Citation: ZHAO Sheng-Jun, ZHANG Wei, DENG Hui-Ning, LIU Wei. Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 723-727. doi: 10.3866/PKU.WHXB201512141 shu

Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China;
2.
2 School of Marine Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

Corresponding author: DENG Hui-Ning,
Received Date: 28 September 2015
Available Online: 8 December 2015
Fund Project: 国家自然科学基金(20906017) (20906017)河北省自然科学基金(B2013202087,D2014202074) (B2013202087,D2014202074)天津市应用基础与前沿技术研究重点项目(14JCZDJC38900)资助 (14JCZDJC38900)

Graphene oxide (GO) composite membranes were fabricated via layer-by-layer (LBL) assembling poly(ethylenimine) (PEI) and a mixture of GO and poly(acrylic acid) (PAA) on a poly(acrylonitrile) (PAN) support membrane. The composite membranes and their application performance were characterized and evaluated. The X-ray powder diffraction (XRD) spectrum shows that GO was successfully synthesized by the modified Hummers method, and it was homogenously dispersed in the composite membranes. Scanning electron microscopy (SEM) shows the successful assembly of multiple polyelectrolyte PEI and a mixture of GO and PAA bilayers on the PAN support membrane. The ultraviolet-visible (UV-Vis) spectrum indicates that the uniformity and continuity of the composite membrane were enhanced with the increasing number of assembled layers. The hydrophilic and selectivity tests reveals that the addition of GO decreased the water contact angle and enhanced the selectivity for monovalent cations of the multilayer polyelectrolyte composite membranes. All these advantages combine to fabricate a high-flux, high selectivity, and anti-fouling composite membrane for separation applications and water softening.
- Multilayer structure,
- Layer-by-layer assembly,
- Deposition,
- Graphene oxide,
- Selectivity
1. [1]
  (1) Xu, Y. X.; Hong, W. J.; Bai, H.; Li, C.; Shi, G. Q. Carbon2009, 47, 3538. doi: 10.1016/j.carbon.2009.08.022
2. [2]
  (2) Lee, D. C.; Yang, H. N.; Park, S. H.; Kim, W. J. J. Membr. Sci.2014, 452, 20. doi: 10.1016/j.memsci.2013.10.018
3. [3]
  (3) Cao, C. H.; Daly, M.; Singh, C. V.; Sun, Y.; Filleter, T. Carbon2015, 81, 497. doi: 10.1016/j.carbon.2014.09.082
4. [4]
  (4) Liang, L.; Lu, Y.; Yao, W. S.; Zhang, X. T. Acta Phys. -Chim. Sin. 2015, 31, 1180. [梁祎, 卢赟, 姚维尚, 张学同. 物理化学学报, 2015, 31, 1180.] doi: 10.3866/PKU.WHXB201504146
5. [5]
  (5) Ji, T. H.; Sun, M.; Zou, L. F.; Ma, N. Mater. Lett. 2014, 120, 30. doi: 10.1016/j.matlet.2014.01.035
6. [6]
  (6) Dreyer, D. R.; Park, S. J.; Bielawski, C.W.; Ruoff, R. S.Chem. Soc. Rev. 2010, 39, 228. doi: 10.1039/B917103G
7. [7]
  (7) Nair, R. R.; Wu, H. A.; Jayaram, P. N.; Grigorieva, I. V.; Geim, A. K. Science 2012, 335, 442. doi: 10.1126/science.1211694
8. [8]
  (8) Mi, B. X. Science 2014, 343, 740. doi: 10.1126/science.1250247
9. [9]
  (9) Valentini, L. Mater. Lett. 2015, 157, 266. doi: 10.1016/j.matlet.2015.05.23
10. [10]
  (10) Li, W. Y.; He, Y. Q.; Li, Y. M. Acta Phys. -Chim. Sin. 2015, 31, 458. [李文有, 贺蕴秋, 李一鸣. 物理化学学报, 2015, 31, 458.] doi: 10.3866/PKU.WHXB201501093
11. [11]
  (11) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.; Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R.S. Nature 2007, 448, 458. doi: 10.1038/nature06016
12. [12]
  (12) Rajasekar, R.; Kim, N. H.; Jung, D.; Kuila, T.; Lim, J. K.; Park, M. J.; Lee, J. H. Compos. Sci. Technol. 2013, 89, 171. doi: 10.1016/j.compscitech.2013.10.004
13. [13]
  (13) Hu, M.; Mi, B. X. J. Membr. Sci. 2014, 469, 80. doi: 10.1016/j.memsci.2014.06.036
14. [14]
  (14) Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
15. [15]
  (15) Wang, J. D.; Peng, T. J.; Xian, H. Y.; Sun, H. J. Acta Phys. -Chim. Sin. 2015, 31, 91. [汪建德, 彭同江, 鲜海洋, 孙红娟. 物理化学学报, 2015, 31, 91.] doi: 10.3866/PKU.WHXB201411202
16. [16]
  (16) Goh, K. L.; Setiawan, L.; Wei, L.; Si, R. M.; Fane, A. G.; Wang, R.; Chen, Y. J. Membr. Sci. 2015, 474, 245. doi: 10.1016/j.memsci.2014.09.057
17. [17]
  (17) Zhou, T. N.; Chen, F.; Tang, C. Y.; Bai, H.W.; Zhang, Q.; Deng, H.; Fu, Q. Compos. Sci. Technol. 2011, 71, 1267. doi: 10.1016/j.compscitech.2011.04.016
18. [18]
  (18) Suresh, D.; Udayabhanu; Kumar, M. A. P.; Nagabhushana, H.; Sharma, S. C. Mater. Lett. 2015, 151, 93. doi: 10.1016/j.matlet.2015.03.035
19. [19]
  (19) Zhang, G. J.; Yan, H. H.; Ji, S. L.; Liu, Z. Z. J. Membr. Sci.2007, 292, 2. doi: 10.1016/j.memsci.2006.11.023
20. [20]
  (20) Wang, N. X.; Ji, S. L.; Zhang, G. J.; Li, J.; Wang, L. Chem. Eng. Technol. 2012, 213, 321. doi: 10.1016/j.cej.2012.09.080
21. [21]
  (21) Wang, X.; Guo, X. Y.; Shao, H. Q.; Zhou, Q. X.; Hu, W. L.; Song, X. J. Prog. Chem. 2015, 27, 1475. [王茜, 郭晓燕, 邵怀启, 周启星, 胡万里, 宋晓静. 化学进展, 2015, 27, 1475.] doi: 10.7536/PC150321
22. [22]
  (22) Schniepp, H. C.; Li, J. L.; McAllister, M. J.; Sai, H.; Herrera-Alonso, M.; Adamson, D. H.; Prud'homme, R. K.; Car, R.; Saville, D. A.; Aksay, I. A. J. Phys. Chem. 2006, 110, 8537. doi: 10.1021/jp060936f
23. [23]
  (23) Zhang, J. G.; Xu, Z.W.; Shan, M. J.; Zhou, B. M.; Li, Y. L.; Li, B. D.; Niu, J. R.; Qian, X. M. J. Membr. Sci. 2013, 448, 91. doi: 10.1016/j.memsci.2013.07.064
24. [24]
  (24) Ben Ameur, S.; Barhoumi, A.; Mimouni, R.; Amlouk, M.; Guermazi, H. Superlattice. Microst. 2015, 84, 110. doi: 10.1016/j.spmi.2015.04.028
25. [25]
  (25) Marmur, A. Langmuir 2004, 20, 3519. doi: 10.1021/la036369u
26. [26]
  (26) Malaisamy, R.; Talla-Nwafo, A.; Jones, K. L. Sep. Purif. Technol. 2011, 77, 370. doi: 10.1016/j.seppur.2011.01.005
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
3. [3]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
4. [4]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
5. [5]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
6. [6]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
7. [7]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
8. [8]
  Wenjian Zhang , Mengxin Fan , Wenwen Fei , Wei Bai . Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly. University Chemistry, 2025, 40(4): 108-112. doi: 10.12461/PKU.DXHX202406099
9. [9]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
10. [10]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
11. [11]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
12. [12]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
13. [13]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
14. [14]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
15. [15]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
16. [16]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
17. [17]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
18. [18]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
19. [19]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
20. [20]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(525)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142