Citation: WANG Yan-Juan, SUN Jia-Yao, FENG Rui-Jiang, ZHANG Jian. Preparation of Ternary Metal Sulfide/g-C₃N₄ Heterojunction Catalysts and Their Photocatalytic Activity under Visible Light[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 728-736. doi: 10.3866/PKU.WHXB201511303 shu

Preparation of Ternary Metal Sulfide/g-C₃N₄ Heterojunction Catalysts and Their Photocatalytic Activity under Visible Light

1.
Division of Chemistry, Chemical Engineering and Environment, Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China

Corresponding author: ZHANG Jian,
Received Date: 15 September 2015
Available Online: 24 November 2015
Fund Project: 辽宁省自然科学基金(2015020590) (2015020590)

A novel Zn-Mo-CdS/g-C₃N₄ heterojunction photocatalyst was prepared by hydrothermal posttreatment using dicyandiamide, zinc acetate, ammonium molybdate, cadmium acetate, and sodium sulfide as raw materials. X-ray diffraction (XRD), ultraviolet-visible (UV-Vis), inductively coupled plasma atomic emission (ICP-AES), electrochemical impedance spectroscopy (EIS), and X-ray photoelectron spectroscopy (XPS) were used to characterize the prepared catalysts. The results indicate that heterojunctions are formed across the g-C₃N₄/Zn-Mo-CdS interface, which promotes interfacial charge transfer and inhibits the recombination of electrons and holes. The activities of as-prepared catalysts were tested through the photocatalytic degradation of Rhodamine B (RhB) under visible light. The results show that the Zn-Mo-CdS/g-C₃N₄ heterojunction photocatalyst clearly displayed increased activity compared with single g-C₃N₄ and Zn-Mo-CdS. At an optimal g-C₃N₄ mass fraction of 20%, the as-prepared heterojunction photocatalyst displayed the highest rate constant under visible light, which was 30 and 10 times of single g-C₃N₄ and Zn-Mo-CdS, respectively. Not only Zn-Mo-CdS, but also Mo-Ni-CdS and Ni-Sn-CdS can form heterojunctions with g-C₃N₄ to promote the rate of separation of electrons and holes and improve photocatalytic activity.
- Carbon nitride,
- Ternary metal sulfide,
- Heterojunction,
- Photocatalysis,
- Organic matter degradation
1. [1]
  (1) Kondo, K.; Murakami, N.; Ye, C.; Tsubota, T.; Ohno, T. Appl. Catal. B: Environ. 2013, 142-143, 362.
2. [2]
  (2) Chen, X. B.; Shen, S. H.; Guo, L. J. Chem. Rev. 2010, 110, 6503. doi: 10.1021/cr1001645
3. [3]
  (3) Zhang, G. G.; Zhang, M.W.; Ye, X. X.; Qiu, X. Q.; Lin, S.; Wang, X. C. Adv. Mater. 2014, 26, 805. doi: 10.1002/adma.201303611
4. [4]
  (4) Xu, J.; Wu, H. T.; Wang, X.; Xue, B.; Li, Y. X.; Cao, Y. Phys. Chem. Chem. Phys. 2013, 15, 4510. doi: 10.1039/c3cp44402c
5. [5]
  (5) Ge, L. Mater. Lett. 2011, 65, 2652. doi: 10.1016/j.matlet.2011.05.069
6. [6]
  (6) Niu, P.; Zhang, L.; Liu, G.; Cheng, H. Adv. Funct. Mater. 2012, 22, 4763. doi: 10.1002/adfm.v22.22
7. [7]
  (7) Zhang, Q.; Wang, H. Y.; Hu, S. Z.; Lu, G.; Bai, J.; Kang, X.X.; Liu, D.; Gui, J. Z. RSC Adv. 2015, 5, 42736. doi: 10.1039/C5RA04189A
8. [8]
  (8) Ong, W. J.; Tan, L. L.; Chai, S. P.; Yong, S. T. Chem. Commun.2015, 51, 858. doi: 10.1039/C4CC08996K
9. [9]
  (9) Ong, W. J.; Tan, L. L.; Chai, S. P.; Yong, S. T.; Mohamed, A.R. Nano Energy 2015, 13, 757. doi: 10.1016/j.nanoen.2015.03.014
10. [10]
  (10) Tian, N.; Huang, H.W.; He, Y.; Guo, Y. X.; Zhang, Y. H. RSC Adv. 2014, 4, 42716. doi: 10.1039/C4RA05917D
11. [11]
  (11) He, Y. M.; Zhang, L. H.; Wang, X. X.; Wu, Y.; Lin, H. J.; Zhao, L. H.; Weng, W. Z.; Wan, H. L.; Fan, M. H. RSC Adv. 2014, 4, 13610. doi: 10.1039/c4ra00693c
12. [12]
  (12) Wang, Y. J.; Bai, X. J.; Pan, C. S.; He, J.; Zhu, Y. F. J. Mater. Chem. 2012, 22, 11568. doi: 10.1039/c2jm16873a
13. [13]
  (13) Hu, J. S.; Ren, L. L.; Guo, Y. G.; Liang, H. P.; Cao, A. M.; Wan, L. J.; Bai, C. L. Angew. Chem. Int. Edit. 2012, 44, 1269.
14. [14]
  (14) Yan, H. J.; Yang, J. H.; Ma, G. J.; Wu, G. P.; Zong, X.; Lei, Z.B.; Shi, J. Y.; Li, C. J. Catal. 2009, 266, 165. doi: 10.1016/j.jcat.2009.06.024
15. [15]
  (15) Huo, Y. N.; Yang, X. L.; Zhu, J.; Li, H. X. Appl. Catal. B: Environ. 2011, 106, 69.
16. [16]
  (16) Fan, Y. H.; Luo, Q.; Liu, G. X.; Wang, J. X.; Dong, X. T.; Yu, W. S.; Sun, D. Chin. J. Inorg. Chem. 2014, 30, 627. [范英华, 雒琴, 刘桂霞, 王进贤, 董相廷, 于文生, 孙德. 无机化学学报, 2014, 30, 627.]
17. [17]
  (17) Nie, Q. L.; Yuan, Q. L.; Wang, Q. S.; Xu, Z. D. J. Mater. Sci.2004, 39, 5611. doi: 10.1023/B: JMSC.0000039301.70811.a4
18. [18]
  (18) Xia, S.; Lei, W.; Yang, Y. L. Nanoscale Res. Lett. 2011, 6, 562. doi: 10.1186/1556-276X-6-562
19. [19]
  (19) Xu, Y.; Schoonen, M. A. A. Am. Mineral. 2000, 85, 543. doi: 10.2138/am-2000-0416
20. [20]
  (20) Ge, L.; Han, C.; Xiao, X. Int. J. Hydrog. Energy 2013, 38, 6960. doi: 10.1016/j.ijhydene.2013.04.006
21. [21]
  (21) Sun, M.; Yan, T.; Yan, Q; Liu, H. Y.; Yan, L. G.; Zhang, Y. F.; Du, B. RSC Adv. 2014, 4, 19980. doi: 10.1039/c4ra01439a
22. [22]
  (22) Sun, M.; Yan, Q.; Yan, T.; Li, M. M.; Wei, D.; Wang, Z. P.; Wei, Q.; Du, B. RSC Adv. 2014, 4, 31019. doi: 10.1039/C4RA03843F
23. [23]
  (23) Xiang, Q.; Yu, J.; Jaroniec, M. J. Am. Chem. Soc. 2012, 134, 6575. doi: 10.1021/ja302846n
24. [24]
  (24) Zong, X.; Yan, H. J.; Wu, G. P.; Ma, G. J.; Wen, F. Y.; Wang, L.; Li, C. J. Am. Chem. Soc. 2008, 130, 7176. doi: 10.1021/ja8007825
25. [25]
  (25) Shen, L. J.; Luo, M. B.; Liu, Y. H.; Liang, R.W.; Jing, F. F.; Wu, L. Appl. Catal. B: Environ. 2015, 166-167, 445.
26. [26]
  (26) Chen, F. J.; Cao, Y. L.; Jia, D. Z.; Liu, A. J. Dyes Pigments2015, 120, 8. doi: 10.1016/j.dyepig.2015.03.030
27. [27]
  (27) Chen, F. J.; Cao, Y. L.; Jia, D. Z. Ceram. Int. 2015, 41, 6645. doi: 10.1016/j.ceramint.2015.01.111
28. [28]
  (28) Hu, S. Z.; Li, F. Y.; Fan, Z. P.; Wang, F.; Zhao, Y. F.; Lv, Z. B. Dalton Trans. 2015, 44, 1084. doi: 10.1039/C4DT02658F
29. [29]
  (29) Wang, D. S.; Duan, Y. D.; Luo, Q. Z.; Li, X. Y.; Bao, L. L.Desalination 2011, 270, 174. doi: 10.1016/j.desal.2010.11.042
30. [30]
  (30) Lu, M. L.; Pei, Z. X.; Weng, S. X.; Feng, W. H.; Fang, Z. B.; Zheng, Z. Y.; Huang, M. L.; Liu, P. Phys. Chem. Chem. Phys.2014, 16, 21280. doi: 10.1039/C4CP02846E
31. [31]
  (31) Liu, L. Y.; Yang, L.; Pu, Y. T.; Xiao, D. Q.; Zhu, J. G. Mater. Lett. 2012, 66, 121. doi: 10.1016/j.matlet.2011.08.025
32. [32]
  (32) Ge, L.; Han, C. C.; Liu, J. Appl. Catal. B: Environ. 2011, 108-109, 100.
33. [33]
  (33) Liu, H.; Jin, Z. T.; Xu, Z. Z. Dalton Trans. 2015, 44, 14368. doi: 10.1039/C5DT01364J
34. [34]
  (34) Dong, F.; Zhao, Z.W.; Xiong, T.; Ni, Z. L.; Zhang, W. D.; Sun, Y. J.; Ho, W. K. ACS Appl. Mater. Interf. 2013, 5, 11392. doi: 10.1021/am403653a
35. [35]
  (35) Cao, J.; Luo, B. D.; Lin. H. L.; Xu, B. Y.; Chen, S. F.J. Hazard. Mater. 2012, 217-218, 107.
36. [36]
  (36) Wang, Y.; Wang, X. C.; Antonietti, M. Angew. Chem. Int. Edit.2012, 51, 68. doi: 10.1002/anie.201101182
37. [37]
  (37) Ge, L.; Han, C. Appl. Catal. B: Environ. 2012, 117-118, 268.
38. [38]
  (38) Ma, D. K.; Zhou, H. Y.; Zhang, J. H.; Qian, Y. T. Mater. Chem. Phys. 2008, 111, 391. doi: 10.1016/j.matchemphys.2008.04.035
39. [39]
  (39) Zhu, Y. P.; Li, J.; Ma, T. Y.; Liu, Y. P.; Du, G. H.; Yuan, Z. Y.J. Mater. Chem. A 2014, 2, 1093. doi: 10.1039/C3TA13636A
40. [40]
  (40) Zhang, K.; Kim, W. J.; Ma, M.; Shi, X. J.; Park, J. H. J. Mater. Chem. A 2015, 3, 4803. doi: 10.1039/C4TA05571C
41. [41]
  (41) Li, Y. G.; Wei, X. L.; Li, H. J.; Wang, R. R.; Feng, J.; Yun, H.; Zhou, A. N. RSC Adv. 2015, 5, 14074 doi: 10.1039/C4RA14690E
42. [42]
  (42) Xu, Y.; Xu, H.; Wang, L.; Yan, J.; Li, H.; Song, Y.; Huang, L.; Cai, G. Dalton Trans. 2013, 42, 7604. doi: 10.1039/c3dt32871f
43. [43]
  (43) He, B. L.; Dong, B.; Li, H. L. Electrochem. Commun. 2007, 9, 425. doi: 10.1016/j.elecom.2006.10.008
44. [44]
  (44) Zhang, J.; Wang, Y. J.; Hu, S. Z. Acta Phys. -Chim. Sin. 2015, 31, 159. [张健, 王彥娟, 胡绍争. 物理化学学报, 2015, 31, 159.] doi: 10.3866/PKU.WHXB201411201
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ternary Metal Sulfide/g-C3N4 Heterojunction Catalysts and Their Photocatalytic Activity under Visible Light

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通讯作者: 陈斌, bchen63@163.com

Preparation of Ternary Metal Sulfide/g-C₃N₄ Heterojunction Catalysts and Their Photocatalytic Activity under Visible Light