Citation: ZHAO Sheng-Jun, ZHANG Wei, DENG Hui-Ning, LIU Wei. Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 723-727. doi: 10.3866/PKU.WHXB201512141 shu

Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China;
2.
2 School of Marine Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

Corresponding author: DENG Hui-Ning,
Received Date: 28 September 2015
Available Online: 8 December 2015
Fund Project: 国家自然科学基金(20906017) (20906017)河北省自然科学基金(B2013202087,D2014202074) (B2013202087,D2014202074)天津市应用基础与前沿技术研究重点项目(14JCZDJC38900)资助 (14JCZDJC38900)

Graphene oxide (GO) composite membranes were fabricated via layer-by-layer (LBL) assembling poly(ethylenimine) (PEI) and a mixture of GO and poly(acrylic acid) (PAA) on a poly(acrylonitrile) (PAN) support membrane. The composite membranes and their application performance were characterized and evaluated. The X-ray powder diffraction (XRD) spectrum shows that GO was successfully synthesized by the modified Hummers method, and it was homogenously dispersed in the composite membranes. Scanning electron microscopy (SEM) shows the successful assembly of multiple polyelectrolyte PEI and a mixture of GO and PAA bilayers on the PAN support membrane. The ultraviolet-visible (UV-Vis) spectrum indicates that the uniformity and continuity of the composite membrane were enhanced with the increasing number of assembled layers. The hydrophilic and selectivity tests reveals that the addition of GO decreased the water contact angle and enhanced the selectivity for monovalent cations of the multilayer polyelectrolyte composite membranes. All these advantages combine to fabricate a high-flux, high selectivity, and anti-fouling composite membrane for separation applications and water softening.
- Multilayer structure,
- Layer-by-layer assembly,
- Deposition,
- Graphene oxide,
- Selectivity
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