Citation: WANG Li, SHI Hong, LIU Hui-Hui, SHAO Xiang, WU Kai. STM Study of CaO(001) Model Catalytic Thin Films Prepared on Mo(001) Surface[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 183-194. doi: 10.3866/PKU.WHXB201512113 shu

STM Study of CaO(001) Model Catalytic Thin Films Prepared on Mo(001) Surface

WANG Li ¹ ,
SHI Hong ¹ ,
LIU Hui-Hui ¹ ,
SHAO Xiang ^1,, ,
WU Kai ^2,,

1.
1 Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China;
2.
2 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Corresponding author: SHAO Xiang, WU Kai,
Received Date: 15 October 2015
Available Online: 11 December 2015
Fund Project: 国家自然科学基金(21333001) (21333001)国家重点基础研究发展规划项目(973)(2014CB932700) (973)(2014CB932700)

Single crystalline oxide thin film has been delegated as an important approach to studying oxide materials. The related researches are at the frontier of model catalysis. In this review, we try to summarize what has been researched so far around the CaO(001) films, which have been recently developed in Prof. Hajo Freund's group at the Fritz-Haber Institute. The revealed properties of CaO films have displayed the common characteristics of supported ultrathin oxide films, which are sensitively dependent on the interface structures and film thicknesses, but they have also shown new aspects such as the novel tuning effects from self-doping by substrate ions. Low-temperature scanning tunneling microscopy (LT-STM) has been applied through all detailed studies, including the characterizations of atomic structure and electronic properties, recognition of various defects and charge analyses of various surface species. The microscopic information received from delicate STM measurements provides atomic views of the effective factors involved in manipulating the oxide surface properties. With the aid of theoretical calculations, deep insights of the doping mechanism and selection principles of the dopants are achieved, which should largely assist the design of new catalysts.
- CaO,
- Thin film,
- Model catalyst,
- STM,
- Surface chemistry
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