of surface physics and chemistry of two-dimensional (2D) atomic crystals are highlighted, which include the growth of 2D atomic crystals, the formation of 2D heterostructures, the intercalation of the 2D materials, and chemical reactions confined under the 2D materials. Using surface imaging, micro-region low energy electron diffraction (μ-LEED), and the intensity-voltage (I-V) curves, the kinetics of 2D material growth and reactions at the 2D material/solid interfaces can be deeply understood.
- Photoemission electron microscopy,
- Low energy electron microscopy,
- Two-dimensional atomic crystal,
- Graphene,
- Interface reaction,
- Catalysis
1. [1]
  (1) Tromp, R. M.; Reuter, M. C. Ultramicroscopy 1991, 36 (1–3), 99. doi: 10.1016/0304-3991(91)90141-R
2. [2]
  (2) Engel, W.; Kordesch, M. E.; Rotermund, H. H.; Kubala, S.; von Oertzen, A. Ultramicroscopy 1991, 36 (1–3), 148. doi: 10.1016/0304-3991(91)90146-W
3. [3]
  (3) Bauer, E. Rep. Prog. Phys. 1994, 57 (9), 895. doi: 0034-4885/94/090895
4. [4]
  (4) Tromp, R. M. Ibm. J. Res. Develop. 2000, 44 (4), 503. doi: 10.1147/rd.444.0503
5. [5]
  (5) Ertl, G. Angew. Chem. Int. Edit. 2008, 47 (19), 3524. doi: 10.1002/anie.200800480
6. [6]
  (6) Imbihl, R. J. Electron. Spectrosc. Relat. Phenom. 2012, 185 (10), 347. doi: 10.1016/j.elspec.2012.05.001
7. [7]
  (7) Luer Ben, B.; Janek, J.; Gunther, S.; Kiskinova, M.; Imbihl, R. Phys. Chem. Chem. Phys. 2002, 4 (12), 2673. doi: 10.1039/B109893D
8. [8]
  (8) Luerβen, B.; Mutoro, E.; Fischer, H.; Günther, S.; Imbihl, R.; Janek, J. Angew. Chem. Int. Edit. 2006, 45 (9), 1473. doi: 10.1002/anie.200503708
9. [9]
  (9) Man, K. L.; Altman, M. S. J. Phys.: Condens. Matter 2012, 24 (31), 314209. doi: 10.1088/0953-8984/24/31/314209
10. [10]
  (10) Sutter, P.; Sutter, E. Adv. Funct. Mater. 2013, 23 (20), 2617. doi: 10.1002/adfm.201203426
11. [11]
  (11) Frazer, B. H.; Girasole, M.; Wiese, L. M.; Franz, T.; Stasio, G. D. Ultramicroscopy 2004, 99 (2–3), 87. doi: 10.1016/j.ultramic.2003.10.001
12. [12]
  (12) Fukidome, H.; Kotsugi, M.; Nagashio, K.; Sato, R.; Ohkochi, T.; Itoh, T.; Toriumi, A.; Suemitsu, M.; Kinoshita, T. Sci. Rep. 2014, 4, 3713. doi: 10.1038/srep03713
13. [13]
  (13) Xiong, G.; Shao, R.; Peppernick, S. J.; Joly, A. G.; Beck, K. M.; Hess, W. P.; Cai, M.; Duchene, J.; Wang, J. Y.; Wei, W. D. JOM 2010, 62 (12), 90. doi: 10.1007/s11837-010-0189-1
14. [14]
  (14) Günther, S.; Kaulich, B.; Gregoratti, L.; Kiskinova, M. Prog. Surf. Sci. 2002, 70 (4–8), 187. doi: 10.1016/S0079-6816(02)00007-2
15. [15]
  (15) Choi, J.; Wu, J.; Won, C.; Wu, Y. Z.; Scholl, A.; Doran, A.; Owens, T.; Qiu, Z. Q. Phys. Rev. Lett. 2007, 98 (20), 207205. doi: 10.1103/PhysRevLett.98.207205
16. [16]
  (16) Chung, W. F.; Altman, M. S. Ultramicroscopy 1998, 74 (4), 237. doi: 10.1016/S0304-3991(98)00043-6
17. [17]
  (17) Loginova, E.; Bartelt, N. C.; Feibelman, P. J.; McCarty, K. F. New J. Phys. 2009, 11 (6), 063046. doi: 10.1088/1367-2630/11/6/063046
18. [18]
  (18) Bauer, E. J. Electron. Spectrosc. Relat. Phenom. 2012, 185 (10), 314. doi: 10.1016/j.elspec.2012.08.001
19. [19]
  (19) Bauer, E. Ultramicroscopy 2012, 119, 18. doi: 10.1016/ j.ultramic.2011.09.006
20. [20]
  (20) Tromp, R. M.; Hannon, J. B.; Ellis, A. W.; Wan, W.; Berghaus, A.; Schaff, O. Ultramicroscopy 2010, 110 (7), 852. doi: 10.1016/j.ultramic.2010.03.005
21. [21]
  (21) Tromp, R. M.; Hannon, J. B.; Wan, W.; Berghaus, A.; Schaff, O. Ultramicroscopy 2013, 127, 25. doi: 10.1016/j.ultramic.2012.07.016
22. [22]
  (22) Cao, N.; Fu, Q.; Bao, X. H. Bulletin of Chinese Academy of Sciences 2012, 27 (1), 103. [曹凝, 傅强, 包信和. 中国科学院院刊, 2012, 27 (1), 103.]
23. [23]
  (23) Meyer zu Heringdorf, F. J.; Reuter, M.; Tromp, R. Nature 2001, 412 (6846), 517. doi: 10.1038/35087532
24. [24]
  (24) Schmid, A. K.; Bartelt, N. C.; Hwang, R. Q. Science 2000, 290 (5496). doi: 10.1126/science.290.5496.1561
25. [25]
  (25) Santos, B.; Loginova, E.; Mascaraque, A.; Schmid, A. K.; McCarty, K. F.; Figuera, J. D. L. J. Phys.: Condens. Matter 2009, 21 (31), 314011. doi: 10.1088/0953-8984/21/31/314011
26. [26]
  (26) Grinter, D. C.; Yim, C. M.; Pang, C. L.; Santos, B.; Menteş, T. O.; Locatelli, A.; Thornton, G. J. Phys. Chem. C 2013, 117 (32), 16509. doi: 10.1021/jp405887h
27. [27]
  (27) Qin, H.; Chen, X.; Li, l.; Sutter, P. W.; Zhou, G. Proc. Natl. Acad. Sci. 2015, 112 (2), E103. doi: 10.1073/pnas.1420690112
28. [28]
  (28) Wu, Q.; Zdyb, R.; Bauer, E.; Altman, M. S. Phys. Rev. B 2013, 87 (10), 104410. doi: 10.1103/PhysRevB.87.104410
29. [29]
  (29) Yang, Y.; Fu, Q.; Li, H.; Wei, M.; Xiao, J.; Wei, W.; Bao, X. ACS Nano 2015, 9 (12), 11589. doi: 10.1021/acsnano.5b05509
30. [30]
  (30) Yeh, P. C.; Jin, W.; Zaki, N.; Zhang, D.; Sadowski, J. T.; Al-Mahboob, A.; van der Zande, A. M.; Chenet, D. A.; Dadap, J. I.; Herman, I. P.; Sutter, P.; Hone, J.; Osgood, R. M. Phys. Rev. B 2014, 89 (15), 155408. doi: 10.1103/PhysRevB.89.155408
31. [31]
  (31) Kim, M.; Bertram, M.; Pollmann, M.; von Oertzen, A.; Mikhailov, A. S.; Rotermund, H. H.; Ertl, G. Science 2001, 292 (5520), 1357. doi: 10.1126/science.1059478
32. [32]
  (32) Cui, Y.; Fu, Q.; Bao, X. Phys. Chem. Chem. Phys. 2010, 12 (19), 5053. doi: 10.1039/C000719F
33. [33]
  (33) Yan, K.; Wu, D.; Peng, H.; Jin, L.; Fu, Q.; Bao, X.; Liu, Z. Nat. Commun. 2012, 3, 1280. doi: 10.1038/ncomms2286
34. [34]
  (34) Cui, Y.; Fu, Q.; Zhang, H.; Tan, D.; Bao, X. J. Phys. Chem. C 2009, 113 (47), 20365. doi: 10.1021/jp907949a
35. [35]
  (35) Gao, L.; Ren, W.; Xu, H.; Jin, L.; Wang, Z.; Ma, T.; Ma, L. P.; Zhang, Z.; Fu, Q.; Peng, L. M.; Bao, X.; Cheng, H. M. Nat. Commun. 2012, 3, 699. doi: 10.1038/ncomms1702
36. [36]
  (36) Liu, L.; Park, J.; Siegel, D. A.; McCarty, K. F.; Clark, K. W.; Deng, W.; Basile, L.; Idrobo, J. C.; Li, A. P.; Gu, G. Science 2014, 343 (6167), 163. doi: 10.1126/science.1246137
37. [37]
  (37) Hibino, H.; Kageshima, H.; Maeda, F.; Nagase, M.; Kobayashi, Y.; Yamaguchi, H. Phys. Rev. B 2008, 77 (7), 075413. doi: 10.1103/PhysRevB.77.075413
38. [38]
  (38) Sutter, P.; Sadowski, J. T.; Sutter, E. Phys. Rev. B 2009, 80 (24), 245411. doi: 10.1103/PhysRevB.80.245411
39. [39]
  (39) Geim, A. K. Science 2009, 324 (5934), 1530. doi: 10.1126/science.1158877
40. [40]
  (40) Sutter, P. W.; Flege, J. I.; Sutter, E. A. Nat Mater. 2008, 7 (5), 406. doi: 10.1038/nmat2166
41. [41]
  (41) Jin, L.; Fu, Q.; Zhang, H.; Mu, R.; Zhang, Y.; Tan, D.; Bao, X. J. Phys. Chem. C 2012, 116 (4), 2988. doi: 10.1021/jp210206y
42. [42]
  (42) Sutter, P.; Cortes, R.; Lahiri, J.; Sutter, E. Nano Lett. 2012, 12 (9), 4869. doi: 10.1021/nl302398m
43. [43]
  (43) Geim, A.; Grigorieva, I. Nature 2013, 499 (7459), 419. doi: 10.1038/nature12385
44. [44]
  (44) Jin, L.; Fu, Q.; Dong, A.; Ning, Y.; Wang, Z.; Bluhm, H.; Bao, X. J. Phys. Chem. C 2014, 118 (23), 12391. doi: 10.1021/jp5034855
45. [45]
  (45) Sutter, P.; Albrecht, P.; Tong, X.; Sutter, E. J. Phys. Chem. C 2013, 117 (12), 6320. doi: 10.1021/jp400838j
46. [46]
  (46) Mu, R.; Fu, Q.; Jin, L.; Yu, L.; Fang, G.; Tan, D.; Bao, X. Angew. Chem. Int. Edit. 2012, 51 (20), 4856. doi: 10.1002/anie.201200413
47. [47]
  (47) Zhang, Y.; Weng, X.; Li, H.; Li, H.; Wei, M.; Xiao, J.; Liu, Z.; Chen, M.; Fu, Q.; Bao, X. Nano Lett. 2015, 15 (5), 3616. doi: 10.1021/acs.nanolett.5b01205
48. [48]
  (48) Zhang, Y.; Wei, M.; Fu, Q.; Bao, X. Sci. Bull. 2015, 60 (18), 1572. doi: 10.1007/s11434-015-0875-z
49. [49]
  (49) Du, Z.; Sarofim, A. F.; Longwell, J. P.; Mims, C. A. Energ. Fuel 1991, 5 (1), 214. doi: 10.1021/ef00025a035
50. [50]
  (50) Hahn, J. R.; Kang, H.; Lee, S. M.; Lee, Y. H. J. Phys. Chem. B 1999, 103 (45), 9944. doi: 10.1021/jp9920895
51. [51]
  (51) Starodub, E.; Bartelt, N. C.; McCarty, K. F. J. Phys. Chem. C 2010, 114 (11), 5134. doi: 10.1021/jp912139e
52. [52]
  (52) Sutter, P.; Sadowski, J. T.; Sutter, E. A. J. Am. Chem. Soc. 2010, 132 (23), 8175. doi: 10.1021/ja102398n
53. [53]
  (53) Yao, Y. X.; Fu, Q.; Zhang, Y. Y.; Weng, X. F.; Li, H.; Chen, M. S.; Jin, L.; Dong, A. Y.; Mu, R. T.; Jiang, P.; Liu, L.; Bluhm, H.; Liu, Z.; Zhang, S. B.; Bao, X. H. Proc. Natl. Acad. Sci. U. S. A. 2014, 111 (48), 17023. doi: 10.1073/pnas.1416368111
54. [54]
  (54) Hrelescu, C.; Sau, T. K.; Rogach, A. L.; Jäckel, F.; Laurent, G.; Douillard, L.; Charra, F. Nano Lett. 2011, 11 (2), 402. doi: 10.1021/nl103007m
55. [55]
  (55) Douillard, L.; Charra, F. J. Electron. Spectrosc. Relat. Phenom. 2013, 189 (Supplement), 24. doi: 10.1016/j.elspec.2013.03.013
56. [56]
  (56) Mutoro, E.; Hellwig, C.; Luerssen, B.; Guenther, S.; Bessler, W. G.; Janek, J. Phys. Chem. Chem. Phys. 2011, 13 (28), 12798.
  doi: 10.1039/C1CP20361D
57. [57]
  (57) Schmidt, T.; Groh, U.; Fink, R.; Umbach, E.; Schaff, O.; Engel, W.; Richter, B.; Kuhlenbeck, H.; Schlogl, R.; Freund, H. J.; Bradshaw, A. M.; Preikszas, D.; Hartel, P.; Spehr, R.; Rose, H.; Lilienkamp, G.; Bauer, E.; Benner, G. Surf. Rev. Lett. 2002, 9 (1), 223. doi: 10.1142/S0218625X02001811
58. [58]
  (58) Guo, F. Z.; Wakita, T.; Shimizu, H.; Matsushita, T.; Yasue, T.; Koshikawa, T.; Bauer, E.; Kobayashi, K. J. Phys.: Condens. Matter 2005, 17 (16), S1363. doi: 10.1088/0953-8984/17/16/007
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