Citation: WANG Xiao-Jie, THAMARATH Smitha Surendran, ALIA A. BODE Bela E., MATYSIK Jörg. The Solid-State Photo-CIDNP Effect[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 399-404. doi: 10.3866/PKU.WHXB201511272 shu

The Solid-State Photo-CIDNP Effect

1.
1 Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073, P. R. China;
2.
2 Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Gemany;
3.
3 Leiden Institute of Chemistry, Einsteinweg 55, 2300 RA Leiden, The Netherlands;
4.
4 Institute of Medical Physics and Biophysics, University of Leipzig, D-04107 Leipzig, Germany;
5.
5 EaStCHEM School of Chemistry and Biomedical Sciences Research Complex, University of St Andrews, St Andrews, KY16 9ST, Scotland

Corresponding author: WANG Xiao-Jie, MATYSIK Jörg,
Received Date: 21 September 2015
Available Online: 26 November 2015
Fund Project: 荷兰科学研究组织(NWO)(713.012.001)资助项目 (NWO)(713.012.001)

Photochemically induced dynamic nuclear polarization (photo-CIDNP) is an effect that produces non-Boltzmann nuclear spin polarization, which can be observed as a modification of signal intensity in nuclear magnetic resonance (NMR) spectroscopy. The effect is well known in liquid-state NMR, where it is explained most generally by the classical radical pair mechanism (RPM). In the solid-state, additional mechanisms are operative in the spin-dynamics of radical pairs, such as three-spin mixing (TSM), differential decay (DD) and differential relaxation (DR). The observed solid-state photo-CIDNP effect is strongly magnetic field dependent, and this field-dependence is well distinguished for the various nuclei. Here, we provide an account of the phenomenology, theory and properties of the magnetic field dependence of the solid-state photo-CIDNP effect.
- Photo-CIDNP,
- Magic angle spinning,
- Nuclear magnetic resonance,
- Radical pair,
- Spin chemistry
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