Citation: GUO Qing, ZHOU Chuan-Yao, MA Zhi-Bo, REN Ze-Feng, FAN Hong-Jun, YANG Xue-Ming. Fundamental Processes in Surface Photocatalysis on TiO₂[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 28-47. doi: 10.3866/PKU.WHXB201512081 shu

Fundamental Processes in Surface Photocatalysis on TiO₂

1.
1 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China;
2.
2 International Center for Quantum Materials and School of Physics, Peking University, Beijing 100871, P. R. China

Corresponding author: YANG Xue-Ming,
Received Date: 6 November 2015
Available Online: 8 December 2015
Fund Project: 国家自然科学基金(21203189,21321091,21173212,21403224,21573225,21322310) (21203189,21321091,21173212,21403224,21573225,21322310)国家重点基础研究发展规划项目(973)(2013CB834605) (973)(2013CB834605)中国科学院重点部署项目(KGZD-EW-T05)以及分子反应动力学国家重点实验室开放课题(ZZ-2014-02)资助 (KGZD-EW-T05)以及分子反应动力学国家重点实验室开放课题(ZZ-2014-02)

Because of the potential applications of TiO₂ in photocatalytic hydrogen production and pollutant degradation, over the past few decades we have witnessed increasing interest in and effort toward developing TiO₂-based photocatalysts, and improving the efficiency and exploring the reaction mechanisms at the atomic and molecular levels. Because surface science studies on single crystal surfaces under ultrahigh vacuum (UHV) conditions can provide fundamental insights into these important processes, both the thermo- and photo-chemistry on TiO₂, especially on rutile TiO₂(110) surfaces, have been extensively investigated with a variety of experimental and theoretical approaches. In this review, commencing with the properties of TiO₂, we then focus on charge transport and trapping, and electron transfer dynamics. Next, we summarize recent progress made in the study of elementary photocatalytic chemistry of methanol on mainly rutile TiO₂(110), as well as in some studies on rutile TiO₂(011) and anatase TiO₂(101). These studies have provided fundamental insights into surface photocatalysis and stimulated new investigations in this exciting area. The implications of these studies for the development of new photocatalysis models are also discussed.
- Titanium dioxide,
- Photocatalysis,
- Electron-hole separation,
- Nonadiabatic process,
- Ground-state potential energy surface
1. [1]
  (1) Schneider, J.; Matsuoka, M.; Takeuchi, M.; Zhang, J.; Horiuchi, Y.; Anpo, M.; Bahnemann, D. W. Chem. Rev. 2014, 114, 9919. doi: 10.1021/cr5001892
2. [2]
  (2) Fujishima, A.; Zhang, X.; Tryk, D. A. Surf. Sci. Rep. 2008, 63, 515. doi: 10.1016/j.surfrep.2008.10.001
3. [3]
  (3) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
4. [4]
  (4) Nakata, K.; Fujishima, A. J. Photochem. Photobiol. C: Photochem. Rev. 2012, 13, 169. doi: 10.1016/j.jphotochemrev.2012.06.001
5. [5]
  (5) Ma, Y.; Wang, X.; Jia, Y.; Chen, X.; Han, H.; Li, C. Chem. Rev. 2014, 114, 9987. doi: 10.1021/cr500008u
6. [6]
  (6) Dambournet, D.; Belharouak, I.; Amine, K. Chem. Mater. 2010, 22, 1173. doi: 10.1021/cm902613h
7. [7]
  (7) Nosheen, S.; Galasso, F. S.; Suib, S. L. Langmuir 2009, 25, 7623. doi: 10.1021/la9002719
8. [8]
  (8) Diebold, U. Surf. Sci. Rep. 2003, 48, 53. doi: 10.1016/S0167-572900100-0
9. [9]
  (9) Zhang, J.; Li, M. J.; Feng, Z. C.; Chen, J.; Li, C. J. Phys. Chem. B 2006, 110, 927. doi: 10.1021/jp0552473
10. [10]
  (10) Su, W. G.; Zhang, J.; Feng, Z. C.; Chen, T.; Ying, P. L.; Li, C. J. Phys. Chem. C 2008, 112, 7710. doi: 10.1021/jp7118422
11. [11]
  (11) Shi, J. Y.; Chen, J.; Feng, Z. C.; Chen, T.; Lian, Y. X.; Wang, X. L.; Li, C. J. Phys. Chem. C 2007, 111, 693. doi: 10.1021/jp065744z
12. [12]
  (12) Zhang, J.; Xu, Q.; Li, M. J.; Feng, Z. C.; Li, C. J. Phys. Chem. C 2009, 113, 1698. doi: 10.1021/jp808013k
13. [13]
  (13) Xu, Q. A.; Zhang, J.; Feng, Z. C.; Ma, Y.; Wang, X.; Li, C. Chem. -Asian J. 2010, 5, 2158. doi: 10.1002/asia.201000249
14. [14]
  (14) Zhang, H. Z.; Banfield, J. F. J. Phys. Chem. B 2000, 104, 3481.
15. [15]
  (15) Yang, H. G.; Sun, C. H.; Qiao, S. Z.; Zou, J.; Liu, G.; Smith, S. C.; Cheng, H. M.; Lu, G. Q. Nature. 2008, 453, 638. doi: 10.1038/nature06964
16. [16]
  (16) He, Y.; Dulub, O.; Cheng, H.; Selloni, A.; Diebold, U. Phys. Rev. Lett. 2009, 102, 106105. doi: 10.1103/PhysRevLett.102.106105
17. [17]
  (17) Liang, Y.; Gan, S.; Chambers, S. A.; Eltman, E. I. Phys. Rev. B 2001, 63, 235402. doi: 10.1103/PhysRevB.63.235402
18. [18]
  (18) Tachibana, Y.; Vayssieres, L.; Durrant, J. R. Nat. Photonics. 2012, 6, 511. doi: 10.1038/nphoton.2012.175
19. [19]
  (19) Kapilashrami, M.; Zhang, Y.; Liu, Y. S.; Hagfeldt, A.; Guo, J. Chem. Rev. 2014, 114, 9662. doi: 10.1021/cr5000893
20. [20]
  (20) Asahi, R.; Taga, Y.; Mannstadt, W.; Freeman, A. J. Phys. Rev. B 2000, 61, 7459. doi: 10.1103/PhysRevB.61.7459
21. [21]
  (21) van de Krol, R.; Grätzel, M. Photoelectrochemical Hydrogen Production; Springer: Heidelberg, 2012; p 16.
22. [22]
  (22) Henderson, M. A. Surf. Sci. Rep. 2011, 66, 185. doi: 10.1016/j.surfrep.2011.01.001
23. [23]
  (23) Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann, D. W. Chem. Rev. 1995, 95, 69. doi: 10.1021/cr00033a004
24. [24]
  (24) Berger, T.; Sterrer, M.; Diwald, O.; Knozinger, E. ChemPhysChem 2005, 6, 2104.
25. [25]
  (25) Gundlach, L.; Felber, S.; Storck, W.; Galoppini, E.; Wei, Q.; Willig, F. Res. Chem. Intermed. 2005, 31, 39. doi: 10.1163/1568567053146841
26. [26]
  (26) Gundlach, L.; Ernstorfer, R.; Willig, F. Phys. Rev. B 2006, 74, 035324. doi: 10.1103/PhysRevB.74.035324
27. [27]
  (27) Nilius, N.; Ernst, N.; Freund, H. J. Chem. Phys. Lett. 2001, 349, 351. doi: 10.1016/S0009-261401232-5
28. [28]
  (28) Yamada, Y.; Kanemitsu, Y. Phys. Rev. B 2010, 82, 113103. doi: 10.1103/PhysRevB.82.113103
29. [29]
  (29) Yamada, Y.; Kanemitsu, Y. Phys. Status. Solidi. C 2011, 8, 104. doi: 10.1002/pssc.201000642
30. [30]
  (30) Sporleder, D.; Wilson, D. P.; White, M. G. J. Phys. Chem. C 2009, 113, 13180. doi: 10.1021/jp901065j
31. [31]
  (31) Diwald, O.; Thompson, T. L.; Goralski, E. G.; Walck, S. D.; Yates, J. T., Jr. J. Phys. Chem. B 2004, 108, 52. doi: 10.1021/jp030529t
32. [32]
  (32) Turner, G. M.; Beard, M. C.; Schmuttenmaer, C. A. J. Phys. Chem. B 2002, 106, 11716. doi: 10.1021/jp025844e
33. [33]
  (33) Grela, M. A.; Brusa, M. A.; Colussi, A. J. J. Phys. Chem. B 1997, 101, 10986. doi: 10.1021/jp972172x
34. [34]
  (34) Grela, M. A.; Colussi, A. J. J. Phys. Chem. B 1999, 103, 2614. doi: 10.1021/jp9829492
35. [35]
  (35) Grela, M. A.; Brusa, M. A.; Colussi, A. J. J. Phys. Chem. B 1999, 103, 6400. doi: 10.1021/jp990952v
36. [36]
  (36) Morishita, T.; Hibara, A.; Sawada, T.; Tsuyumoto, I. J. Phys. Chem. B 1999, 103, 5984. doi: 10.1021/jp984729u
37. [37]
  (37) Bahnemann, D. W.; Hilgendorff, M.; Memming, R. J. Phys. Chem. B 1997, 101, 4265. doi: 10.1021/jp9639915
38. [38]
  (38) Yoshihara, T.; Katoh, R.; Furube, A.; Tamaki, Y.; Murai, M.; Hara, K.; Murata, S.; Arakawa, H.; Tachiya, M. J. Phys. Chem. B 2004, 108, 3817.
39. [39]
  (39) Tamaki, Y.; Furube, A.; Murai, M.; Hara, K.; Katoh, R.; Tachiya, M. J. Am. Chem. Soc. 2006, 128, 416. doi: 10.1021/ja055866p
40. [40]
  (40) Tamaki, Y.; Furube, A.; Murai, M.; Hara, K.; Katoh, R.; Tachiya, M. Phys. Chem. Chem. Phys. 2007, 9, 1453. doi: 10.1039/b617552j
41. [41]
  (41) Nakaoka, Y.; Nosaka, Y. J. Photochem. Photobiol. A 1997, 110, 299. doi: 10.1016/S1010-603000208-6
42. [42]
  (42) Jenkins, C. A.; Murphy, D. M. J. Phys. Chem. B 1999, 103, 101.
43. [43]
  (43) Ganduglia-Pirovano, M. V.; Hofmann, A.; Sauer, J. Surf. Sci. Rep. 2007, 62, 219. doi: 10.1016/j.surfrep.2007.03.002
44. [44]
  (44) Kowalski, P. M.; Camellone, M. F.; Nair, N. N.; Meyer, B.; Marx, D. Phys. Rev. Lett. 2010, 105, 146405. doi: 10.1103/PhysRevLett.105.146405
45. [45]
  (45) Qu, Z. W.; Kroes, G. J. J. Phys. Chem. B 2006, 110, 8998. doi: 10.1021/jp056607p
46. [46]
  (46) Miyagi, T.; Kamei, M.; Mitsuhashi, T.; Ishigaki, T.; Yamazaki, A. Chem. Phys. Lett. 2004, 390, 399. doi: 10.1016/j.cplett.2004.04.042
47. [47]
  (47) Kamei, M.; Miyagi, T.; Ishigaki, T. Chem. Phys. Lett. 2005, 407, 209. doi: 10.1016/j.cplett.2005.03.075
48. [48]
  (48) Planelles, J.; Movilla, J. L. Phys. Rev. B 2006, 73, 235350. doi: 10.1103/PhysRevB.73.235350
49. [49]
  (49) Deskins, N. A.; Dupuis, M. Phys. Rev. B 2007, 75, 195212. doi: 10.1103/PhysRevB.75.195212
50. [50]
  (50) Agrell, H. G.; Boschloo, G.; Hagfeldt, A. J. Phys. Chem. B 2004, 108, 12388. doi: 10.1021/jp037119p
51. [51]
  (51) Mora-Sero, I.; Bisquert, J. Nano Lett. 2003, 3, 945. doi: 10.1021/nl0342390
52. [52]
  (52) Barzykin, A. V.; Tachiya, M. J. Phys. Chem. B 2002, 106, 4356. doi: 10.1021/jp012957+
53. [53]
  (53) Shkrob, I. A.; Sauer, M. C. J. Phys. Chem. B 2004, 108, 12497. doi: 10.1021/jp047736t
54. [54]
  (54) Beermann, N.; Boschloo, G.; Hagfeldt, A. J. Photochem. Photobiol. A 2002, 152, 213. doi: 10.1016/S1010-603000236-8
55. [55]
  (55) van de Lagemaat, J.; Frank, A. J. J. Phys. Chem. B 2001, 105, 11194. doi: 10.1021/jp0118468
56. [56]
  (56) Komaguchi, K.; Nakano, H.; Araki, A.; Harima, Y. Chem. Phys. Lett. 2006, 428, 338. doi: 10.1016/j.cplett.2006.07.003
57. [57]
  (57) Peiro, A. M.; Colombo, C.; Doyle, G.; Nelson, J.; Mills, A.; Durrant, J. R. J. Phys. Chem. B 2006, 110, 23255. doi: 10.1021/jp064591c
58. [58]
  (58) Takahashi, H.; Watanabe, R.; Miyauchi, Y.; Mizutani, G. J. Chem. Phys. 2011, 134, 154704. doi: 10.1063/1.3578178
59. [59]
  (59) Kerisit, S.; Deskins, N. A.; Rosso, K. M.; Dupuis, M. J. Phys. Chem. C 2008, 112, 7678. doi: 10.1021/jp8007865
60. [60]
  (60) Shapovalov, V.; Stefanovich, E. V.; Truong, T. N. Surf. Sci. 2002, 498, L103.
61. [61]
  (61) Yang, X. J.; Tamai, N. Phys. Chem. Chem. Phys. 2001, 3, 3393. doi: 10.1039/b101721g
62. [62]
  (62) Tamaki, Y.; Furube, A.; Katoh, R.; Murai, M.; Hara, K.; Arakawa, H.; Tachiya, M. C. R. Chim. 2006, 9, 268. doi: 10.1016/j.crci.2005.05.018
63. [63]
  (63) Thompson, T. L.; Yates, J. T., Jr. J. Phys. Chem. B 2005, 109, 18230. doi: 10.1021/jp0530451
64. [64]
  (64) Berger, T.; Sterrer, M.; Diwald, O.; Knozinger, E.; Panayotov, D.; Thompson, T. L.; Yates, J. T., Jr. J. Phys. Chem. B 2005, 109, 6061. doi: 10.1021/jp0404293
65. [65]
  (65) Tang, H.; Levy, F.; Berger, H.; Schmid, P. E. Phys. Rev. B 1995, 52, 7771. doi: 10.1103/PhysRevB.52.7771
66. [66]
  (66) Stevanovic, A.; Buettner, M.; Zhang, Z.; Yates, J. T., Jr. J. Am. Chem. Soc. 2012, 134, 324. doi: 10.1021/ja2072737
67. [67]
  (67) Murakami, M.; Matsumoto, Y.; Nakajima, K.; Makino, T.; Segawa, Y.; Chikyow, T.; Ahmet, P.; Kawasaki, M.; Koinuma, H. Appl. Phys. Lett. 2001, 78, 2664. doi: 10.1063/1.1365412
1. [1]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
5. [5]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
6. [6]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
7. [7]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
8. [8]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
9. [9]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
10. [10]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
11. [11]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
12. [12]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
13. [13]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
19. [19]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
20. [20]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(479)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fundamental Processes in Surface Photocatalysis on TiO2

Metrics

通讯作者: 陈斌, bchen63@163.com

Fundamental Processes in Surface Photocatalysis on TiO₂