Citation: ZHANG Xiao-Hong, XU Hong-Yan, GE Ling-Ling, GUO Rong. Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 356-364. doi: 10.3866/PKU.WHXB201512012 shu

Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions

1.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu Province, P. R. China

Corresponding author: GUO Rong,
Received Date: 15 October 2015
Available Online: 1 December 2015
Fund Project: 国家自然科学基金(201010113,21573191) (201010113,21573191)

The critical micelle concentrations of binary systems of surface active ionic liquid lauryl isoquinolium bromide ([C₁₂iQuin]Br) with nonionic surfactant Triton X-100 in aqueous solution were investigated by isothermal titration calorimetry. The location of [C₁₂iQuin]Br and Triton X-100 in the mixed micelle was studied using ¹H nuclear magnetic resonance (NMR) and two-dimensional nuclear Overhauser enhancement spectroscopy (2D NOESY). It was found that the polyoxyethylene chain of Triton X-100 forms random coils around the isoquinolinium ring. The interaction of molecules in the mixed micelle of [C₁₂iQuin]Br- Triton X-100 was also studied using regular solution theory and the cloud point measurement technique, with comparison to the interaction of doceyl trimethyl ammonium bromide (DTAB)-Triton X-100.
- Surface active ionic liquid,
- Lauryl isoquinolinium bromide,
- Triton X-100,
- Mixed micelle,
- Cloud point
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