Citation: CHEN Fang, CHEN Zhu-Guo, SUN Hui-Zhao, MENG Fan-Xiang, MA Xiao-Yan. Anion Effect on the Tunable Stability of a Thermoresponsive Pickering Emulsion Based on SiO₂-PNIPAM[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 763-770. doi: 10.3866/PKU.WHXB201512111 shu

Anion Effect on the Tunable Stability of a Thermoresponsive Pickering Emulsion Based on SiO₂-PNIPAM

1.
The Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, The Key Laboratory of Polymer Science and Technology of Shaanxi Province, School of Science, Northwestern Polytechnical University, Xi'an 710129, P. R. China

Corresponding author: CHEN Fang, MA Xiao-Yan,
Received Date: 30 September 2015
Available Online: 9 December 2015
Fund Project: 国家自然科学基金(51103117) (51103117)陕西省自然科学基金(2013JQ2010,2013/M2012) (2013JQ2010,2013/M2012)西北工业大学基础研究基金(3102014JCQ01089)资助项目 (3102014JCQ01089)

Thermoresponsive hybrid particles of SiO₂-PNIPAM (PNIPAM: poly(N-isopropyl acrylamide) were synthesized by surface initiated atom transfer radical polymerization (SI-ATRP). The structure of hybrid particles was characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The grafting ratio of PNIPAM on the silica surface was about 103.7%as measured by thermogravimetric analysis (TGA). The thermoresponsive behavior of monodisperse hybrid particles was analyzed by dynamic light scattering (DLS), and its lower critical solution temperature (LCST) is 30 ℃. The influence of anions on the wettability of hybrid particles was studied by measuring the surface contact angle. A large stability difference of the emulsion based on SiO₂-PNIPAM exists between 40 and 10 ℃. The degree of flocculation of hybrid particles shows a significant influence on the stability of the emulsion. The emulsion stability is dependent on the electrostatic interaction and salting out caused by the solvation effect. This stability is tunable by introducing different anions at different concentrations.
- Hybrid particle,
- Temperature responsive,
- Anion,
- Pickering emulsion,
- Flocculation
1. [1]
  (1) Pickering, S. U. Journal of the Chemical Society, Transactions1907, 91, 2001. doi: 10.1039/ct9079102001
2. [2]
  (2) Binks, B.; Lumsdon, S. Langmuir 2000, 16, 8622. doi: 10.1021/la000189s
3. [3]
  (3) Binks, B.; Lumsdon, S. Langmuir 2001, 17, 4540. doi: 10.1021/la0103822
4. [4]
  (4) Binks, B. P.; Isa, L.; Tyowua, A. T. Langmuir 2013, 29, 4923. doi: 10.1021/la4006899
5. [5]
  (5) Binks, B. P.; Clint, J. H. Langmuir 2002, 18, 1270. doi: 10.1021/la011420k
6. [6]
  (6) Tang, J.; Quinlan, P. J.; Tam, K. C. Soft Matter 2015, 11, 3512. doi: 10.1039/C5SM00247H
7. [7]
  (7) Li, J.; Stöver, H. D. Langmuir 2008, 24, 13237. doi: 10.1021/la802619m
8. [8]
  (8) Wei, Z.; Yang, Y.; Yang, R.; Wang, C. Green Chem. 2012, 14, 3230. doi: 10.1039/c2gc36278c
9. [9]
  (9) Lan, Q.; Liu, C.; Yang, F.; Liu, S.; Xu, J.; Sun, D. J. Colloid Interface Sci. 2007, 310, 260. doi: 10.1016/j.jcis.2007.01.081
10. [10]
  (10) Saigal, T.; Dong, H.; Matyjaszewski, K.; Tilton, R. D.Langmuir 2010, 26, 15200. doi: 10.1021/la1027898
11. [11]
  (11) Tsuji, S.; Kawaguchi, H. Langmuir 2008, 24, 3300. doi: 10.1021/la701780g
12. [12]
  (12) Brugger, B.; Richtering, W. Adv. Mater. 2007, 19, 2973. doi: 10.1002/adma.200700487
13. [13]
  (13) Yi, C.; Liu, N.; Zheng, J.; Jiang, J.; Liu, X. J. Colloid Interface Sci. 2012, 380, 90. doi: 10.1016/j.jcis.2012.04.067
14. [14]
  (14) Tai, X.; Ma, J. H.; Du, Z.; Wang, W.; Wu, J. Powder Technol.2013, 233, 47. doi: 10.1016/j.powtec.2012.08.026
15. [15]
  (15) Wang, H. L.; Shi, T. J.; Zhai, L. F. Polymer Materials Science and Engineering 2005, 21, 250. [王华林, 史铁钧, 翟林峰. 高分子材料科学与工程, 2005, 21, 250.] doi: 10.3321/j.issn: 1000-7555.2005.03.063
16. [16]
  (16) Wu, T.; Zhang, Y.; Wang, X.; Liu, S. Chem. Mater. 2007, 20, 101. doi: 10.1021/cm702073f
17. [17]
  (17) Wang, H.; Zhong, W.; Du, Q.; Yang, Y.; Okamoto, H.; Inoue, S. Polym. Bull. 2003, 51, 63. doi: 10.1007/s00289-003-0188-2
18. [18]
  (18) Wang, Z. Y.; Liu, H.; Liu, H. X.; Gao, Q. X.; Chen, Y. H.; Li, Y.; Tong, Z. Science China Chemistry 2011, 41, 195. [王朝阳, 刘浩, 刘红霞, 高权星, 陈云华, 李煜, 童真. 中国科学: 化学(中文版), 2011, 41, 195.] doi: 10.1360/032010-705
19. [19]
  (19) Fu, H.; Hong, X.; Wan, A.; Batteas, J. D.; Bergbreiter, D. E.ACS Applied Materials & Interfaces 2010, 2, 452. doi: 10.1021/am9007006
20. [20]
  (20) Liao, K. S.; Fu, H.; Wan, A.; Batteas, J. D.; Bergbreiter, D. E.Langmuir 2008, 25, 26. doi: 10.1021/la803176d
21. [21]
  (21) Stöber, W.; Fink, A.; Bohn, E. J. Colloid Interface Sci. 1968, 26, 62. doi: 10.1016/0021-9797(68)90272-5
22. [22]
  (22) Tsubokawa, N.; Ichioka, H.; Satoh, T.; Hayashi, S.; Fujiki, K.Reactive and Functional Polymers 1998, 37, 75. doi: 10.1016/S1381-5148(97)00139-9
23. [23]
  (23) Afroze, F.; Nies, E.; Berghmans, H. J. Mol. Struct. 2000, 554, 55. doi: 10.1016/S0022-2860(00)00559-7
24. [24]
  (24) Yang, F.; Liu, S.; Xu, J.; Lan, Q.; Wei, F.; Sun, D. J. Colloid Interface Sci. 2006, 302, 159. doi: 10.1016/j.jcis.2006.06.015
25. [25]
  (25) Liu, G. P.; Wang, J.; Li, W.; Liu, S. Y.; Sun, D. J. Chemical Journal of Chinese Universities 2013, 34, 386. [刘国鹏, 王君, 李伟, 刘尚营, 孙德军. 高等学校化学学报, 2013, 34, 386.] doi: 10.7503/cjcu20120411
26. [26]
  (26) Zhang, Y.; Furyk, S.; Bergbreiter, D. E.; Cremer, P. S. J. Am. Chem. Soc. 2005, 127, 14505. doi: 10.1021/ja0546424
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Anion Effect on the Tunable Stability of a Thermoresponsive Pickering Emulsion Based on SiO2-PNIPAM

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通讯作者: 陈斌, bchen63@163.com

Anion Effect on the Tunable Stability of a Thermoresponsive Pickering Emulsion Based on SiO₂-PNIPAM